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Synthesis and characterization of antimony trichloride and bismuth trichloride complexes with valine

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Abstract

Two compounds of antimony trichloride and bismuth trichloride with valine are synthesized by solid phase synthesis at room temperature. Their compositions, determined by element analysis, are Sb(C5H10O2N)3·2H2O and Bi(C5H10O2N)2Cl·0.5H2O. The crystal structure of antimony complex with valine belongs to triclinic system and its lattice parameters are: a=0.9599 nm, b=1.5068 nm, c=1.9851 nm, α=92.270, β=95.050, γ=104.270. The crystal structure of bismuth complex with valine belongs to monoclinic system and its lattice parameters are: a=1.6012 nm, b=1.8941 nm, c=1.839 nm, β=99.73°. The far-infrared spectra and infrared spectra show that the amino group and carboxyl of valine may be coordinated to antimony and bismuth, respectively, in two compounds. The TG-DSC results also reveal that the complexes were formed.

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, 225002, P.R. China

    J. G. Shao

  2. Department of Chemistry, East China University of Science and Technology, 200237, Shanghai, P.R. China

    Y. X. Yang, B. W. Li, L. P. Zhang & Y. R. Chen

  3. Analysis Test Center, Yangzhou University, Yangzhou, 225009, P.R. China

    X. L. Liu

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  1. J. G. Shao
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  2. Y. X. Yang
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  3. B. W. Li
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  4. L. P. Zhang
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  5. Y. R. Chen
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  6. X. L. Liu
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Correspondence to Y. X. Yang.

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Shao, J.G., Yang, Y.X., Li, B.W. et al. Synthesis and characterization of antimony trichloride and bismuth trichloride complexes with valine. J Therm Anal Calorim 96, 277–285 (2009). https://doi.org/10.1007/s10973-008-9045-8

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  • DOI: https://doi.org/10.1007/s10973-008-9045-8

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