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The synthesis and selected properties of Co2InV3O11

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Abstract

It has been demonstrated that Co2V2O7 and InVO4 react with each other forming a new compound of the Co2InV3O11 formula, when their molar ratio is equal to 1:1, or among CoCO3, In2O3 and V2O5, mixed at a molar ratio of 4:1:3. This compound melts incongruently at the temperature of 960±5°C, depositing crystals of InVO4. It crystallizes in the triclinic system and the unit cell parameters amount to: a=0.6524(6) nm, b=0.6885(5) nm, c=1.0290(4) nm, α=96.5°, β=104.1°, γ=100.9°, Z=2. The phase equilibria being established in the Co2V2O7–InVO4 system over the whole components concentration range up to the solidus line were described.

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  1. Department of Inorganic and Analytical Chemistry, Szczecin University of Technology, Szczecin, Poland, 71-065, Al.Piastów 42

    Monika Bosacka

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  1. Monika Bosacka
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Correspondence to Monika Bosacka.

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Bosacka, M. The synthesis and selected properties of Co2InV3O11 . J Therm Anal Calorim 88, 43–46 (2007). https://doi.org/10.1007/s10973-006-8052-x

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