Skip to main content
Log in

Natural antioxidant from bamboo leaves for the processing stability of polypropylene

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

The antioxidant of bamboo leaves (AOB) was used firstly to stabilize polypropylene (PP). Thermogravimetric analysis, oxidation onset temperature and oxidation induction time tests were carried out to test the thermal and thermo-oxidative stability of samples. The melt flow rate and yellowness index were used to characterize the processing stability and color of samples. Field emission scanning electron microscopy was used to determine the distribution of additives. Results showed that AOB improved the thermo-oxidative stability and processing stability of PP. The efficacy of AOB was comparable with that of Irganox 1010 in protecting PP. However, due to the dark yellow color of AOB, the problem of the discoloration of the polymer matrix was not solved.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11

Similar content being viewed by others

References

  1. Boyong X, Ogata K, Toyota A. Synthesis of polymeric antioxidants based on ring-opening metathesis polymerization (ROMP) and their antioxidant ability for preventing polypropylene (PP) from thermal oxidation degradation. Polym Degrad Stab. 2008;93:347–52.

    Article  Google Scholar 

  2. Gao YH, Jiang F, Zhang L, Cui YC. Enzymatic synthesis of polyguaiacol and its thermal antioxidant behavior in polypropylene. Polym Bull. 2016;73:1343–59.

    Article  CAS  Google Scholar 

  3. Brocca D, Arvin E, Mosbæk H. Identification of organic compounds migrating from polyethylene pipelines into drinking water. Water Res. 2002;36:3675–80.

    Article  CAS  Google Scholar 

  4. Tatraaljai D, Kirschwengab B, Kovács J, Födes E, Pukanszky B. Processing stabilisation of PE with a natural antioxidant, curcumin. Eur Polym J. 2013;49:1196–206.

    Article  CAS  Google Scholar 

  5. Kirschwengab B, Tatraaljai D, Födes E, Pukanszky B. Efficiency of curcumin, a natural antioxidant, in the processing stabilization of PE: concentration effects. Polym Degrad Stab. 2015;118:17–23.

    Article  Google Scholar 

  6. Tatraaljai D, Födes E, Pukanszky B. Efficient melt stabilization of polyethylene with quercetin, a flavonoid type natural antioxidant. Polym Degrad Stab. 2014;102:41–8.

    Article  CAS  Google Scholar 

  7. Kirschweng B, Benedek V, Tatraaljai D, Miklós Z, Födes E, Pukanszky B. Natural antioxidants as melt stabilizers for PE: comparison of silymarin and quercetin. Eur Polym J. 2017;90:456–66.

    Article  CAS  Google Scholar 

  8. Tatraaljai D, Major L, Födes E, Pukanszky B. Study of the effect of natural antioxidants in polyethylene: performance of β-carotene. Polym Degrad Stab. 2014;102:33–40.

    Article  CAS  Google Scholar 

  9. Ambrogi V, Cerruti P, Carfagna C, Malinconico M, Marturano V, Perrotti M, Persico P. Natural antioxidants for polypropylene stabilization. Polym Degrad Stab. 2011;96:2152–8.

    Article  CAS  Google Scholar 

  10. Bridson JH, Kaur J, Zhang ZH, Donaldson L, Fernyhough A. Polymeric flavonoids processed with co-polymers as UV and thermal stabilisers for polyethylene films. Polym Degrad Stab. 2015;122:18–24.

    Article  CAS  Google Scholar 

  11. Kirschweng B, Bencze K, Sárköozi M, Hégely B, Samu G, Haria J, Tatraaljai D, Földes E, Kállay M, Pukánszky B. Melt stabilization of polyethylene with dihydromyricetin, a natural antioxidant. Polym Degrad Stab. 2016;133:192–200.

    Article  CAS  Google Scholar 

  12. Xin ML, Ma YJ, Lin WH, Xu K, Chen MC. Use of dihydromyricetin as antioxidant for polypropylene stabilization. J Therm Anal Calorim. 2015;120:1741–7.

    Article  CAS  Google Scholar 

  13. Veronica A, Lucia P, Paola P, Pierfrancesco C, Carlo AL, Cosimo C, Luisella V, Enrico C, Alessandra N, d’Ischia M. An antioxidant bioinspired phenolic polymer for efficient stabilization of polyethylene. Biomacromol. 2014;15:302–10.

    Article  Google Scholar 

  14. Reano AF, Domenek S, Pernes M, Beaugrand J, Allais F. Ferulic acid-based bis/trisphenols as renewable antioxidants for polypropylene and poly(butylene succinate). ACS Sustain Chem Eng. 2016;4:6562–71.

    Article  CAS  Google Scholar 

  15. Lucia P, Luis G, Sonia R, María ÁM, José ÁRH, Silvia P, Sergio PB, Alessandra N, d’Ischia M. A superior all-natural antioxidant biomaterial from spent coffee grounds for polymer stabilization, cell protection, and food lipid preservation. ACS Sustain Chem Eng. 2016;4:1169–79.

    Article  Google Scholar 

  16. Sarai AS, Nohemi GM, Luis ÁMJ, Mario M, Pierfrancesco C. Stabilization of polylactic acid and polyethylene with nutshell extract: efficiency assessment and economic evaluation. ACS Sustain Chem Eng. 2017;5:4607–18.

    Article  Google Scholar 

  17. Pierfrancesco C, Mario M, Jozef R, Lyda MR, Cosimo C. Effect of natural antioxidants on the stability of polypropylene films. Polym Degrad Stab. 2009;94:2095–100.

    Article  Google Scholar 

  18. Nanni A, Messori M. A comparative study of different winemaking by-products derived additives on oxidation stability, mechanical and thermal proprieties of polypropylene. Polym Degrad Stab. 2018;149:9–18.

    Article  CAS  Google Scholar 

  19. Aroso IM, Fernandes EM, Pires RA, Mano JF, Rui LR. Cork extractives exhibit thermo-oxidative protection properties in polypropylene-cork composites and as direct additives for polypropylene. Polym Degrad Stab. 2015;116:45–52.

    Article  CAS  Google Scholar 

  20. Iyer KA, Zhang LH, Torkelson JM. Direct use of natural antioxidant-rich agro-wastes as thermal stabilizer for polymer: processing and Recycling. ACS Sustain Chem Eng. 2016;4:881–9.

    Article  CAS  Google Scholar 

  21. Gong JY, Xia DZ, Huang J, Ge Q, Mao JW, Liu SW, Zhang Y. Functional components of bamboo shavings and bamboo leaf extracts and their antioxidant activities in vitro. J Med Food. 2015;18:453–9.

    Article  CAS  Google Scholar 

  22. Chun H, Ying Z, David DK. Evaluation of antioxidant and prooxidant activities of bamboo Phyllostachys nigra Var. Henonis leaf extract in vitro. J Agric Food Chem. 2000;48:3170–6.

    Article  Google Scholar 

  23. Ma YL, Zhu DY, Wang CH, Zhang YS, Shang YF, Liu FR, Ye TQ, Chen X, Wei ZJ. Simultaneous and fast separation of three chlorogenic acids and two flavonoids from bamboo leaves extracts using zirconia. Food Chem Toxicol. 2018;119:375–9.

    Article  CAS  Google Scholar 

  24. Liu MH, Ko CH, Ma N, Tan PW, Fu WM, He JY. Chemical profiles, antioxidant and anti-obesity effects of extract of Bambusa textilis McClure leaves. J Funct Foods. 2016;22:533–46.

    Article  CAS  Google Scholar 

  25. Xie J, Lin YS, Shi XJ, Zhu XY, Su WK, Wang P. Mechanochemical-assisted extraction of flavonoids from bamboo (Phyllostachys edulis) leaves. Ind Crop Prod. 2013;43:276–82.

    Article  CAS  Google Scholar 

  26. Awad AH, Abdel-Ghany AW, Abd El-Wahab A, El-Gamasy R, Abdellatif MH. The influence of adding marble and granite dust on the mechanical and physical properties of PP composites. J Therm Anal Calorim. 2020;140:2615–23.

    Article  CAS  Google Scholar 

  27. Wen X, Szymańska K, Chen XC, Mijowska E. Nanosized carbon black as synergist in PP/POE-MA/IFR system for simultaneously improving thermal, electrical and mechanical properties. J Therm Anal Calorim. 2020;139:1091–8.

    Article  CAS  Google Scholar 

  28. Kirschweng B, Tátraaljai D, Földes E, Pukánszky B. Natural antioxidants as stabilizers for polymers. Polym Degrad Stab. 2017;145:25–40.

    Article  CAS  Google Scholar 

  29. Leopoldini M, Russo N, Toscano M. The molecular basis of working mechanism of natural polyphenolic antioxidants. Food Chem. 2011;125:288–306.

    Article  CAS  Google Scholar 

  30. Deepha V, Praveena R, Sadasivam K. DFT studies on antioxidant mechanisms, electronic properties, spectroscopic (FT-IR and UV) and NBO analysis of C-glycosyl flavone, an isoorientin. J Mol Struct. 2015;1082:131–42.

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was funded by the Research Foundation of Qingdao Fusilin Chemical Science & Technology Co., Ltd. (FSL-RF 2016), National Natural Science Foundation of China (Grant Nos. 21676285 and 21306214) and Qingdao Indigenous Innovation Program (No. 15-9-1-76-jch).

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Xiaowen Huang or Qing Yu.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOCX 312 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Xia, H., Gao, H., Zhang, Y. et al. Natural antioxidant from bamboo leaves for the processing stability of polypropylene. J Therm Anal Calorim 146, 1657–1665 (2021). https://doi.org/10.1007/s10973-020-10115-0

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10973-020-10115-0

Keywords

Navigation