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Solvent effects on solution enthalpies of adamantyl derivatives

A multiparametric approach

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Abstract

Solution enthalpies of 1-bromoadamantane, 1-adamantanol, and 2-adamantanone in a large set of protic and aprotic solvents are reported at 298.15 K. Solvent effects on the solution processes of these solutes are analyzed in terms of a modified TAKA equation, involving δcav h s as the cavity term. The nature and magnitude of the major interactions which influence these processes are assessed and discussed in terms of the solutes’ characteristics. New insights on the solution processes under scrutiny are presented.

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Authors and Affiliations

  1. Department of Chemistry and Biochemistry, Faculty of Sciences, University of Lisbon, CQB, Ed. C8, Campo Grande, 1749-016, Lisbon, Portugal

    Filomena Martins & Luís Moreira

  2. Instituto Superior de Educação e Ciências, CQB, Alameda das Linhas de Torres, 174, 1750, Lisbon, Portugal

    Luís Moreira

  3. Department of Chemical Engineering, Engineering Institute (ISEL), Polytechnic Institute of Lisbon, CQB, R. Conselheiro Emídio Navarro 1, 1950-062, Lisbon, Portugal

    Nélson Nunes & Ruben E. Leitão

Authors
  1. Filomena Martins
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  2. Luís Moreira
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  3. Nélson Nunes
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  4. Ruben E. Leitão
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Correspondence to Filomena Martins or Ruben E. Leitão.

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Martins, F., Moreira, L., Nunes, N. et al. Solvent effects on solution enthalpies of adamantyl derivatives. J Therm Anal Calorim 100, 483–491 (2010). https://doi.org/10.1007/s10973-009-0651-x

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  • DOI: https://doi.org/10.1007/s10973-009-0651-x

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