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Synthesis, spectral characterization, and thermal behavior of mononuclear Cu(II), Co(II), Ni(II), Mn(II), and Zn(II) complexes with 5-bromosalycilaldehyde isonicotinoylhydrazone

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Abstract

A bidentate/tridentate 5-bromosalycilaldehyde isonicotinoylhydrazone Schiff base was synthesized by condensing 5-bromosalycilaldehyde with isonicotinoylhydrazine. Cu(II), Co(II), Ni(II), Mn(II) and Zn(II) complexes of this chelating ligand were synthesized using nitrates of these metals. The ligand and the complexes were characterized by elemental analysis, UV–Vis, IR and EPR spectroscopy, conductance and magnetic susceptibility measurements, fluorescence, cyclic voltammetry and thermogravimetric analysis. The ligand and Zn(II) complex exhibits solid-state photoluminescence at room temperature.

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Authors and Affiliations

  1. Department of Inorganic Chemistry, Faculty of Chemistry, University of Bucharest, 23 Dumbrava Rosie St., 020464, Bucharest, Romania

    Mariana Loredana Dianu & Angela Kriza

  2. “Ilie Murgulescu” Institute of Physical Chemistry, Romanian Academy, 202 Spl. Independentei, 060021, Bucharest, Romania

    Adina Magdalena Musuc

Authors
  1. Mariana Loredana Dianu
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  2. Angela Kriza
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  3. Adina Magdalena Musuc
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Correspondence to Adina Magdalena Musuc.

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Dianu, M.L., Kriza, A. & Musuc, A.M. Synthesis, spectral characterization, and thermal behavior of mononuclear Cu(II), Co(II), Ni(II), Mn(II), and Zn(II) complexes with 5-bromosalycilaldehyde isonicotinoylhydrazone. J Therm Anal Calorim 112, 585–593 (2013). https://doi.org/10.1007/s10973-012-2578-x

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