Skip to main content
Log in

Thermodynamic optimization of the Yb–Sn system

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

The thermodynamic optimization of the Yb–Sn binary system was carried out with the help of the CALPHAD (CALculation of PHAse Diagram) method. Yb2Sn, α-βYb5Sn3, Yb5Sn4, YbSn, Yb3Sn5, and YbSn3 have been treated as stoichiometric compounds, while a sublattice model has been used for the description of the liquid, BCC, BCT, and FCC phases. The calculations based on the thermodynamic modeling are in good agreement with the phase diagram data and experimental thermodynamic values.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. Idbenali M, Servant C, Selhaoui N, Bouirden L. A thermodynamic reassessment of the La_Sn system. Calphad. 2009;33:398–404.

    Article  CAS  Google Scholar 

  2. Kaufman L, Bernstein H. Computer calculations of phase diagrams. New York, NY: Academic Press; 1970.

    Google Scholar 

  3. Palenzona A, Cirafici S. The Sn–Yb (Tin–Ytterbium) system. J Phase Equilib. 1991;12:482–5.

    Article  CAS  Google Scholar 

  4. Palenzona A, Cirafici S. The ytterbium–tin system. J Less Common Met. 1976;46:321–6.

    Article  CAS  Google Scholar 

  5. Manfrinetti P, Mazzone D, Palenzona A. An up-dating of the Yb–Sn phase diagram. J Alloys Compd. 1999;284:L1–3.

    Article  CAS  Google Scholar 

  6. Leon-Escamilla EA, Corbett JD. Solid state compounds with tin–tin bonding. Yb36Sn23: a novel compound containing oligomeric tin anions. Inorg Chem. 1999;38:738–43.

    Article  CAS  Google Scholar 

  7. Alejandro A, Leon-Escamilla EA, Corbett JD. Hydrogen impurity effects. A5Tt3Z intermetallic compounds between A = Ca, Sr, Ba, Eu, Yb and Tt = Sn, Pb with Cr5B3-like structures that are stabilized by hydride or fluoride (Z). Inorg Chem. 2001;40:1226–33.

    Article  Google Scholar 

  8. Palenzona A. Dynamic differential calorimetry of intermetallic compounds I. Heat of formation, heat and entropy of fusion of rare earth–tin compounds. Thermochim Acta. 1973;5:473–80.

    Article  CAS  Google Scholar 

  9. Chatillon-Colinet C, Percheron A, Mathieu J-C, Achard J-C. Calorimetric measurements of the heat of solution of ytterbium in tin. determination of the heat of formation of YbSn3 phase. Compte Rend C. 1970;270:473–6.

    CAS  Google Scholar 

  10. Witusiewicz VT, Sidorko VR, Bulanova MV. Assessment of thermodynamic functions of formation for rare earth silicides, germanides, stannides and plumbides. J Alloys Compd. 1997;248:233–45.

    Article  CAS  Google Scholar 

  11. Dinsdale AT. SGTE data for pure elements. Calphad. 1991;15:317–425.

    Article  CAS  Google Scholar 

  12. Redlich O, Kister A. Algebraic representation of thermodynamic properties and the classification of solutions. Ind Eng Chem. 1948;40:345–8.

    Article  Google Scholar 

  13. Sundman B, Jansson B, Andersson JO. The Thermo-Calc databank system. Calphad. 1985;9:153–90.

    Article  CAS  Google Scholar 

  14. Jansson B. Evaluation of parameters in thermodynamic models using different types of experimental data simultaneously. Thesis, Stockholm: Royal Institute of Technology; 1984.

  15. Arroyave R, Liu ZK. Thermodynamic modelling of the Zn–Zr system. Calphad. 2006;30:1–13.

    Article  CAS  Google Scholar 

  16. Kumar KC, Wollants P. Some guidelines for thermodynamic optimisation of phase diagrams. J Alloys Compd. 2001;320:189–98.

    Article  Google Scholar 

  17. Chen SL, Daniel S, Zhang F, Chang YA, Oates WA, Schmid-Fetzer R. On the calculation of multicomponent stable phase diagrams. J Phase Equilib. 2001;22:373–8.

    Article  CAS  Google Scholar 

  18. Stein F, Palm M, Sauthoff G. Structure and stability of Laves phases part II—structure type variations in binary and ternary system. Intermetallics. 2005;13:1056–74.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Mohamed Idbenali.

Additional information

It was presented at JEEP2010 Montpellier, France

Rights and permissions

Reprints and permissions

About this article

Cite this article

Idbenali, M., Servant, C. Thermodynamic optimization of the Yb–Sn system. J Therm Anal Calorim 103, 131–135 (2011). https://doi.org/10.1007/s10973-010-1082-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10973-010-1082-4

Keywords

Navigation