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2-Methoxybenzylidenepyruvatewith heavier trivalent lanthanides and yttrium(III)

Synthesis and characterization

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Abstract

Solid-state Ln(2-MeO-BP) compounds, where Ln stands for trivalent Eu to Lu and Y(III) and 2-MeO-BP (which is 2-methoxybenzylidenepyruvate) have been synthesized. Simultaneous thermogravimetry and differential thermal analysis (TG-DTA), differential scanning calorimetry (DSC), X-ray powder diffraction, infrared spectroscopy and other methods of analysis were used to characterize and to study these compounds. On the base of the obtained results an Ln(2MeO-BP)3·nH2O general formula can be established.

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Correspondence to E. Y. Ionashiro.

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Ionashiro, E.Y., Bannach, G., Siqueira, A.B. et al. 2-Methoxybenzylidenepyruvatewith heavier trivalent lanthanides and yttrium(III). J Therm Anal Calorim 92, 953–959 (2008). https://doi.org/10.1007/s10973-007-8699-y

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  • DOI: https://doi.org/10.1007/s10973-007-8699-y

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