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Influence of the thermal degradation on the dielectric properties of a thermoset

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Abstract

The thermal degradation of an epoxy system consisting of a diglycidyl ether of bisphenol A (DGEBA, n=0) and m-xylylenediamine (m-XDA) was studied by both thermogravimetric analysis (TG) and dielectric analysis (DEA). It has been checked a deviation of the typical behaviour in the Arrhenius plot expected for this kind of systems, owing to the thermal degradation.

Both, structural relaxation time and conductivity values, were represented as a function of the mass loss, that allow a relationship to be obtained between characteristic relaxation time and the degree of degradation at the beginning of the degradation process.

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References

  1. Y-I Liu W-L Wei K-Y Hsu W-H Ho (2004) Thermochim. Acta 421 139 Occurrence Handle10.1016/j.tca.2003.09.004

    Article  Google Scholar 

  2. L Núñez-Regueira CA Gracia-Fernández S Gómez-Barreiro (2005) J. Therm. Anal. Cal. 96 2027

    Google Scholar 

  3. M Vinnik VA Roznyanovsky (2004) J. Therm. Anal. Cal. 75 753 Occurrence Handle1:CAS:528:DC%2BD2cXjsValu78%3D Occurrence Handle10.1023/B:JTAN.0000027171.45995.f6

    Article  CAS  Google Scholar 

  4. NE Marcovich MM Reboredo MI Aranguren (2001) Thermochim. Acta 372 45 Occurrence Handle1:CAS:528:DC%2BD3MXjtlaru74%3D Occurrence Handle10.1016/S0040-6031(01)00425-7

    Article  CAS  Google Scholar 

  5. L Núñez F Fraga MR Núñez A Castro L Fraga (1999) J. Appl. Polym. Sci. 74 2997

    Google Scholar 

  6. L Núñez F Fraga A Castro MR Núñez M Villanueva (2000) J. Appl. Polym. Sci. 75 291 Occurrence Handle10.1002/(SICI)1097-4628(20000110)75:2<291::AID-APP12>3.0.CO;2-A

    Article  Google Scholar 

  7. L Núñez F Fraga MR Núñez M Villanueva (2000) J. Appl. Polym. Sci. 78 1239 Occurrence Handle10.1002/1097-4628(20001107)78:6<1239::AID-APP90>3.0.CO;2-X

    Article  Google Scholar 

  8. MR Núñez M Villanueva B Rial L Núñez (2001) J. Therm. Anal. Cal. 66 209 Occurrence Handle10.1023/A:1012452002088

    Article  Google Scholar 

  9. ME Brown (1998) ‘Handbook of Thermal Analysis and Calorimetry’, Vol. 1: Principles and Practice Elsevier Science B. V. Amsterdam

    Google Scholar 

  10. EA Turi (1997) ‘Thermal Characterization of Polymeric Materials’ Academic Press, Inc. San Diego

    Google Scholar 

  11. M. C. W. Coln and S. D. Senturia, ‘The application of linear system theory to parametric microsensor’, Proc. Transducers’ 85, 1985, p. 118.

  12. BJ Hunt MI James (1993) ‘Polymer Characterisation’ Blackie Academic and Professional. Great Britain

    Google Scholar 

  13. J Köplinger G Kasper S Hunklinger (2000) J. Chem. Phys. 113 4701 Occurrence Handle10.1063/1.1288904

    Article  Google Scholar 

  14. JD Ferry (1990) Viscoelastic Properties of Polymers EditionNumber3 Wiley & Sons New York

    Google Scholar 

  15. FN Sheppard Jr. SD Senturia (1989) J. Polym. Sci., Part B; Polym. Phys. 27 753 Occurrence Handle10.1002/polb.1989.090270403

    Article  Google Scholar 

  16. SD Senturia NF Sheppard (1986) ‘Dielectric Analysis of Thermoset Cure’, Advances in Polymer Science, 80 Springer- Verlag Berlin Heidelberg

    Google Scholar 

  17. P Debye (1929) ‘Polar Molecules’ Chemical Catalog Co. New York

    Google Scholar 

  18. L Núñez L Fraga MR Núñez M Villanueva B Rial (2002) J. Therm. Anal. Cal. 70 1931

    Google Scholar 

  19. S Havriliak Jr. SJ Havriliak (1996) ‘Dielectric and Mechanical Relaxation in Materials’ Hanser/Gardner Publications, Inc. Cincinnati

    Google Scholar 

  20. J Einfeldt D Meissner A Kwasniewski (2001) Prog. Polym. Sci. 26 1419 Occurrence Handle1:CAS:528:DC%2BD3MXoslCjsbs%3D Occurrence Handle10.1016/S0079-6700(01)00020-X

    Article  CAS  Google Scholar 

  21. RA Pethrick D Hayward (2002) Prog. Polym. Sci. 27 1983 Occurrence Handle1:CAS:528:DC%2BD38Xms1Kitrs%3D Occurrence Handle10.1016/S0079-6700(02)00027-8

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Research Group TERBIPROMAT, Departamento Física Aplicada, Universidade de Santiago de Compostela, Santiago, Spain, 15782

    Lisardo Núñez-Regueira, M. Villanueva, I. Fraga, C. A. Gracia-Fernández & S. Gómez-Barreiro

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  1. Lisardo Núñez-Regueira
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  2. M. Villanueva
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  3. I. Fraga
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  4. C. A. Gracia-Fernández
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  5. S. Gómez-Barreiro
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Núñez-Regueira, L., Villanueva, M., Fraga, I. et al. Influence of the thermal degradation on the dielectric properties of a thermoset. J Therm Anal Calorim 86, 235–241 (2006). https://doi.org/10.1007/s10973-005-7190-x

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  • DOI: https://doi.org/10.1007/s10973-005-7190-x

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