Abstract
The present work is to study the effect of pressure on the gasification of sugarcane bagasse in a pressurized circulating fluidized bed reactor. The range of operating pressure is maintained at 1–4 bar, and thereby the composition of generated syngas is measured with the help of gas chromatography. The gasification parameters like dry gas yield, lower heating value (LHV), cold gas efficiency (CGE), and carbon conversion efficiency (CCE) have been calculated from the syngas composition. The output yields some interesting results, i.e., with the increase in pressure from 1 to 4 bar, and there is an increment of concentration value by 26% for CH4 as well as CO2. However, a decreasing trend of H2 concentration (7.62–6.75% by volume) is observed for the same pressure rise. In addition, it has been observed a little deviation in the trend for CO (16.39–16.86%), which bears an increasing trend from a pressure of 1–2 bar and a decreasing trend thereafter. Following a similar trend for CO, the LHV first increases from 4013 to 4200 kJ Nm−3 with an increase in pressure from 1 to 2 bar and thereafter decreases gradually to 4081 kJ Nm−3 at a pressure of 4 bar. Apart from these parameters, gas yield, CCE, and CGE values imparted positive effects with pressure rise, and the magnitudes increased from 0.93 to 1.27 Nm3 kg−1, 38.3–57.5 and 23.3–32.3%, respectively, with an increase in pressure from 1 to 4 bar. The exergy destruction and exergy efficiency are observed to be 140 MW and 76% at 4 bar operating pressure.
Similar content being viewed by others
Abbreviations
- H2 :
-
Concentration of hydrogen in the syngas
- N2 :
-
Concentration of nitrogen in the syngas
- C:
-
Content of carbon in the feed material
- CO:
-
Concentration of carbon monoxide in the syngas
- CO2 :
-
Concentration of carbon dioxide in the syngas
- CH4 :
-
Concentration of methane in the syngas
- CmHn :
-
Concentration of higher hydrocarbon in the syngas
- c p :
-
Constant pressure specific heat capacity (kJ kmol−1 K−1)
- ER:
-
Equivalence ratio
- h :
-
Specific enthalpy (kJ kmol−1)
- X ash :
-
Ash content of the feed material
- Y :
-
Dry gas yield (Nm3 kg−1)
- Q a :
-
Mass flow rate of air (Nm3 h−1)
- M b :
-
Mass flow rate of feed material (kg h−1)
- LHV:
-
Lower heating value (kJ Nm−3)
- HHV:
-
Higher heating value (kJ Nm−3)
- \( {\dot{\text{E}}\text{n}} \) :
-
Energy rate (MW)
- \( {\dot{\text{E}}\text{x}}_{{{\text{feed}}\,{\text{material}}}} \) :
-
Exergy of feed material
- \( {\dot{\text{E}}\text{x}}_{\text{air}} \) :
-
Exergy of the fluidization air
- \( {\dot{\text{E}}\text{x}}_{{{\text{heat}}\,{\text{input}}}} \) :
-
Exergy of the electrical heat input
- \( {\dot{\text{E}}\text{x}}_{\text{Syngas}} \) :
-
Exergy of the syngas
- \( {\dot{\text{E}}\text{x}}_{\text{Char}} \) :
-
Exergy of the char
- \( {\dot{\text{E}}\text{x}}_{\text{tar}} \) :
-
Exergy of the tar
- \( \dot{I}_{\text{gasifier}} \) :
-
Irreversibility of the gasifier
- β :
-
Quality of feed material
References
Karmakar MK, Datta AB. Generation of hydrogen rich gas through fluidized bed gasification of biomass. Bioresour Technol. 2011;102:1907–13.
Tursunov O, Zubek K, Czerski G, Dobrowolski J. Studies of CO2 gasification of the Miscanthus giganteus biomass over Ni/Al2O3–SiO2 and Ni/Al2O3–SiO2 with K2O promoter as catalysts. J Therm Anal Calorim. 2020;139:3481–92.
Abdoulmoumine N, Kulkarni A, Adhikari S. Effects of temperature and equivalence ratio on pine syngas primary gases and contaminants in a bench-scale fluidized bed gasifier. Ind Eng Chem Res. 2014;53:5767–77.
Suksuwan W, Wae M, Mel M. Fluid development of mini pilot fluidized bed gasifier for industrial approach: preliminary study based on continuous operation Akademia Baru combust fine solid fuels having non-uniform size, is applied. Akademia Baru J Adv Res. 2018;1:35–43.
Naidu VS, Aghalayam P, Jayanti S. Evaluation of CO2 gasification kinetics for low-rank Indian coals and biomass fuels. J Therm Anal Calorim. 2016;123:467–78.
Chen D, Bu C, Wang X, Zhang J, Kobayashi N, Piao G, et al. Gasification and combustion kinetics of a high-ash-fusion-temperature coal using thermogravimetric analysis. J Therm Anal Calorim. 2020. https://doi.org/10.1007/s10973-020-09460-x.
Wang Y, Wang Z, Huang J, Fang Y. Investigation into the characteristics of Na2CO3-catalyzed steam gasification for a high-aluminum coal char. J Therm Anal Calorim. 2018;131:1213–20.
García-Ibañez P, Cabanillas A, Sánchez JM. Gasification of leached orujillo (olive oil waste) in a pilot plant circulating fluidised bed reactor. Preliminary results. Biomass Bioenergy. 2004;27:183–94.
Li XT, Grace JR, Lim CJ, Watkinson AP, Chen HP, Kim JR. Biomass gasification in a circulating fluidized bed. Biomass Bioenergy. 2004;26:171–93.
Doherty W, Reynolds A, Kennedy D. The effect of air preheating in a biomass CFB gasifier using ASPEN Plus simulation. Biomass Bioenergy. 2009;33:1158–67.
Duan W, Yu Q. Thermodynamic analysis of hydrogen-enriched syngas generation coupled with in situ CO2 capture using chemical looping gasification method. J Therm Anal Calorim. 2018;131:1671–80.
Cheng L, Basu P. Effect of pressure on loop seal operation for a pressurized circulating fluidized bed. Powder Technol. 1999;103:203–11.
Xiao R, Zhang M, Jin B, Huang Y, Zhou H, Motta IL, et al. Equilibrium modeling of gasification: a free energy minimization approach and its application to a circulating fluidized bed coal gasifier. Biomass Bioenergy. 2018;53:433–45.
Srinivas T, Gupta AVSSKS, Reddy BV. Thermodynamic equilibrium model and exergy analysis of a biomass gasifier. J Energy Resour Technol. 2009;131:031801.
Sahoo A, Ram DK. Gasifier performance and energy analysis for fluidized bed gasification of sugarcane bagasse. Energy. 2015;90:1420–5.
Figueroa JEJ, Ardila YC, Filho RM, Maciel MRW. Fluidized bed reactor for gasification of sugarcane bagasse: distribution of syngas, bio-tar and char. Chem Eng Trans. 2014;37:229–34.
Pellegrini LF, de Oliveira S. Exergy analysis of sugarcane bagasse gasification. Energy. 2007;32:314–27.
Ardila YC, Figueroa JEJ, Lunelli BH, Filho RM, Maciel MRW. Syngas production from sugar cane bagasse in a circulating fluidized bed gasifier using Aspen Plus™: modelling and simulation. Comput Aided Chem Eng. 2012;30:1093–7.
Motta IL, Miranda NT, Maciel Filho R, Wolf Maciel MR. Sugarcane bagasse gasification: Simulation and analysis of different operating parameters, fluidizing media, and gasifier types. Biomass Bioenergy. 2019;122:433–45.
Ptasinski KJ, Prins MJ, Pierik A. Exergetic evaluation of biomass gasification. Energy. 2007;32:568–74.
Dhivagar R, Mohanraj M, Hidouri K, Belyayev Y. Energy, exergy, economic and enviro-economic (4E) analysis of gravel coarse aggregate sensible heat storage-assisted single-slope solar still. J Therm Anal Calorim. 2020. https://doi.org/10.1007/s10973-020-09766-w.
Zhang Y, Li B, Li H, Liu H. Exergy analysis of biomass gasification with steam/air: a comparison study. In: Proceedings of the 2010 international conference on digital manufacturing and automation ICDMA 2010, vol 1. 2010. pp. 678–81.
Karamarkovic R, Karamarkovic V. Energy and exergy analysis of biomass gasification at different temperatures. Energy. 2010;35:537–49.
Li G, Liu Z, Liu F, Yang B, Ma S, Weng Y, et al. Advanced exergy analysis of ash agglomerating fluidized bed gasification. Energy Convers Manag. 2019;199:111952.
Martínez González A, Lesme Jaén R, Silva Lora EE. Thermodynamic assessment of the integrated gasification-power plant operating in the sawmill industry: an energy and exergy analysis. Renew Energy. 2020;147:1151–63.
Mahapatro A, Mahanta P, Jana K. Hydrodynamic study of low-grade Indian coal and sawdust as bed inventory in a pressurized circulating fluidized bed. Energy. 2019;189:116234.
Mahapatro A, Mahanta P. Gasification studies of low-grade Indian coal and biomass in a lab-scale pressurized circulating fl uidized bed. Renew Energy. 2020;150:1151–9.
Zhang Y, Li B, Li H, Liu H. Thermodynamic evaluation of biomass gasification with air in autothermal gasifiers. Thermochim Acta. 2011;519:65–71.
Li J, Li F, Liu W, Liu Z, Zhan H, Zhang Y, et al. Influence of pressure on fluidized bed gasifier: specific coal throughput and particle behavior. Fuel. 2018;220:80–8.
Han L, Wang Q, Luo Z, Rong N, Deng G. H2 rich gas production via pressurized fluidized bed gasification of sawdust with in situ CO2 capture. Appl Energy. 2013;109:36–43.
Kitzler H, Pfeifer C, Hofbauer H. Pressurized gasification of woody biomass-variation of parameter. Fuel Process Technol. 2011;92:908–14.
Duan F, Jin B, Huang Y, Li B, Wu Y, Zhang M. Results of bituminous coal gasification upon exposure to a pressurized pilot-plant circulating fluidized-bed (CFB) reactor. Energy Fuels. 2010;24:3150–8.
Gül S, Akgün F, Aydar E, Ünlü N. Pressurized gasification of lignite in a pilot scale bubbling fluidized bed reactor with air, oxygen, steam and CO2 agents. Appl Therm Eng. 2018;130:203–10.
Yin XL, Wu CZ, Zheng SP, Chen Y. Design and operation of a CFB gasification and power generation system for rice husk. Biomass Bioenergy. 2002;23:181–7.
Mayerhofer M, Mitsakis P, Meng X, De Jong W, Spliethoff H, Gaderer M. Influence of pressure, temperature and steam on tar and gas in allothermal fluidized bed gasification. Fuel. 2012;99:204–9.
Fermoso J, Arias B, Gil MV, Plaza MG, Pevida C, Pis JJ, et al. Co-gasification of different rank coals with biomass and petroleum coke in a high-pressure reactor for H2-rich gas production. Bioresour Technol. 2010;101:3230–5.
Xiao R, Zhang M, Jin B, Huang Y, Zhou H. High-temperature air/steam-blown gasification of coal in a pressurized spout-fluid bed. Energy Fuels. 2006;20:715–20.
Li X, Grace JR, Watkinson AP, Lim CJ, Ergüdenler A. Equilibrium modeling of gasification: a free energy minimization approach and its application to a circulating fluidized bed coal gasifier. Fuel. 2001;80:195–207.
Fermoso J, Arias B, Plaza MG, Pevida C, Rubiera F, Pis JJ, et al. High-pressure co-gasification of coal with biomass and petroleum coke. Fuel Process Technol. 2009;90:926–32.
Zhang Y, Li B, Li H, Zhang B. Exergy analysis of biomass utilization via steam gasification and partial oxidation. Thermochim Acta. 2012;538:21–8.
Manatura K, Lu JH, Wu KT, Te HsuH. Exergy analysis on torrefied rice husk pellet in fluidized bed gasification. Appl Therm Eng. 2017;111:1016–24.
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Mahapatro, A., Kumar, A. & Mahanta, P. Parametric study and exergy analysis of the gasification of sugarcane bagasse in a pressurized circulating fluidized bed gasifier. J Therm Anal Calorim 141, 2635–2645 (2020). https://doi.org/10.1007/s10973-020-10108-z
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10973-020-10108-z