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Polymerization behavior and thermal properties of benzoxazine based on 4,4′-diaminodiphenyl ether

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Abstract

The thermally activated ring-opening polymerization behavior of benzoxazine based on 4,4′-diaminodiphenyl ether was investigated by Fourier transform infrared and differential scanning calorimetry, and the thermal properties of the corresponding polybenzoxazine were studied by dynamic mechanical analysis, thermogravimetry-mass spectrometry, and differential thermal analysis. In the ring-opening polymerization reaction, the C–O–C absorption peak of the oxazine ring at 1,054 cm–1 disappeared first, and the C–N–C absorption intensity of the oxazine ring decreased gradually with time rising. The activation energies of the non-isothermal polymerization are 83.4 and 87.4 kJ mol–1 evaluated with Kissinger and Flynn–Wall–Ozawa methods, respectively. Dynamic mechanical analysis shows the glass transition temperature of the resultant polybenzoxazine is 188 °C. In the thermal degradation, the 10 % mass loss temperature of the polybenzoxazine is 353 °C and the char yield is about 48 % at 800 °C in nitrogen, while 415 °C and close to 0 % at 650 °C in air.

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Acknowledgments

This study was financially supported by the Natural Science Foundation of Hebei University (2011YY06).

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Authors and Affiliations

  1. College of Chemistry & Environmental Science, Hebei University, Baoding, 071002, China

    Yanfang Liu, Jian Zhang, Haili Zhang, Huiying Fan & Mingtao Run

  2. Office of Educational Administration, Hebei University, Baoding, 071002, China

    Zhihong Li

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  1. Yanfang Liu
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Correspondence to Yanfang Liu.

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Liu, Y., Li, Z., Zhang, J. et al. Polymerization behavior and thermal properties of benzoxazine based on 4,4′-diaminodiphenyl ether. J Therm Anal Calorim 111, 1523–1530 (2013). https://doi.org/10.1007/s10973-012-2480-6

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  • DOI: https://doi.org/10.1007/s10973-012-2480-6

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