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Synthesis, spectral and thermal studies of Mn(II), Co(II), Ni(II), Cu(II) and Zn(II) complex dyes based on hydroxyquinoline moiety

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Abstract

A series of Mn(II), Co(II), Ni(II), Cu(II) and Zn(II) complexes of azo-compounds containing hydroxyl quinoline moiety have been synthesized and characterized by elemental analysis, molar conductance, magnetic moments, IR, electronic and ESR spectral studies. The results revealed the formation of 1:1 and 1:2 (L:M) complexes. The molar conductance data reveal that the chelates are nonelectrolyte. IR spectra indicate that the azodyes behave as monobasic bidentate or dibasic tetradentate ligands through phenolate or carboxy oxygen, azo N for 1:1 (L:M) complexes beside phenolate oxygen and quinoline N atoms for 1:2 (L:M) complexes. The thermal analyses (TG and DTA) as well as the solid electrical conductivity measurements are also studied. The molecular parameters of the ligands and their metal complexes have been calculated.

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Authors and Affiliations

  1. Chemistry Department, Faculty of Science, Tanta University, Tanta, Egypt

    M. Gaber, G. B. El-Hefnawy, M. A. El-Borai & N. F. Mohamed

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  1. M. Gaber
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  2. G. B. El-Hefnawy
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  3. M. A. El-Borai
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  4. N. F. Mohamed
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Correspondence to M. Gaber.

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Gaber, M., El-Hefnawy, G.B., El-Borai, M.A. et al. Synthesis, spectral and thermal studies of Mn(II), Co(II), Ni(II), Cu(II) and Zn(II) complex dyes based on hydroxyquinoline moiety. J Therm Anal Calorim 109, 1397–1405 (2012). https://doi.org/10.1007/s10973-011-1911-0

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