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Effect of different dimethylphenols on the interactions with Ni2+-exchanged montmorillonite

Thermal, spectral, and diffraction studies

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Abstract

The influence of different steric and electronic properties of 2,4-; 2,5-; and 3,5- dimethylphenols (2,4-; 2,5-; and 3,5- DMP, respectively) on Ni2+-montmorillonite (Ni2+-MMT) (I) were studied. The results of X-ray diffraction show that the observed changes of the basal spacing were due to the intercalation of phenol derivatives into the interlayer space of montmorillonite. The existence of one peak at ~1,633 cm−1 in the IR spectra of sample Ni2+-MMT + 2,4-DMP (II) and Ni2+-MMT + 2,5-DMP (III) and shift of this peaks to higher frequency indicate that 2,4-DMP and 2,5-DMP exist in the interlayer space of Ni2+-MMT in the protonated form. The two bands at ~1,622 and 1,597 cm−1 in the sample Ni2+-MMT + 3,5-DMP (IV) indicate that 3,5-DMP may be also directly coordinated to Ni2+ cations. The different interactions of phenol derivatives in the silicate interlayers will be connected with different position of methyl groups on the phenol ring.

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Authors and Affiliations

  1. Department of Material Technologies and Environment, Faculty of Industrial Technologies, University of Trenčín, I. Krasku 491/30, 020 01, Púchov, Slovak Republic

    R. Janík, E. Jóna, M. Pajtášová, D. Ondrušová, M. Loduhová & S. C. Mojumdar

  2. Department of Inorganic Chemistry, Slovak Academy of Sciences, 842 36, Bratislava, Slovak Republic

    V. Pavlík

  3. University of Sládkovičovo, Fučíkova 269, 925 21, Sládkovičovo, Slovak Republic

    R. Durný

  4. Department of Nuclear Physics and Technology, Faculty of Electrical Engineering and Information Technology, Slovak University of Technology, Ilkovičova 3, 812 1, Bratislava, Slovak Republic

    R. Durný

  5. Department of Chemistry, University of Guelph, Guelph, ON, Canada

    S. C. Mojumdar

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  1. R. Janík
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  2. E. Jóna
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  3. M. Pajtášová
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  4. D. Ondrušová
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  5. M. Loduhová
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  6. V. Pavlík
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Correspondence to S. C. Mojumdar.

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Janík, R., Jóna, E., Pajtášová, M. et al. Effect of different dimethylphenols on the interactions with Ni2+-exchanged montmorillonite. J Therm Anal Calorim 112, 1053–1058 (2013). https://doi.org/10.1007/s10973-013-2990-x

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  • DOI: https://doi.org/10.1007/s10973-013-2990-x

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