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’Model-free‘ approach in the study of decomposition kinetics for cluster compounds and coordination compounds

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Abstract

’Model-free’ approach was used for the study of decomposition kinetics: the dehydration of cluster compound [{Mg(H2O)5}2Re6S8(OH)6]·H2O and the phase transformation under partial pyrolysis of bismuth oxohydroxolaurate Bi6O4(OH)4(C11H23COO)6.

The primary calculation of accurate activation energy values and the obvious discrimination of separate decomposition steps allow using further linear and non-linear regression methods for more accurate and full kinetic description.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, Lavrentyev Ave. 3, Novosibirsk-90, 630090, Russia

    V. Logvinenko

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  1. V. Logvinenko
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Correspondence to V. Logvinenko.

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Logvinenko, V. ’Model-free‘ approach in the study of decomposition kinetics for cluster compounds and coordination compounds. J Therm Anal Calorim 93, 805–809 (2008). https://doi.org/10.1007/s10973-008-9300-z

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