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Determination of heat capacities and thermodynamic properties of two structurally unrelated but isotypic calcium and manganese(II) 2,6-naphthalene dicarboxylate-based MOFs

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Abstract

Two metal-organic frameworks, Ca(2,6-NDC)(DMF) (1) and Mn3(2,6-NDC)3(DMF)4 (2) (where 2,6-NDC = 2,6-naphthalene dicarboxylate and DMF = N,N′-dimethylformamide) have been solvothermally synthesized under optimized conditions and characterized by X-ray powder diffraction, elemental analysis, FT-IR spectroscopy, and TG analysis. The thermal decomposition characteristics were investigated under air atmosphere from 300 to 1,170 K (for 1) and from 300 to 971 K (for 2). The molar heat capacities were measured from 198 to 548 K (for 1) and from 198 to 448 K (for 2) by temperature modulated differential scanning calorimetry (TMDSC) for the first time. The fundamental thermodynamic parameters such as entropy and enthalpy variations with temperature were calculated based on the experimentally determined molar heat capacities.

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Acknowledgements

The authors gratefully acknowledge the financial support for this work from the National Natural Science Foundation of China (No. 20833009, 51071146, 51071081, 20873148, 20903095, 50901070 and U0734005), the National Basic Research Program (973 program) of China (2010CB631303), IUPAC (Project No. 2008-006-3-100), Dalian Science and Technology Foundation (2009A11GX052) and the State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology (Grant No. KFJJ10-1Z).

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Authors and Affiliations

  1. Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian, 116023, People’s Republic of China

    Chun-Hong Jiang, Li-Fang Song, Cheng-Li Jiao, Jian Zhang, Li-Xian Sun, Huan-Zhi Zhang & Qing-Yang Xu

  2. Graduate School of the Chinese Academy of Sciences, Beijing, 100049, People’s Republic of China

    Chun-Hong Jiang, Li-Fang Song & Cheng-Li Jiao

  3. Faculty of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, 116029, People’s Republic of China

    Fen Xu

  4. Université de Haute Alsace, ENSCMu, Lab. LPI-GSEC, 3, Rue A. Werner, 68094, Mulhouse Cedex, France

    Zelimir Gabelica

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  1. Chun-Hong Jiang
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  2. Li-Fang Song
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  3. Cheng-Li Jiao
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  4. Jian Zhang
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Correspondence to Li-Xian Sun or Fen Xu.

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Jiang, CH., Song, LF., Jiao, CL. et al. Determination of heat capacities and thermodynamic properties of two structurally unrelated but isotypic calcium and manganese(II) 2,6-naphthalene dicarboxylate-based MOFs. J Therm Anal Calorim 103, 1095–1103 (2011). https://doi.org/10.1007/s10973-010-1197-7

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  • DOI: https://doi.org/10.1007/s10973-010-1197-7

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