Abstract
Sorption of water, n-butanol and n-heptane into different porous copolymers of 1-vinyl-2-pyrrolidone was studied by thermogravimetry. It was shown that differences in interactions of these adsorbates with copolymers of different surface area and polarity can be monitored by this technique. The relative thermodesorption plot was introduced and used to analyze thermogravimetric data.
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Maciejewska M, Gawdzik B. Preparation and porous structure characterization of 4,4′-diphenylmethane dimethacrylate/divinylbenzene polymeric particles. J Appl Polym Sci. 2005;95:863–7.
Gawdzik B, Maciejewska M. Synthesis of isobutyl maleate-divinylbenzene microspheres by different techniques of heterogeneous polymerizations. J Appl Polym Sci. 2004;91:2008–15.
Grochowicz M, Gawdzik B, Bartnicki A. New tetrafunctional monomer 1,3-di(2-hydroxy-3-methacryloyloxypropoxy) benzene in the synthesis of porous microspheres. J Polym Sci A. 2009;47:3190–201.
Grochowicz M, Gawdzik B. Permanently porous copolymeric microspheres based on aromatic methacrylates. React Funct Polym. 2011;71:625–33.
Maciejewska M, Gawdzik J. Preparation and characterization of sorption properties of porous microspheres of 1-vinyl-2-pyrrolidone-divinylbenzene. J Liq Chromatogr Relat Technol. 2008;31:950–61.
Maciejewska M, Osypiuk J, Gawdzik B. Preparation and characterization of the chromatographic properties of ethylene glycol dimethacrylate/divinylbenzene polymeric microspheres. J Polym Sci A. 2005;43:3049–58.
Grochowicz M, Gawdzik B, Bartnicki A. Preparation and characterization of porous polymeric microspheres obtained from multifunctional methacrylate monomers. J Polym Sci A. 2008;46:6165–74.
Araujo A, Jaroniec M. Determination of the surface area and mesopore volume for lanthanide-incorporated MCM materials by using high resolution thermogravimetry. Thermochim Acta. 2000;345:173–7.
Goworek J, Kierys A, Iwan M, Stefaniak W. Sorption on as-synthesized MCM-41. J Therm Anal Calorim. 2007;87:165–9.
Majchrzak-Kucęba I. Thermogravimetry applied to characterization of fly ash-based MCM-41 mesoporous materials. J Therm Anal Calorim. 2012;107:911–21.
Li Z, Jaroniec M. Comparative studies of carbon blacks by thermogravimetry and nitrogen adsorption. J Colloid Interface Sci. 1999;210:200–6.
Lima A, Musumeci A, Liu H-W, Waclawik E, Silva G. Purity evaluation and influence of carbon nanotube on carbon nanotube/graphite thermal stability. J Therm Anal Calorim. 2009;97:257–63.
Sarkar S, Das P. Non-isothermal oxidation kinetics of single- and multi-walled carbon nanotubes up to 1273 K in ambient. J Therm Anal Calorim. 2012;107:1093–103.
Skwarek E, Khalameida S, Janusz W, Sydorchuk V, Konovalova N, Zazigalov V, Skubiszewska-Zięba J, Leboda R. Influence of mechanomechanical activation on structure and some properties of mixed vanadium–molybdenum oxides. J Therm Anal Calorim. 2012;106:881–94.
Trach Y, Sydorchuk V, Makota O, Khalameida S, Leboda R, Skubiszewska-Zięba J, Zazhigalov V. Synthesis, physical and catalytic properties of mixed composition Ag/H3PMo12O40/SiO2. J Therm Anal Calorim. 2012;107:453–61.
Borrachero M, Paya J, Bonilla M, Monzo J. The use of thermogravimetric analysis technique for the characterization of construction materials. The gypsum case. J Therm Anal Calorim. 2008;91:503–9.
Batko K, Voelkel A. Inverse gas chromatography as a tool for investigation of nanomaterials. J Colloid Interface Sci. 2007;315:768–71.
Castello G, Vezzani S, Gardella L. Influence of temperature on the polarity of porous polymer beads stationary phases for gas chromatography. J Chromatogr A. 1999;837:153–70.
Maciejewska M. Characterization of macroporous 1-vinyl-2-pyrrolidone copolymers obtained by suspension polymerization. J Appl Polym Sci. 2012;124:568–75.
Gregg SJ, Sing K. Adsorption, surface area and porosity. London: Academic Press Inc; 1982.
Castello G, D’Amato G. Fast evaluation of the polarity of gas chromatographic columns using the difference in apparent carbon number of linear alkanes and alcohols with the same retention. J Chromatogr A. 1992;623:289–95.
Gawdzik B. Studies on the selectivity of porous polymers based on polyaromatic esters. J Chromatogr. 1990;503:41–9.
Gawdzik B. McReynolds method for stationary phase classification. In: Cazes J, editor. Encyclopedia of chromatography. 3rd ed. London: Taylor & Francis; 2009. p. 1434–8.
Conder JR, Young CL. Physicochemical measurement by gas chromatography. Chichester: Wiley; 1979.
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Maciejewska, M., Osypiuk-Tomasik, J. Studies of sorption properties of porous copolymers of 1-vinyl-2-pyrrolidone. J Therm Anal Calorim 111, 1595–1601 (2013). https://doi.org/10.1007/s10973-012-2509-x
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DOI: https://doi.org/10.1007/s10973-012-2509-x