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Studies of sorption properties of porous copolymers of 1-vinyl-2-pyrrolidone

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Abstract

Sorption of water, n-butanol and n-heptane into different porous copolymers of 1-vinyl-2-pyrrolidone was studied by thermogravimetry. It was shown that differences in interactions of these adsorbates with copolymers of different surface area and polarity can be monitored by this technique. The relative thermodesorption plot was introduced and used to analyze thermogravimetric data.

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References

  1. Maciejewska M, Gawdzik B. Preparation and porous structure characterization of 4,4′-diphenylmethane dimethacrylate/divinylbenzene polymeric particles. J Appl Polym Sci. 2005;95:863–7.

    Article  CAS  Google Scholar 

  2. Gawdzik B, Maciejewska M. Synthesis of isobutyl maleate-divinylbenzene microspheres by different techniques of heterogeneous polymerizations. J Appl Polym Sci. 2004;91:2008–15.

    Article  CAS  Google Scholar 

  3. Grochowicz M, Gawdzik B, Bartnicki A. New tetrafunctional monomer 1,3-di(2-hydroxy-3-methacryloyloxypropoxy) benzene in the synthesis of porous microspheres. J Polym Sci A. 2009;47:3190–201.

    Article  CAS  Google Scholar 

  4. Grochowicz M, Gawdzik B. Permanently porous copolymeric microspheres based on aromatic methacrylates. React Funct Polym. 2011;71:625–33.

    Article  CAS  Google Scholar 

  5. Maciejewska M, Gawdzik J. Preparation and characterization of sorption properties of porous microspheres of 1-vinyl-2-pyrrolidone-divinylbenzene. J Liq Chromatogr Relat Technol. 2008;31:950–61.

    Article  CAS  Google Scholar 

  6. Maciejewska M, Osypiuk J, Gawdzik B. Preparation and characterization of the chromatographic properties of ethylene glycol dimethacrylate/divinylbenzene polymeric microspheres. J Polym Sci A. 2005;43:3049–58.

    Article  CAS  Google Scholar 

  7. Grochowicz M, Gawdzik B, Bartnicki A. Preparation and characterization of porous polymeric microspheres obtained from multifunctional methacrylate monomers. J Polym Sci A. 2008;46:6165–74.

    Article  CAS  Google Scholar 

  8. Araujo A, Jaroniec M. Determination of the surface area and mesopore volume for lanthanide-incorporated MCM materials by using high resolution thermogravimetry. Thermochim Acta. 2000;345:173–7.

    Article  CAS  Google Scholar 

  9. Goworek J, Kierys A, Iwan M, Stefaniak W. Sorption on as-synthesized MCM-41. J Therm Anal Calorim. 2007;87:165–9.

    Article  CAS  Google Scholar 

  10. Majchrzak-Kucęba I. Thermogravimetry applied to characterization of fly ash-based MCM-41 mesoporous materials. J Therm Anal Calorim. 2012;107:911–21.

    Article  Google Scholar 

  11. Li Z, Jaroniec M. Comparative studies of carbon blacks by thermogravimetry and nitrogen adsorption. J Colloid Interface Sci. 1999;210:200–6.

    Article  CAS  Google Scholar 

  12. Lima A, Musumeci A, Liu H-W, Waclawik E, Silva G. Purity evaluation and influence of carbon nanotube on carbon nanotube/graphite thermal stability. J Therm Anal Calorim. 2009;97:257–63.

    Article  CAS  Google Scholar 

  13. Sarkar S, Das P. Non-isothermal oxidation kinetics of single- and multi-walled carbon nanotubes up to 1273 K in ambient. J Therm Anal Calorim. 2012;107:1093–103.

    Article  CAS  Google Scholar 

  14. Skwarek E, Khalameida S, Janusz W, Sydorchuk V, Konovalova N, Zazigalov V, Skubiszewska-Zięba J, Leboda R. Influence of mechanomechanical activation on structure and some properties of mixed vanadium–molybdenum oxides. J Therm Anal Calorim. 2012;106:881–94.

    Article  Google Scholar 

  15. Trach Y, Sydorchuk V, Makota O, Khalameida S, Leboda R, Skubiszewska-Zięba J, Zazhigalov V. Synthesis, physical and catalytic properties of mixed composition Ag/H3PMo12O40/SiO2. J Therm Anal Calorim. 2012;107:453–61.

    Article  CAS  Google Scholar 

  16. Borrachero M, Paya J, Bonilla M, Monzo J. The use of thermogravimetric analysis technique for the characterization of construction materials. The gypsum case. J Therm Anal Calorim. 2008;91:503–9.

    Article  CAS  Google Scholar 

  17. Batko K, Voelkel A. Inverse gas chromatography as a tool for investigation of nanomaterials. J Colloid Interface Sci. 2007;315:768–71.

    Article  CAS  Google Scholar 

  18. Castello G, Vezzani S, Gardella L. Influence of temperature on the polarity of porous polymer beads stationary phases for gas chromatography. J Chromatogr A. 1999;837:153–70.

    Article  CAS  Google Scholar 

  19. Maciejewska M. Characterization of macroporous 1-vinyl-2-pyrrolidone copolymers obtained by suspension polymerization. J Appl Polym Sci. 2012;124:568–75.

    Article  CAS  Google Scholar 

  20. Gregg SJ, Sing K. Adsorption, surface area and porosity. London: Academic Press Inc; 1982.

    Google Scholar 

  21. Castello G, D’Amato G. Fast evaluation of the polarity of gas chromatographic columns using the difference in apparent carbon number of linear alkanes and alcohols with the same retention. J Chromatogr A. 1992;623:289–95.

    Article  CAS  Google Scholar 

  22. Gawdzik B. Studies on the selectivity of porous polymers based on polyaromatic esters. J Chromatogr. 1990;503:41–9.

    Article  CAS  Google Scholar 

  23. Gawdzik B. McReynolds method for stationary phase classification. In: Cazes J, editor. Encyclopedia of chromatography. 3rd ed. London: Taylor & Francis; 2009. p. 1434–8.

    Google Scholar 

  24. Conder JR, Young CL. Physicochemical measurement by gas chromatography. Chichester: Wiley; 1979.

    Google Scholar 

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Maciejewska, M., Osypiuk-Tomasik, J. Studies of sorption properties of porous copolymers of 1-vinyl-2-pyrrolidone. J Therm Anal Calorim 111, 1595–1601 (2013). https://doi.org/10.1007/s10973-012-2509-x

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  • DOI: https://doi.org/10.1007/s10973-012-2509-x

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