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Surface properties of silica gel samples modified by selected proteins

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Abstract

The adsorption of a polar (water) and a non-polar (n-octane) liquid on silica gels, modified by adsorption of proteins, has been studied by thermal analysis. Silica gels with physically adsorbed BSA and ovalbumin layers were used. Thermodesorption energies were determined from Q-TG and Q-DTG curves recorded under quasi-equilibrium conditions. Significant differences in liquid desorption were observed from the surfaces due to heterogeneous changes (energetic and geometrical) as a result of modification. These results are compared with those obtained for the samples heated at 160°C for 1 h.

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Authors and Affiliations

  1. Department of Physicochemistry of Solid Surface, Chemistry Faculty, Maria Curie-Skłodowska University, Lublin, Poland, 20-031, M. Curie-Skłodowska Sq. 3

    D. Sternik, P. Staszczuk, J. Pękalska, G. Grodzicka & P. Witer

  2. Department of Chemistry and Polymer Technology, Chemistry Faculty, Maria Curie-Skłodowska University, Lublin, Poland, 20-031, M. Curie-Skłodowska Sq. 3

    B. Gawdzik & J. Osypiuk-Tomasik

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  1. D. Sternik
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  3. J. Pękalska
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Correspondence to P. Staszczuk.

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Sternik, D., Staszczuk, P., Pękalska, J. et al. Surface properties of silica gel samples modified by selected proteins. J Therm Anal Calorim 86, 85–91 (2006). https://doi.org/10.1007/s10973-006-7581-7

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  • DOI: https://doi.org/10.1007/s10973-006-7581-7

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