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Interactions of 2,5- and 3,5-dimethylphenols with co-exchanged montmorillonite

Thermal, IR-spectral and X-ray studies

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Abstract

The influence of different steric and electronic properties of 2,5- and 3,5-dimethylphenols (2,5 and 3,5-DMP) on the type of interactions with Cobalt-exchanged montmorillonite (Co-MMT) was studied. The results of X-ray diffraction (XRD), IR-spectroscopy and thermal (TG, DTG) analysis show that phenol derivatives are intercalated into the interlayer space of montmorillonite. Thermal decomposition in the temperature interval 20–700 °C of Co-MMT with 3,5-DMP proceeds in four steps while Co-MMT with 2,5-DMP decompose only in three steps. These differences are connected with different acid–base interactions of individual phenol derivatives in the interlayer space of montmorillonite, which is in agreement with the results of IR-spectroscopy.

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Acknowledgements

We wish to thank the Slovak Grant Agency (project KEGA 002 TnUAD4/2011) for the financial support.

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Authors and Affiliations

  1. Department of Chemical Technologies and Environment, Faculty of Industrial Technologies, University of Trenčín, 020 32, Púchov, Slovakia

    R. Janík, E. Jóna & S. C. Mojumdar

  2. Department of Inorganic Chemistry, Slovak Academy of Sciences, SR-842 36, Bratislava, Slovakia

    V. Pavlík

  3. Department of Industry Design, Faculty of Industrial Technologies, University of Trenčín, 034 01, Ružomberok, Slovakia

    P. Lizák

  4. Department of Chemistry, University of Guelph, Guelph, ON, Canada

    S. C. Mojumdar

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  1. R. Janík
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  2. E. Jóna
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Correspondence to S. C. Mojumdar.

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Janík, R., Jóna, E., Pavlík, V. et al. Interactions of 2,5- and 3,5-dimethylphenols with co-exchanged montmorillonite. J Therm Anal Calorim 112, 1083–1087 (2013). https://doi.org/10.1007/s10973-013-3012-8

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