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Thermal behaviour of tin(II/IV) phosphates prepared by various methods

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Abstract

Tin(II/IV) phosphate was prepared by various synthetic methods. The different methods resulted in tin phosphate with different properties, i.e., different crystalline form and behaviour during thermal treatment. The prepared materials have 3 mol water of crystallisation, which they lose in different ways. Total mass loss was between 20 and 30%. This could be connected with water loss, going generally in two steps in parallel with endothermic processes. At the end of thermal treatment, tin pyrophosphate is obtained, irrespective of the method of preparation used.

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Acknowledgements

The authors are grateful to Zs. Révay for performing the prompt gamma-activation analysis.

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Authors and Affiliations

  1. Institute of Isotopes of the Hungarian Academy of Sciences, P.O. Box 77, 1525, Budapest, Hungary

    L. Szirtes & J. Megyeri

  2. Laboratory of Nuclear Chemistry, CRC of the Hungarian Academy of Sciences at Eötvös University, P.O. Box 32, 1518, Budapest, Hungary

    E. Kuzmann

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  1. L. Szirtes
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  2. J. Megyeri
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  3. E. Kuzmann
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Correspondence to L. Szirtes.

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Szirtes, L., Megyeri, J. & Kuzmann, E. Thermal behaviour of tin(II/IV) phosphates prepared by various methods. J Therm Anal Calorim 99, 415–421 (2010). https://doi.org/10.1007/s10973-009-0461-1

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  • DOI: https://doi.org/10.1007/s10973-009-0461-1

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