Abstract
Soybean oil-based polyurethane (PU)/epoxy (EP) interpenetrating polymer network (IPN) nanocomposites were prepared with natural attapulgite (N-ATT) and acid-treated attapulgite (A-ATT). The structure, glass transition, damping properties, thermal stability, mechanical properties and morphology of PU/EP IPN/ATT nanocomposites were characterized by X-ray diffraction (XRD), dynamic mechanical analysis (DMA), thermogravimetric analyzer, universal test machine and scanning electronic microscope (SEM). XRD showed that interaction with PU did not change the crystal structures of ATT. DMA results revealed the addition of ATT improved the glass transition temperature of the soybean oil-based PU/EP IPN, especially for A-ATT. However, the incorporation of ATT slightly decreased the damping properties of the soybean oil-based PU/EP IPN. Tensile tests confirmed that A-ATT had a significant reinforcement effect on the soybean oil-based PU/EP IPN. The tensile strength of the soybean oil-based PU/EP IPN increased by 56% with the addition of 4 mass% A-ATT. SEM demonstrated the relatively uniform dispersion of both N-ATT and A-ATT in the soybean oil-based PU/EP IPN matrix.
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References
Petrie E. Epoxy adhesive formulations. New York: McGraw Hill; 2005.
Chen R, Gong J, Jiang Y, Wang Q, Xi Z, Xie H. Halogen-free flame retarded cold-mix epoxy asphalt binders: rheological, thermal and mechanical characterization. Constr Build Mater. 2018;186:863–70.
Sun Y, Gong J, Liu Y, Jiang Y, Xi Z, Cai J, et al. Viscous, damping, and mechanical properties of epoxy asphalt adhesives containing different penetration-grade asphalts. J Appl Polym Sci. 2019;136(5):47027.
Liu Y, Zhang J, Jiang Y, Li C, Xi Z, Cai J, et al. Investigation of secondary phase separation and mechanical properties of epoxy SBS-modified asphalts. Constr Build Mater. 2018;165:163–72.
Zhang Y, Sun Y, Xu K, Yuan Z, Zhang J, Chen R, et al. Brucite modified epoxy mortar binders: flame retardancy, thermal and mechanical characterization. Constr Build Mater. 2015;93:1089–96.
Liu Y, Xi Z, Cai J, Xie H. Laboratory investigation of the properties of epoxy asphalt rubber (EAR). Mater Struct. 2017;50(5):219.
Auvergne R, Caillol S, David G, Boutevin B, Pascault J-P. Biobased thermosetting epoxy: present and future. Chem Rev. 2014;114(2):1082–115.
Yin H, Jin H, Wang C, Sun Y, Yuan Z, Xie H, et al. Thermal, damping, and mechanical properties of thermosetting epoxy-modified asphalts. J Therm Anal Calorim. 2014;115(2):1073–80.
Kargarzadeh H, Ahmad I, Abdullah I. Liquid rubbers as toughening agents. Micro- and nanostructured epoxy/rubber blends. New York: Wiley; 2014. p. 31–52.
Dhevi DM, Jaisankar SN, Pathak M. Effect of new hyperbranched polyester of varying generations on toughening of epoxy resin through interpenetrating polymer networks using urethane linkages. Eur Polym J. 2013;49(11):3561–72.
Zhang J, Wang Y, Wang X, Ding G, Pan Y, Xie H, et al. Effects of amino- functionalized carbon nanotubes on the properties of amine- terminated butadiene- acrylonitrile rubber- toughened epoxy resins. J Appl Polym Sci. 2014;131(13):40472.
Wang YT, Wang CS, Yin HY, Wang LL, Xie HF, Cheng RS. Carboxyl-terminated butadiene-acrylonitrile-toughened epoxy/carboxyl-modified carbon nanotube nanocomposites: thermal and mechanical properties. Express Polym Lett. 2012;6(9):719–28.
Harani H, Fellahi S, Bakar M. Toughening of epoxy resin using synthesized polyurethane prepolymer based on hydroxyl-terminated polyesters. J Appl Polym Sci. 1998;70(13):2603–18.
Sperling L, Hu R. Interpenetrating polymer networks. Polymer blends handbook. Berlin: Springer; 2014. p. 677–724.
Lv X, Huang Z, Huang C, Shi M, Gao G, Gao Q. Damping properties and the morphology analysis of the polyurethane/epoxy continuous gradient IPN materials. Compos Part B Eng. 2016;88:139–49.
Karak N. Vegetable oil-based polymers. Cambridge: Woodhead Publishing Limited; 2012.
Liu W, Xu K, Wang C, Qian B, Sun Y, Zhang Y, et al. Carbon nanofibers reinforced soy polyol-based polyurethane nanocomposites. J Therm Anal Calorim. 2016;123(3):2459–68.
Wang C, Zhang Y, Lin L, Ding L, Li J, Lu R, et al. Thermal, mechanical, and morphological properties of functionalized graphene-reinforced bio-based polyurethane nanocomposites. Eur J Lipid Sci Technol. 2015;117(12):1940–6.
Chen S, Wang Q, Wang T, Pei X. Preparation, damping and thermal properties of potassium titanate whiskers filled castor oil-based polyurethane/epoxy interpenetrating polymer network composites. Mater Des. 2011;32(2):803–7.
Jin H, Zhang Y, Wang C, Sun Y, Yuan Z, Pan Y, et al. Thermal, mechanical, and morphological properties of soybean oil-based polyurethane/epoxy resin interpenetrating polymer networks (IPNs). J Therm Anal Calorim. 2014;117(2):773–81.
Xu K, Chen R, Wang C, Sun Y, Zhang J, Liu Y, et al. Organomontmorillonite-modified soybean oil-based polyurethane/epoxy resin interpenetrating polymer networks (IPNs). J Therm Anal Calorim. 2016;126(3):1253–60.
Bradley W. The structural scheme of attapulgite. Am Mineral. 1940;25:405–10.
Sun Y, Zhang Y, Xu K, Xu W, Yu D, Zhu L, et al. Thermal, mechanical properties, and low-temperature performance of fibrous nanoclay-reinforced epoxy asphalt composites and their concretes. J Appl Polym Sci. 2015;132(12):41694.
Wang C, Wang Y, Liu W, Yin H, Yuan Z, Wang Q, et al. Natural fibrous nanoclay reinforced soy polyol-based polyurethane. Mater Lett. 2012;78:85–7.
Williams RJJ, Rozenberg BA, Pascault J-P. Reaction-induced phase separation in modified thermosetting polymers. Polymer analysis polymer physics. Berlin: Springer; 1997. p. 95–156.
Sun Y, Liu Y, Jiang Y, Xu K, Xi Z, Xie H. Thermal and mechanical properties of natural fibrous nanoclay reinforced epoxy asphalt adhesives. Int J Adhes Adhes. 2018;85:308–14.
Komadel P. Acid activated clays: materials in continuous demand. Appl Clay Sci. 2016;131:84–99.
Lai S-Q, Li T-S, Liu X-J, Lv R-G. A Study on the friction and wear behavior of PTFE filled with acid treated nano-attapulgite. Macromol Mater Eng. 2004;289(10):916–22.
Tang QG, Yang Y, Wang F, Liang XH, Zhang FQ, Liang JS. Effect of acid on surface properties of modified attapulgite and performance of styrene butadiene rubber filled by modified attapulgite. Nanosc Nanotechnol Lett. 2014;6(3):231–7.
Yeh JT, Wang CK, Tsai CC, Lin CH, Huang CY, Chen KN, et al. Ultradrawing properties of ultra-high molecular weight polyethylene/hydrochloric acid treated attapulgite fibers. J Polym Res. 2013;20(9):240.
Wang W, Li A, Zhang J, Wang A. Study on superabsorbent composite. XI. Effect of thermal treatment and acid activation of attapulgite on water absorbency of poly(acrylic acid)/attapulgite superabsorbent composite. Polym Compos. 2007;28(3):397–404.
Wang W, Zhang J, Chen H, Wang A. Study on superabsorbent composite. VIII. Effects of acid- and heat- activated attapulgite on water absorbency of polyacrylamide/attapulgite. J Appl Polym Sci. 2007;103(4):2419–24.
Wang R, Li Z, Wang Y, Liu W, Deng L, Jiao W, et al. Effects of modified attapulgite on the properties of attapulgite/epoxy nanocomposites. Polym Compos. 2013;34(1):22–31.
Wang C, Dai L, Yang Z, Ge C, Li S, He M, et al. Reinforcement of castor oil-based polyurethane with surface modification of attapulgite. Polymers. 2018;10(11):1236.
Dai HH, Yang LT, Lin B, Wang CS, Shi G. Synthesis and characterization of the different soy-based polyols by ring opening of epoxidized soybean oil with methanol, 1,2-ethanediol and 1,2-propanediol. J Am Oil Chem Soc. 2009;86(3):261–7.
Wang C, Ding L, Wu Q, Liu F, Wei J, Lu R, et al. Soy polyol-based polyurethane modified by raw and silylated palygorskite. Ind Crop Prod. 2014;57:29–34.
Mendelovici E. Infrared study of attapulgite and HCl treated attapulgite. Clays Clay Miner. 1973;21(2):115–9.
Myriam M, Suarez M, Martin-Pozas JM. Structural and textural modifications of palygorskite and sepiolite under acid treatment. Clays Clay Miner. 1998;46(3):225–31.
González F, Pesquera C, Benito I. Thermal investigation of acid-activated attapulgites: influence of isomorphic substitution in the octahedral sheet. Thermochim Acta. 1992;194:239–46.
Gonzalez F, Pesquera C, Benito I, Mendioroz S, Pajares JA. Mechanism of acid activation of magnesic palygorskite. Clays Clay Miner. 1989;37(3):258–62.
Boudriche L, Calvet R, Hamdi B, Balard H. Effect of acid treatment on surface properties evolution of attapulgite clay: an application of inverse gas chromatography. Colloids Surf A Physicochem Eng Asp. 2011;392(1):45–54.
Tian M, Qu C, Feng Y, Zhang L. Structure and properties of fibrillar silicate/SBR composites by direct blend process. J Mater Sci. 2003;38(24):4917–24.
Wang LH, Sheng J. Preparation and properties of polypropylene/org-attapulgite nanocomposites. Polymer. 2005;46(16):6243–9.
Guo N, Wang J-S, Li J, Teng Y-G, Zhai Y-Z. Dynamic adsorption of Cd2+ onto acid-modified attapulgite from aqueous solution. Clays Clay Miner. 2014;62(5–6):415–24.
Chartoff RP, Weissman PT, Sircar A. The application of dynamic mechanical methods to Tg determination in polymers: an overview. Assignment of the glass transition. West Conshohocken: ASTM International; 1994.
Yan W, Yuan P, Chen M, Wang L, Liu D. Infrared spectroscopic evidence of a direct addition reaction between palygorskite and pyromellitic dianhydride. Appl Surf Sci. 2013;265:585–90.
Xie H, Liu B, Yang H, Wang Z, Shen J, Cheng R. Thermal characterization of carbon-nanofiber-reinforced tetraglycidyl-4,4’-diaminodiphenylmethane/4,4’-diaminodiphenylsulfone epoxy composites. J Appl Polym Sci. 2006;100(1):295–8.
Wang C, Wu Q, Liu F, An J, Lu R, Xie H, et al. Synthesis and characterization of soy polyol-based polyurethane nanocomposites reinforced with silylated palygorskite. Appl Clay Sci. 2014;101:246–52.
El-Aasser M, Hu R, Dimonie V, Sperling L. Morphology, design and characterization of IPN-containing structured latex particles for damping applications. Colloids Surf A Physicochem Eng Asp. 1999;153(1):241–53.
Sun Y, Xu K, Zhang Y, Zhang J, Chen R, Yuan Z, et al. Organic montmorillonite reinforced epoxy mortar binders. Constr Build Mater. 2016;107:378–84.
Yin H, Zhang Y, Sun Y, Xu W, Yu D, Xie H, et al. Performance of hot mix epoxy asphalt binder and its concrete. Mater Struct. 2015;48(11):3825–35.
Jiang Y, Liu Y, Gong J, Li C, Xi Z, Cai J, et al. Microstructures, thermal and mechanical properties of epoxy asphalt binder modified by SBS containing various styrene-butadiene structures. Mater Struct. 2018;51(4):86.
Yak S. Advances in interpenetrating polymer networks. In: Klempner D, Frisch KC, editors. Lancaster: Technomic Publishing Company; 1994.
Liu Y, Zhang J, Chen R, Cai J, Xi Z, Xie H. Ethylene vinyl acetate copolymer modified epoxy asphalt binders: phase separation evolution and mechanical properties. Constr Build Mater. 2017;137:55–65.
Pan B, Yue Q, Ren J, Wang H, Jian L, Zhang J, et al. A study on attapulgite reinforced PA6 composites. Polym Test. 2006;25(3):384–91.
Acknowledgements
The authors are grateful for financial supports from Program for the Fundamental Research Funds for the Central Universities (20620140066), Changjiang Scholars and Innovative Research Team in University (IRT1252) and the Priority Academic Program Development of Jiangsu Higher Education Institutions.
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Xu, K., Li, C., Wang, C. et al. Natural and acid-treated attapulgite reinforced soybean oil-based polyurethane/epoxy resin interpenetrating polymer networks. J Therm Anal Calorim 137, 1189–1198 (2019). https://doi.org/10.1007/s10973-019-08033-x
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DOI: https://doi.org/10.1007/s10973-019-08033-x