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Synthesis of mesoporous silicas inside large pores of inorganic matrix

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Abstract

Template syntheses of mesoporous silicas have been carried out inside large pores of inorganic matrix. Portions of tetraethoxysilane and cetyltrimethylammonium bromide micellar solution were incorporated step-by-step inside pore volume of silica gel with large pore size. Synthesized materials were characterized using thermal analysis, adsorption-desorption of nitrogen and X-ray diffraction scattering.

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References

  1. P. Van Der Voort, M. Baltes and E. F. Vansant, Catal. Today, 68 (2001) 121.

    Google Scholar 

  2. S. Kawi and S.-C. Shen, Mater. Lett., 42 (2000) 108.

    Article  CAS  Google Scholar 

  3. S. Jun, J. M. Kim, R. Ryoo, Y.-S. Ahn and M.-K. Han, Micropor. Mesopor. Mater., 41 (2000) 119.

    Article  CAS  Google Scholar 

  4. R. Mokaya, J. Phys. Chem., B 103 (1999) 10204.

    Article  CAS  Google Scholar 

  5. J. Goworek, W. Stefaniak, A. Kierys and M. Iwan, J. Therm. Anal. Cal., 87 (2007) 217.

    Article  CAS  Google Scholar 

  6. A. Braileanu, M. Raileanu, M. Crisan, D. Crisan, R. Birjega, V. E. Marinescu, J. Madarász and G. Pokol, J. Therm. Anal. Cal., 88 (2007) 163.

    Article  CAS  Google Scholar 

  7. R. Mokaya and W. Jones, Chem. Commun., (1998) 1839.

  8. S.-C. Shen and S. Kawi, J. Phys. Chem., B 103 (1999) 8870.

    Article  CAS  Google Scholar 

  9. S. D’arbonneau, A. Tuel and A. Auroux, J. Therm. Anal. Cal., 56 (1999) 287.

    Article  CAS  Google Scholar 

  10. E. Molnár, Z. Konya and I. Kiricsi, J. Therm. Anal. Cal., 79 (2005) 573.

    Article  Google Scholar 

  11. P. T. Tanev and T. J. Pinnavaia, Chem. Mater., 8 (1996) 2068.

    Article  CAS  Google Scholar 

  12. M. Kruk, M. Jaroniec, C. H. Ko and R. Ryoo, Chem. Mater., 12 (2000) 1961.

    Article  CAS  Google Scholar 

  13. P. E. A. De Moor, T. P. M. Beelen and A. van Santen, J. Phys. Chem., B 103 (1999) 36.

    Article  Google Scholar 

  14. A. Firouzi, F. Atef, A. G. Oertli, G. D. Stucky and D. F. Chmelka, J. Am. Chem. Soc., 119 (1997) 3596.

    Article  CAS  Google Scholar 

  15. Y. Liu, W. Zhang and T. J. Pinnavaia, J. Am. Chem. Soc., 122 (2000) 8791.

    Article  CAS  Google Scholar 

  16. Z. Zhang, Y. Han and F.-S. Xiao, J. Am. Chem. Soc., 123 (2001) 5014.

    Article  CAS  Google Scholar 

  17. D. T. On and S. Kaliaguine, Angew. Chem. Int. Sd., 41 (2002) 1036.

    Article  CAS  Google Scholar 

  18. X. Wang, W. Li, G. Zhu, S. Qiu, D. Zhao and B. Zhong, Micropor. Mesopor. Mater., 71 (2004) 87.

    Article  CAS  Google Scholar 

  19. S. J. Gregg and K. S. W. Sing, Academic Press, London 1967, p. 303.

  20. M. Hakuman and H. Naono, J. Colloid Interface Sci., 241 (2001) 127.

    Article  CAS  Google Scholar 

  21. M. Jaroniec and M. Kruk, Langmuir, 15 (1999) 5410.

    Article  CAS  Google Scholar 

  22. C. T. Kresge, M. E. Leonowicz, W. J. Roth, J. C. Vartuli and J. S. Beck, Nature, 359 (1992) 710.

    Article  CAS  Google Scholar 

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Correspondence to I. S. Berezovska.

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Berezovska, I.S., Yanishpolskii, V.V. & Tertykh, V.A. Synthesis of mesoporous silicas inside large pores of inorganic matrix. J Therm Anal Calorim 94, 649–653 (2008). https://doi.org/10.1007/s10973-008-9361-z

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  • DOI: https://doi.org/10.1007/s10973-008-9361-z

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