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Thermodynamic model and Raman spectra of ZnO–P2O5 glasses

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Abstract

Raman spectra of xZnO (100−x)P2O5 (x = 35, 40, 45, 50, 55) glasses were described by the thermodynamic model of Shakhmatkin and Vedishcheva using the method of Malfait. The glasses were considered as the ideal solution of unreacted oxides and four compounds (ZnP2O6, Zn2P2O7, Zn3P2O8, and ZnP2O11). Due to missing thermodynamic data, thermodynamic model was based on the estimates of reaction Gibbs energies of formation of considered compounds obtained by fitting the 31P MAS NMR Q-distribution in ZnO–MoO3–P2O5 glasses. Simultaneously, the set of Raman spectra was analyzed by multivariate curve resolution method. The very good coincidence between the results of spectral decomposition based on the thermodynamic model on one side and on the results of MCR method on the other can be considered as plausible validation of the thermodynamic data used, i.e., as a general guideline for the situations where the thermodynamic data needed for the construction of Shakhmatkin and Vedishcheva thermodynamic model are missing but the detailed structural information is available.

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Acknowledgements

This work was supported by the Slovak Grant Agency for Science under the grant VEGA 1/0006/12 and by the Slovak Research and Development Agency Project ID: APVV-0487-11. This work was also supported by the Grant Agency of the Czech Republic through the Grant No. P108/10/1631.

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Authors and Affiliations

  1. Vitrum Laugaricio – Joint Glass Center of IIC SAS, TnUAD, and FChPT STU, Študentská 2, Trenčín, 91150, Slovakia

    Marek Liška, Magdaléna Lissová, Alfonz Plško & Mária Chromčíková

  2. University of Chemistry and Technology, Technická 5, Prague, 166 28, Czech Republic

    Tadeáš Gavenda & Jan Macháček

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  1. Marek Liška
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  2. Magdaléna Lissová
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  4. Mária Chromčíková
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  5. Tadeáš Gavenda
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  6. Jan Macháček
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Correspondence to Marek Liška.

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Liška, M., Lissová, M., Plško, A. et al. Thermodynamic model and Raman spectra of ZnO–P2O5 glasses. J Therm Anal Calorim 121, 85–91 (2015). https://doi.org/10.1007/s10973-015-4563-7

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  • DOI: https://doi.org/10.1007/s10973-015-4563-7

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