Abstract
In the search for new intermetallic materials with high thermoelectric performances, the Co–Sb–S ternary system has been explored and polycrystalline CoSbS samples have been prepared by a vapour phase technique starting from the pure elements. The crystal cell of CoSbS belongs to the Pbca space group and shows an orthorhombic structural arrangement with the following lattice parameters: a = 5.8341(2) Å; b = 5.9477(2) Å, and c = 11.6540(4) Å. The structure belongs to the pyrite–marcasite family, as Co forms tilted corner- and edge-sharing octahedra with three Sb and three S atoms. Scanning electronic microscopy (SEM), electron-probe microanalysis (EPMA) and X-ray powder diffraction were used to investigate the microstructure and to carry out the structural analysis; the crystal structure was refined by the Rietveld method using the DBWS-9807 program. The thermal stability of CoSbS was investigated referring to the ternary Co–S–Sb phase diagram and by differential thermal analysis (DTA) measurements. Thermoelectric power measurements at room temperature were also performed by a home-made instrument.
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Snyder GJ, Toberer ES. Complex thermoelectric materials. Nat Mater. 2008;7:105–14.
Kawaharada Y, Kurosaki K, Uno M, Yamanaka S. Thermoelectric properties of CoSb3. J Alloys Compd. 2001;315:193–7.
Zhang JX, Lu QM, Liu KG, Zhang L, Zhou ML. Synthesis and thermoelectric properties of CoSb3 compounds by spark plasma sintering. Mater Lett. 2004;58:1981–4.
Furuyama S, Iida T, Matsui S, Akasaka M, Nishio K, Takanashi Y. Thermoelectric properties of undoped p-type CoSb3 prepared by vertical Bridgman crystal growth and spark plasma sintering. J Alloys Compd. 2006;415:251–6.
Nakamoto G, Yoshida Y, Vu LV, Huong NT, Anh DTK, Kurisu M. Effect of segregated impurity phases on lattice thermal conductivity in Y-added CoSb3. Scr Mater. 2007;56:269–72.
Jiang YP, Jia XP, Su TC, Dong N, Yu FR, Tian YJ, Guo W, Xu HW, Deng L, Ma HA. Thermoelectric properties of Sm x Co4Sb12 prepared by high pressure and high temperature. J Alloys Compd. 2010;493:535–8.
Mi JL, Zhao XB, Zhu TJ, Tu JP. Nanosized La filled CoSb3 prepared by a solvothermal-annealing method. Mater Lett. 2008;62:2363–5.
Wojciechowski KT. Effect of tellurium doping on the thermoelectric properties of CoSb3. Mater Res Bull. 2002;37:2023–33.
Chitroub M, Besse F, Scherrer H. Thermoelectric properties of semi-conducting compound CoSb3 doped with Pd and Te. J Alloys Compd. 2009;467:31–4.
Kim I-H, Park K-H, Ur S-C. Thermoelectric properties of Sn-doped CoSb3 prepared by encapsulated induction melting. J Alloys Compd. 2007;442:351–4.
Wojciechowski KT, Tobola J, Leszczyński J. Thermoelectric properties and electronic structure of CoSb doped with Se and Te. J Alloys Compd. 2003;361:19–27.
Kim IH, Ur SC. Electronic transport properties of Fe-doped CoSb3 prepared by encapsulated induction melting. Mater Lett. 2007;61:2446–50.
Kitagawa H, Wakatsuki M, Nagaoka H, Noguchi H, Isoda Y, Hasezaki K, Noda Y. Temperature dependence of thermoelectric properties of Ni-doped CoSb3. J Phys Chem Solids. 2005;66:1635–9.
Al-Ghamdi AA. Thermoelectric power (TEP) of layered chalcogenides GaTe crystals. J Therm Anal Calorim. 2008;94:597–600.
Vaqueiro P, Sobany GG, Stindl M. Structure and electrical transport properties of the ordered skutterudites MGe1.5S1.5 (M = Co, Rh, Ir). J Solid State Chem. 2008;181:768–76.
Bos JWG, Cava RJ. Synthesis, crystal structure and thermoelectric properties of IrSn1.5Te1.5-based skutterudites. Solid State Commun. 2007;141:38–41.
Laufek F, Navrátil, Plášil J, Plecháček T. Crystal structure determination of CoGeTe from powder diffraction data. J Alloys Compd. 2008;460:155–9.
Vaqueiro P, Sobany GG, Guinet F, Leyva-Bailen P. Synthesis and characterization of the anion-ordered tellurides MGeTe. Solid State Sci. 2009;11:1077–82.
Schenck R, Von der Forst P. Gleichgewichtsstudien and erzbildenden Sulfiden III. Z Anorg Allg Chem. 1942;249:76–87.
Allazov MR, Gulieva ZT. Physicochemical interaction in the CoS–Sb and NiS–Sb systems. Russ J Inorg Chem. 1988;33:1075–8.
Young RA, Sakthiel A, Moss TS, Paiva-Santos CO. DBWS-9411, an upgrade of the DBWS*.* programs for Rietveld refinement with PC and mainframe computers. J Appl Cryst. 1995;28:366–7.
Uher C. Skutterudite-based thermoelectrics. In: Rowe DM, editor. Thermoelectrics handbook. Boca Raton: Taylor & Francis; 2006. p. 34-1–17.
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The authors gratefully acknowledge Dr. D. Macciò for his helpful contribution with DTA measurements.
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Carlini, R., Artini, C., Borzone, G. et al. Synthesis and characterisation of the compound CoSbS. J Therm Anal Calorim 103, 23–27 (2011). https://doi.org/10.1007/s10973-010-1034-z
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DOI: https://doi.org/10.1007/s10973-010-1034-z