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Extrapolation of accelerated thermooxidative tests to lower temperatures applying non-Arrhenius temperature functions

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Abstract

Extrapolations of the accelerated thermooxidative tests, based on the Arrhenius and two non-Arrhenius temperature functions, have been tested for 26 data sets. The data cover a wide range of materials from polyolefins and other polymers to biodiesel, edible oils and dried milk. It has been found that the extrapolation from high-temperature data to ambient temperature based on the Arrhenius temperature function leads to the estimations of unrealistically long durability. The best estimations corresponding most with experience are obtained for the extrapolation based on the temperature function k(T)=A kexp(DT).

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References

  1. P. Šimon and Ľ. Kolman, J. Therm. Anal. Cal., 64 (2001) 813.

    Article  Google Scholar 

  2. P. Šimon, J. Therm. Anal. Cal., 84 (2006) 263.

    Article  Google Scholar 

  3. P. Šimon, Ľ. Kolman, I. Niklová and Š. Schmidt, J. Am. Oil Chem. Soc., 77 (2000) 639.

    Article  Google Scholar 

  4. J. Polavka, J. Paligová, J. Cvengroš and P. Šimon, J. Am. Oil Chem. Soc., 82 (2005) 519.

    Article  CAS  Google Scholar 

  5. A. Gregorová, Z. Cibulková, B. Koİíková and P. Šimon, Polym. Degrad. Stab., 89 (2005) 553.

    Article  Google Scholar 

  6. P. Šimon, M. Veverka and J. Okuliar, Int. J. Pharm., 270 (2004) 21.

    Article  Google Scholar 

  7. Z. Cibulková, P. Šimon, P. Lehocký and J. Balko, Polym. Degrad. Stab., 87 (2005) 479.

    Article  Google Scholar 

  8. Z. Cibulková, P. Šimon, P. Lehocký and J. Balko, J. Therm. Anal. Cal., 80 (2005) 357.

    Article  Google Scholar 

  9. M. Fratričová, P. Šimon, P. Schwarzer and H. W. Wilde, Polym. Degrad. Stab., 91 (2006) 94.

    Article  Google Scholar 

  10. P. Šimon, M. Fratričová, P. Schwarzer and H. W. Wilde, J. Therm. Anal. Cal., 84 (2006) 679.

    Article  Google Scholar 

  11. P. Šimon and J. Polavka, J. Food Nutr. Res., 45 (2006) 166.

    Google Scholar 

  12. P. Šimon, W. Zhong, D. Bakoš and D. Hynek, Chem. Papers, 62 (2008) 176.

    Article  Google Scholar 

  13. L. Woo, A. R. Khare, C. L. Sandford, M. T. K. Ling and S. Y. Ding, J. Therm. Anal. Cal., 64 (2001) 539.

    Article  CAS  Google Scholar 

  14. K. T. Gillen, R. Bernstein and D. K. Derzon, Polym. Degrad. Stab., 87 (2005) 57.

    Article  CAS  Google Scholar 

  15. K. T. Gillen, R. Bernstein and M. Celina, Polym. Degrad. Stab., 87 (2005) 335.

    Article  CAS  Google Scholar 

  16. M. Celina, K. T. Gillen and R. A. Assink, Polym. Degrad. Stab., 90 (2005) 395.

    Article  CAS  Google Scholar 

  17. P. Šimon, J. Therm. Anal. Cal., 88 (2007) 709.

    Article  Google Scholar 

  18. P. Šimon, J. Therm. Anal. Cal., 79 (2005) 703.

    Article  Google Scholar 

  19. P. Šimon, Z. Cibulková and P. Thomas, J. Therm. Anal. Cal., 80 (2005) 381.

    Article  Google Scholar 

  20. P. Šimon, J. Therm. Anal. Cal., 82 (2005) 651.

    Article  Google Scholar 

  21. P. Šimon, J. Therm. Anal. Cal., 76 (2004) 123.

    Article  Google Scholar 

  22. J. H. Flynn, Thermochim. Acta, 300 (1997) 83.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Institute of Physical Chemistry and Chemical Physics, Faculty of Chemical and Food Technology, Slovak University of Technology, Radlinského 9, 812 37, Bratislava, Slovak Republic

    P. Šimon & Zuzana Cibulková

  2. Faculty of Chemistry, Brno University of Technology, Purkyňova 118, 612 00, Brno, Czech Republic

    D. Hynek

  3. Institute of Polymers, Slovak Academy of Sciences, Dúbravská cesta 9, 842 36, Bratislava, Slovak Republic

    Marta Malíková

Authors
  1. P. Šimon
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  2. D. Hynek
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  3. Marta Malíková
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  4. Zuzana Cibulková
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Correspondence to P. Šimon.

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Šimon, P., Hynek, D., Malíková, M. et al. Extrapolation of accelerated thermooxidative tests to lower temperatures applying non-Arrhenius temperature functions. J Therm Anal Calorim 93, 817–821 (2008). https://doi.org/10.1007/s10973-008-9328-0

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  • DOI: https://doi.org/10.1007/s10973-008-9328-0

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