Skip to main content
SpringerLink
Log in

Thermal decomposition and stability of [Fe(η4-enone)(CO)2L] complexes (L=CO and PPh3)

  • regular
  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

The compounds [Fe(bda)(CO)2L] and [Fe(ch)(CO)2L], (bda=benzylideneacetone; ch=chalcone; L=CO, PPh3) were investigated by thermogravimetry and derivative thermogravimetry (TG and DTG). The fragmentation patterns suggest that the iron atom protects the enone fragment, so that the organic ligands break up with the loss of the pendant aromatic rings.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. DHR Barton AAL Gunatilaka T Nakanishi H Patin WA Barton BR Worth (1976) J. C. S. Perkin I 8 821 Occurrence Handle10.1039/p19760000821

    Article  Google Scholar 

  2. G Sholes CR Graham M Brookhart (1974) J. Am. Chem. Soc. 96 5665 Occurrence Handle10.1021/ja00824a106

    Article  Google Scholar 

  3. M Brookhart GO Nelson G Scholes RA Watson (1976) J. C. S. Chem. Comm. 6 195 Occurrence Handle10.1039/c39760000195

    Article  Google Scholar 

  4. BFG Johson J Lewis P McArdle GLP Randall (1971) Chem. Comm. 2 177

    Google Scholar 

  5. GD Sargent N Lowry SD Reich (1967) J. Amer. Chem. Soc. 89 5985 Occurrence Handle10.1021/ja00999a066 Occurrence Handle1:CAS:528:DyaF1cXmvVWitQ%3D%3D

    Article  CAS  Google Scholar 

  6. CR Ganellin R Petit (1958) J. Chem. Soc. 112 576 Occurrence Handle10.1039/jr9580000576

    Article  Google Scholar 

  7. JAS Howell BFG Johnson PL Josty J Lewis (1972) J. Organomet. Chem. 39 329 Occurrence Handle10.1016/S0022-328X(00)80458-1 Occurrence Handle1:CAS:528:DyaE38XkslGgs78%3D

    Article  CAS  Google Scholar 

  8. EJS Vichi PR Raithby M McPartlin (1983) J. Organomet. Chem. 256 111 Occurrence Handle10.1016/S0022-328X(00)99303-3 Occurrence Handle1:CAS:528:DyaL2cXht1Wgsrs%3D

    Article  CAS  Google Scholar 

  9. A Vessieres P Dixneuf (1974) Tetrahedron Lett. 16 1499 Occurrence Handle10.1016/S0040-4039(01)93120-X

    Article  Google Scholar 

  10. BFG Johnson J Lewis GR Stephenson EJS Vichi (1978) J. Chem. Soc., Dalton Trans. 5 369 Occurrence Handle10.1039/dt9780000369

    Article  Google Scholar 

  11. EJS Vichi FY Fujiwara E Stein (1985) Inorg. Chem. 24 286 Occurrence Handle10.1021/ic00197a009 Occurrence Handle1:CAS:528:DyaL2MXpsFOqsg%3D%3D

    Article  CAS  Google Scholar 

  12. JAS Howell DT Dixon JC Kole (1984) J. Organomet. Chem. 69 266

    Google Scholar 

  13. MJ Calhorda EJS Vichi (1990) Organometallics 9 1060 Occurrence Handle10.1021/om00118a024 Occurrence Handle1:CAS:528:DyaK3cXhsl2gurw%3D

    Article  CAS  Google Scholar 

  14. VM Nogueira AV Benedetti EJS Vichi E Stein (1991) J. Electroanal. Chem. 287 761

    Google Scholar 

  15. K Zutin VM Nogueira AE Mauro P Melnikov A Iluykhin (2001) Polyhedron 20 1011 Occurrence Handle10.1016/S0277-5387(01)00763-X Occurrence Handle1:CAS:528:DC%2BD3MXktFeqsbY%3D

    Article  CAS  Google Scholar 

  16. PS Haddad AE Mauro VM Nogueira SI Klein (2003) Trans. Metal Chem. 28 899 Occurrence Handle10.1023/A:1026332111423 Occurrence Handle1:CAS:528:DC%2BD3sXosFCnur4%3D

    Article  CAS  Google Scholar 

  17. AF Clifford AK Mukherjee (1966) Inorg. Synth. 8 185 Occurrence Handle10.1002/9780470132395.ch49 Occurrence Handle1:CAS:528:DyaF28XkvFOjtLg%3D

    Article  CAS  Google Scholar 

  18. FM Chaudari PL Pauson (1966) J. Organomet. Chem. 5 73 Occurrence Handle10.1016/S0022-328X(00)82252-4

    Article  Google Scholar 

  19. R Edwards JAS Howell BFG Johnson J Lewis (1974) J. Chem. Soc. Dalton Trans. 19 2105 Occurrence Handle10.1039/dt9740002105

    Article  Google Scholar 

  20. J Chatt LA Duncanson (1953) J. Chem. Soc. 1 2939 Occurrence Handle10.1039/jr9530002939

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Instituto de Química de Araraquara, UNESP, São Paulo State University, São Paulo, Brazil, C.P. 355, CEP 14800-900, Araraquara

    K. Zutin, V. M. Nogueira, A. E. Mauro, G. R. de Souza & S. I. Klein

Authors
  1. K. Zutin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. M. Nogueira
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. E. Mauro
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. G. R. de Souza
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. S. I. Klein
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. M. Nogueira.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zutin, K., Nogueira, V.M., Mauro, A.E. et al. Thermal decomposition and stability of [Fe(η4-enone)(CO)2L] complexes (L=CO and PPh3). J Therm Anal Calorim 87, 449–452 (2007). https://doi.org/10.1007/s10973-006-7687-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10973-006-7687-y

Keywords

Search

Navigation