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Thermal properties of oxide glasses

Part IV. Induction period of crystallization as a criterion of thermal stability of M2OSiO2 (M = Li, Na) glass systems against crystallization

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Abstract

A criterion based on the length of induction period of crystallization was used to evaluate the thermal stability of M2O·SiO2 (M = Li, Na) glasses against crystallization. It was founded out that the stability of studied glasses against crystallization is Li2O·SiO2 < Na2O·SiO2. The results coincide with the order determined by stability criteria based on temperatures and the values of activation energy. A criterion based on the length of induction period enables to discriminate among the thermal stabilities of the silicate glass systems.

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Authors and Affiliations

  1. Department of Chemical Technologies and Environment, Faculty of Industrial Technologies, Trenčín University of A. Dubček, SK-020 32, Púchov, Slovakia

    S. Lendvayová, K. Moricová, E. Jóna, M. Loduhová, J. Pagáčová & S. C. Mojumdar

  2. Vitrum Laugaricio – Joint Glass Center of Institute of Inorganic Chemistry SAS, Alexander Dubcek University of Trencin and RONA Lednicke Rovne, Studentska 2, SK-911 50, Trencin, Slovak Republic

    J. Kraxner

  3. Institute of Inorganic Chemistry, Slovak Academy of Scienties, 842 36, Bratislava, Slovakia

    V. Pavlík

  4. Department of Chemistry, University of Guelph, Guelph, ON, Canada

    S. C. Mojumdar

Authors
  1. S. Lendvayová
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  2. K. Moricová
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  3. E. Jóna
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  4. J. Kraxner
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  5. M. Loduhová
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  6. V. Pavlík
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  7. J. Pagáčová
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  8. S. C. Mojumdar
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Correspondence to S. C. Mojumdar.

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Lendvayová, S., Moricová, K., Jóna, E. et al. Thermal properties of oxide glasses. J Therm Anal Calorim 108, 901–904 (2012). https://doi.org/10.1007/s10973-012-2393-4

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  • DOI: https://doi.org/10.1007/s10973-012-2393-4

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