Skip to main content
Log in

The effect of thermal stability of carbon nanotubes on the flame retardancy of epoxy and bismaleimide/carbon fiber/buckypaper composites

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

Single-walled carbon nanotube (SWCNT) and multi-walled carbon nanotube (MWCNT) membranes (buckypaper) were incorporated onto the surface of epoxy and bismaleimide (BMI) carbon fiber composites. Their flammability behaviors were investigated by a cone calorimeter. The composites with buckypaper reduced the heat release rate (HRR) by more than 60% peak and smoke generation by 50% during combustion. The effects of different buckypaper on the flame retardancy of epoxy and BMI were compared and discussed. Our research team found that buckypapers acted as an effective flame-retardant shield to dramatically reduce the fire hazards of composites if they survived during fire combustion. Thermogravimetric analyses was used to compare the thermo-oxidation stability of the resins and buckypapers to explain the different effects of SWCNT and MWCNT buckypaper on flammability of epoxy and BMI carbon fiber composites.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. Beyer G. Carbon nanotubes as flame retardants for polymers. Fire Mater. 2002;26:291–3.

    Article  CAS  Google Scholar 

  2. Kashiwagi T, Du F, Douglas JF, Winey KI, Harris RH, Shields JR. Nanoparticle networks reduced the flammability of polymer nanocomposites. Nat Mater. 2005;4:928–33.

    Article  CAS  Google Scholar 

  3. Kashiwagi T, Du F, Winey KI, Groth KM, Shields JR, Bellayer SP, et al. Thermal and flammability properties of polypropylene/carbon nanotube nanocomposites. Polymer. 2005;46:471–81.

    Article  CAS  Google Scholar 

  4. Cipiriano BH, Kashiwagi T, Raghavan SR, Yang Y, Grulke EA, Yamamoto K, Shields JR, Douglas JF. Effects of aspect ratio of MWNT on the flammability properties of polymer nanocomposites. Polymer. 2007;48:6086–96.

    Article  CAS  Google Scholar 

  5. Kashiwagi T, Mu M, Winey K, Cipriano B, Raghavan SR, Pack S, Rafailovich M, Yang Y, Grulke E, Shields J, Harris R, Douglas J. Relation between the viscoelastic and flammability properties of polymer nanocomposites. Polymer. 2008;49:4358–68.

    Article  CAS  Google Scholar 

  6. Wu Q, Zhu W, Zhang C, Liang ZY, Wang B. Study of fire resistance of carbon nanotube membranes and carbon nanofiber paper in carbon fiber reinforced epoxy composites. Carbon. 2008;48:1799–806.

    Article  Google Scholar 

  7. Wu Q, Zhang C, Liang ZY, Wang B. Fire retardancy of a buckypaper membrane. Carbon. 2008;46:1164–5.

    Article  CAS  Google Scholar 

  8. Pang LSK, Saxby JD, Chatfield SP. Thermogravimetric analysis of carbon nanotubes and nanoparticles. J Phys Chem B. 1993;97:6941–2.

    Article  CAS  Google Scholar 

  9. Musumeci AW, Silva GG, Martens WN, Waclawik ER, Frost RL. Thermal decomposition and electron microscopy studies of single-walled carbon nanotubes. J Therm Anal Calorim. 2007;88:885–91.

    Article  CAS  Google Scholar 

  10. Lima AMF, Musumeci AW, Liu HW, Silva GG, Waclawik ER. Purity evaluation and influence of carbon nanotube on carbon nanotube/graphite thermal stability. J Therm Anal Calorim. 2009;97:257–63.

    Article  CAS  Google Scholar 

  11. Wang Z, Liang Z, Wang B, Zhang C, Kramer L. Processing and property investigation of single-walled carbon nanotube (SWNT) buckypaper/epoxy resin matrix nanocomposites. Compos A. 2004;5:1225–32.

    Article  Google Scholar 

  12. Laoutid F, Bonnaud L, Alexandre M. New prospects in flame retardant polymer materials: From fundamentals to nanocomposites. Mater Sci Eng. 2009;63(3):100–25.

    Article  Google Scholar 

  13. Schartel B, Bartholmai M, Knoll U. Some comments on the use of cone calorimeter data. Polym Degrad Stab. 2005;88(3):540–7.

    Article  CAS  Google Scholar 

  14. Cooper SM. Gas permeability of a buckypaper membrane. Nano Lett. 2003;3:189–92.

    Article  CAS  Google Scholar 

  15. Smajda R, Kukovecz A, Konya Z, Kiricsi I. Structure and gas permeability of multi-wall carbon nanotube buckypapers. Carbon. 2007;45(6):1176–84.

    Article  CAS  Google Scholar 

  16. Arepalli S, Nikolaev P, Gorelik O, Hadjiev VG, Holmes W, Files B, Yowell L. Protocol for the characterization of single-wall carbon nanotube material quality. Carbon. 2004;42(8–9):1783–91.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Qiang Wu.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Wu, Q., Bao, J., Zhang, C. et al. The effect of thermal stability of carbon nanotubes on the flame retardancy of epoxy and bismaleimide/carbon fiber/buckypaper composites. J Therm Anal Calorim 103, 237–242 (2011). https://doi.org/10.1007/s10973-010-0960-0

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10973-010-0960-0

Keywords

Navigation