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Divalent transition metal complexes

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Abstract

4-(4-ethoxy-phenylhydrazono)-1-phenyl-3-methyl-1H-pyrazolin-5(4H)-one (5a) (H-EMPhP) as ligand and its Cu(II), Co(II) and Ni(II) complexes 4(a-c) were synthesized and characterized by their thermal and spectral properties. The azocoupling product (H-EMPhP), able of azo-hydrazone tautomerism 5(a-d), act as a bidentate ligand involving in coordination the azogroup nitrogen of its common anion (7) and the oxygen atom that is bound to the pyrazole ring of the mentioned anion (7).

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Authors and Affiliations

  1. Department of Chemistry, ‘Babeş-Bolyai’ University 3400 Cluj-Napoca, Romania

    C. Bâtiu, I. Panea & L. Ghizdavu

  2. Department of Physics, ‘Babeş-Bolyai’ University 3400 Cluj-Napoca, Romania

    L. David

  3. French College Debarcadere, Str., 2502 Bienne, Switzerland

    S. Ghizdavu Pellascio

Authors
  1. C. Bâtiu
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  2. I. Panea
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  3. L. Ghizdavu
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  4. L. David
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  5. S. Ghizdavu Pellascio
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Bâtiu, C., Panea, I., Ghizdavu, L. et al. Divalent transition metal complexes. J Therm Anal Calorim 79, 129–134 (2005). https://doi.org/10.1007/s10973-004-0573-6

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  • DOI: https://doi.org/10.1007/s10973-004-0573-6

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