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Synthesis, crystal structure, and thermal decomposition kinetics of complex [Nd(BA)3bipy]2

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Abstract

The complex of [Nd(BA)3bipy]2 (BA = benzoic acid; bipy = 2,2′-bipyridine) has been synthesized and characterized by elemental analysis, IR spectra, single crystal X-ray diffraction, and TG/DTG techniques. The crystal is monoclinic with space group P2(1)/n. The two–eight coordinated Nd3+ ions are linked together by four bridged BA ligands and each Nd3+ ion is further bonded to one chelated bidentate BA ligand and one 2,2′-bipyridine molecule. The thermal decomposition process of the title complex was discussed by TG/DTG and IR techniques. The non-isothermal kinetics was investigated by using double equal-double step method. The kinetic equation for the first stage can be expressed as dα/dt = A exp(−E/RT)(1 − α). The thermodynamic parameters (ΔH ≠, ΔG ≠, and ΔS ≠) and kinetic parameters (activation energy E and pre-exponential factor A) were also calculated.

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References

  1. Li X, Zhang ZY, Zou YQ. Synthesis, structure and luminescence properties of four novel terbium 2-fluorobenzoate complexes. Eur J Inorg Chem. 2005; 2909–918.

  2. Song YS, Yan B, Weng LH. Four distinctive 1-D lanthanide carboxylate coordination polymers: synthesis, crystal structures and spectral properties. Polyhedron. 2007;26:4591–601.

    Article  CAS  Google Scholar 

  3. Huang Y, Yan B, Shao M. Synthesis, crystal structure and photoluminescent properties of four lanthanide 5-nitroisophthalate coordination polymers. J Solid State Chem. 2009;182:657–68.

    Article  CAS  Google Scholar 

  4. Zhao LY, Chen YP, Zhang HH, Li CY, Sun RQ, Yang QY. Study of structure and two-dimension correlation infrared spectroscopy on three rare-earth/3-methylbenzoic acid complexes. J Mol Struct. 2009;920:441–9.

    Article  CAS  Google Scholar 

  5. Deng H, Cai YP, Chao H. Synthesis, characterization and crystal structures of lanthanide phenoxyacetate complexes with 1, 10-phenanthroline. Chin J Inorg Chem. 2003;21:409–14.

    CAS  Google Scholar 

  6. Thompson L, Legendziewicz J, Cybinska J, Li P, Brennessel W. Structure, photophysics and magnetism of a europium mixed complex Eu(HFAA)3bipy·H2O in the solid state and solution. J Alloy Compd. 2002;341:312–22.

    Article  CAS  Google Scholar 

  7. Yang YT, Zhan SY. Study of lanthanide complexes with salicylic acid by photoacoustic and fluorescence spectroscopy. Spectrochim Acta A. 2004;60:2065–9.

    Article  Google Scholar 

  8. Huang CH. Coordination chemistry of rare earths. Beijing: Science Press; 1997. p. 378–87.

    Google Scholar 

  9. Zhang HY, Ren N, Tian L, Zhang JJ. Thermal decomposition reaction kinetics of complexes of [Sm(o-MOBA)3bipy]2·H2O and [Sm(m-MOBA)3bipy]2·H2O. J Therm Anal Calorim. doi:10.1007/s10973-009-0304-0.

  10. Ren N, Zhang JJ, Wang RF. Synthesis, crystal structure and thermal decomposition process of complex [Sm(BA)3phen]2. J Chil Chem Soc. 2006;53:293–8.

    Article  CAS  Google Scholar 

  11. Ren N, Zhang JJ, Guo YH, Sun MQ, Xu SL, Zhang HY. Non-isothermal decomposition kinetics of complexes [Sm(m-MBA)3phen]2 and [Sm(o-MOBA)3phen]2·2H2O. Chem Res Chin U. 2007;23:489–92.

    Article  CAS  Google Scholar 

  12. Ionashiro EY, Bannach G, Siqueira AB, deCarvalho CT, Rodrigues EC, Ionashiro M. 2-Methoxybenzylidenepyruvate with heavier trivalent lanthanides and yttrium(III) synthesis and characterization. J Therm Anal Calorim. 2008;92:953–9.

    Article  CAS  Google Scholar 

  13. Zhang JJ, Xu SL, Ren N, Zhang HY, Tian L. Preparation and thermal decomposition reaction kinetics of a dysprosium(iii) p-chlorobenzoate 1, 10-phenanthroline complex. Int J Chem Kinet. 2008;40:66–72.

    Article  CAS  Google Scholar 

  14. Ferenc W, Dziewulska-Kuaczkowska A, Sarzyski J, Paszkowska B. 4-Chloro-2-methoxybenzoates of heavy lanthanides(III) and yttrium(III) thermal spectral and magnetic behaviour. J Therm Anal Calorim. 2008;91:285–92.

    Article  CAS  Google Scholar 

  15. Zhang JJ, Ren N, Bai JH, Xu SL. Synthesis and thermal decomposition reaction kinetics of complexes of [Sm2(m-ClBA)6(phen)2]·2H2O and [Sm2(m-BrBA)6(phen)2]·2H2O. Int J Chem Kinet. 2007;39:67–74.

    Article  Google Scholar 

  16. Locatelli JR, Rodrigues EC, Siqueira AB, Ionashiro EY, Bannach G, Ionashiro M, et al. Synthesis, characterization and thermal behaviour of solid-state compounds of yttrium and lanthanide benzoates. J Therm Anal Calorim. 2007;90(3):737–46.

    Article  CAS  Google Scholar 

  17. Xu XL, Zhang JJ, Yang HF, Ren N, Zhang HY. Synthesis, crystal structure and thermal decomposition of a dysprosium(III) p-fluorobenzoate 1, 10-phenanthroline complex. J Chem Sci. 2007;62b:51–4.

    Google Scholar 

  18. Zhang HY, Zhang JJ, Ren N, Xu SL, Tian L, Bai JH. Synthesis, crystal structure and thermal decomposition mechanism of the complex [Sm(p-BrBA)3bipy·H2O]2·H2O. J Alloy Compd. 2008;464:277–81.

    Article  CAS  Google Scholar 

  19. Tian L, Ren N, Zhang JJ, Liu HM, Bai JH, Ye HM, et al. Synthesis, crystal structure luminescence and thermal decomposition kinetics of Eu(III) complex with 2, 4-dichlorobenzoic acid and 2, 2′-bipyridine. Inorg Chim Acta. 2009;362:3388–94.

    Article  CAS  Google Scholar 

  20. Zhang JJ, Ren N. A new kinetic method of processing TA data. Chin J Chem. 2004;22:1459–62.

    Article  CAS  Google Scholar 

  21. Shi YZ, Sun XZ, Jiang YH. Spectra and chemical identification of organic compounds. Nanjing: Science and Technology Press; 1988. p. 98.

    Google Scholar 

  22. Xu CJ, Xie F, Guo XZ, Yang H. Synthesis and cofluorescence of Eu(Y) complexes with salicylic acid and o-phenanthroline. Spectrochim Acta A. 2005;61:2005–8.

    Article  Google Scholar 

  23. Wang RF, Jin LP, Wang MZ, Huang SH, Chen XT. Synthesis, crystal structure and luminescence of coordination compound of europium p-methylbenzoate with 2, 2′-dipyridine. Acta Chimi Sinica. 1995;53:39–45.

    Article  CAS  Google Scholar 

  24. Zhang HY, Wu KZ, Zhang JJ. Synthesis, crystal structure and thermal decomposition kinetics of the complex [Sm(BA)3bipy]2. Synth Met. 2008;158:157–64.

    Article  CAS  Google Scholar 

  25. Tian L, Ren N, Zhang JJ, Sun SJ, Ye HM, Bai JH, et al. Synthesis, crystal structure, and thermal decomposition kinetics of the complex of dysprosium benzoate with 2, 2′-bipyridine. J Chem Eng Data. 2009;54:69–74.

    Article  CAS  Google Scholar 

  26. Zhang Y, Jin LP, Lŭ SZ. Crystal structure and luminescence of [Eu2(BA)6(bipy)2]. J Inorg Chem (in Chinese). 1997;13:280–7.

    CAS  Google Scholar 

  27. Lam AWH, Wong WT, Gao S, Wen GH, Zhang XX. Synthesis, crystal structure, and photophysical and magnetic properties of dimeric and polymeric lanthanide complexes with benzoic acid and its derivatives. Eur J Inorg Chem. 2003; 149–63.

  28. Vyazovkin S, Dollimore D. Linear and nonlinear procedures in isoconversional computations of the activation energy of nonisothermal reactions in solids. J Chem Inf Comput Sci. 1996;36:42–5.

    Article  CAS  Google Scholar 

  29. Lu ZR, Ding YC, Xu Y, Li BL, Zhang Y. TA Study on four-one-dimensional chain copper complexes with benzoylacetone or 1, 1, 1-trifluoro-3-(2-thenoyl)-acetone bridged through azobispyridine ligands. J Inorg Chem (in Chinese). 2005;21:181–5.

    Google Scholar 

  30. Gao Z, Nakada M, Amasski I. A consideration of errors and accuracy in the isoconversional methods. Thermochim Acta. 2001;369:137–42.

    Article  CAS  Google Scholar 

  31. Hu RZ, Gao SL, Zhao FQ, Shi QZ, Zhang TL, Zhang JJ. Thermal analysis kinetics. 2nd ed. Beijing: Science Press; 2008. p. 151.

    Google Scholar 

  32. Straszko J, Olstak-Humienik M, Mozejko J. Kinetics of thermal decomposition of ZnSO4·7H2O. Thermochim Acta. 1997;292:145–50.

    Article  CAS  Google Scholar 

  33. Olstak-Humienik M, Mozejko J. Thermodynamic functions of activated complexes created in thermal decomposition processes of sulphates. Thermochim Acta. 2000;344:73–9.

    Article  Google Scholar 

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Acknowledgements

This project was supported by the National Natural Science Foundation of China (No. 20773034) and the Natural Science Foundation of Hebei Province (No. B2007000237).

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Authors and Affiliations

  1. Experimental Center, Hebei Normal University, Shijiazhuang, 050016, People’s Republic of China

    H. M. Ye, J. J. Zhang, S. J. Sun & L. Tian

  2. College of Chemistry and Material Science, Hebei Normal University, Shijiazhuang, 050016, People’s Republic of China

    H. M. Ye, S. J. Sun & L. Tian

  3. Department of Chemistry, Handan College, Handan, 056005, People’s Republic of China

    N. Ren

  4. Shijiazhuang College, Shijiazhuang, 050035, People’s Republic of China

    H. Li

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  1. H. M. Ye
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Correspondence to J. J. Zhang.

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Ye, H.M., Ren, N., Li, H. et al. Synthesis, crystal structure, and thermal decomposition kinetics of complex [Nd(BA)3bipy]2 . J Therm Anal Calorim 101, 205–211 (2010). https://doi.org/10.1007/s10973-009-0428-2

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  • DOI: https://doi.org/10.1007/s10973-009-0428-2

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