Abstract
Aerogel is a solid material with a porous structure created by replacing the liquid component of a gel with gas. It has low density, excellent thermal insulation, high surface area, and is hydrophobic. Aerogel blankets are reinforced, flexible, and ideal for thermal insulation, but drying them using a supercritical method is challenging for large-scale production. Researchers are developing more efficient methods to produce aerogel blankets, which could increase their adoption in various industries. This research aims to design a portable, lightweight, super-insulating aerogel blanket dried under ambient conditions for various applications. Bulk density, mechanical properties, acoustic properties, and thermal conductivity are used to assess the impact of silica concentration on aerogel-enhanced blankets. The adhesion between the aerogel and the blanket’s fiber is influenced by the concentration of silica in the aerogel material, as revealed by scanning electron microscopy. Prepared aerogel blankets have excellent thermal conductivity (0.021 W m−1 K−1) and hydrophobic behavior. Prepared blankets qualify for the fire-proof requirement as per norm ISO2685 at 64 kW/m2 flux for 15 minutes. Aerogel blankets produced under ambient drying approach have properties comparable to those produced through the supercritical drying process. This represents a significant advancement in the commercialization of aerogel blankets.
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References
Kistler SS, Caldwell AG (1934) Thermal conductivity of silica aërogel. Ind Eng Chem 26(6):658–662. https://doi.org/10.1021/ie50294a016
Wang J, Petit D, Ren S (2020) Transparent thermal insulation silica aerogels. Nanoscale Adv 2(12):5504–5515. https://doi.org/10.1039/d0na00655f
Zhang Y et al. (2021) Rapid synthesis of dual-mesoporous silica aerogel with excellent adsorption capacity and ultra-low thermal conductivity. J Non Cryst Solids 555:120547. https://doi.org/10.1016/J.JNONCRYSOL.2020.120547
Gao B, Lu S, Kalulu M, Oderinde O and Ren L, (2017) Synthesis of silica aerogel monoliths with controlled specific surface areas and pore sizes. Mater Res Express, 4(7), https://doi.org/10.1088/2053-1591/aa748e
Aravind PR, Soraru GD (2011) High surface area methyltriethoxysilane-derived aerogels by ambient pressure drying. J Porous Mater 18(2):159–165. https://doi.org/10.1007/s10934-010-9366-4
Xiong X, Yang T, Mishra R, Militky J (2016) Transport properties of aerogel-based nanofibrous nonwoven fabrics. Fibers Polym 17(10):1709–1714. https://doi.org/10.1007/s12221-016-6745-8
Wen S, Zhu J, Yin Q, Bi Y, Ren H, Zhang L (2020) Fabrication of infrared opacifiers loaded Al2O3 aerogel-SiO2 fiber mat composites with high thermal resistance. Int J Nanosci 19(3), https://doi.org/10.1142/S0219581X19500212
Tascan M, Vaughn EA, Stevens KA, Brown PJ (2011) Effects of total surface area and fabric density on the acoustical behavior of traditional. J Text Inst 102(9):746–751. https://doi.org/10.1080/00405000.2010.515731
Zhi C et al. (2020) Warp-knitted spacer fabric reinforced syntactic foam: a compression modulus meso-mechanics theoretical model and experimental verification. Polymers 12(2) https://doi.org/10.3390/polym12020286
Rwawiire S, Tomkova B, Militky J, Hes L, Kale BM (2017) Acoustic and thermal properties of a cellulose nonwoven natural fabric (barkcloth). Appl Acoust 116:177–183. https://doi.org/10.1016/J.APACOUST.2016.09.027
Fu R et al. (2003) The fabrication and characterization of carbon aerogels by gelation and supercritical drying in isopropanol. Adv Funct Mater 13(7):558–562. https://doi.org/10.1002/adfm.200304289
Wen S, Ren H, Zhu J, Bi Y, Zhang L (2019) Fabrication of Al2O3 aerogel-SiO2 fiber composite with enhanced thermal insulation and high heat resistance. J Porous Mater 26(4):1027–1034
Chakraborty S, Pisal AA, Kothari VK, Venkateswara Rao A (2016) Synthesis and characterization of fibre reinforced silica aerogel blankets for thermal protection. Adv Mater Sci Eng 2016, https://doi.org/10.1155/2016/2495623
Huang Y et al. (2018) Mechanical reinforced fiber needle felt/silica aerogel composite with its flammability. J Sol-Gel Sci Technol 88(1):129–140. https://doi.org/10.1007/s10971-018-4796-6
Li C, Cheng X, Li Z, Pan Y, Huang Y, Gong L (2017) Mechanical, thermal and flammability properties of glass fiber film/silica aerogel composites. J Non Cryst Solids 457:52–59. https://doi.org/10.1016/j.jnoncrysol.2016.11.017
Boukind S et al. (2021) Ambient pressure drying as an advanced approach to the synthesis of silica aerogel composite for building thermal insulation. J Nat Fibers, https://doi.org/10.1080/15440478.2021.1993486/FORMAT/EPUB
Wang L, Feng J, Jiang Y, Li L, Feng J (2019) Elastic methyltrimethoxysilane based silica aerogels reinforced with polyvinylmethyldimethoxysilane. RSC Adv 9(19):10948–10957. https://doi.org/10.1039/c9ra00970a
Karamikamkar S, Naguib HE, Park CB (2020) Advances in precursor system for silica-based aerogel production toward improved mechanical properties, customized morphology, and multifunctionality: A review. Adv Colloid Interface Sci 276:102101
Leventis N, Palczer A, McCorkle L, Zhang G, Sotiriou-Leventis C (2005) Nanoengineered silica-polymer composite aerogels with No need for supercritical fluid drying. J Sol-Gel Sci Technol 35(2):99–105. https://doi.org/10.1007/s10971-005-1372-7
Ul Haq E, Zaidi SFA, Zubair M, Abdul Karim MR, Padmanabhan SK, Licciulli A (2017) Hydrophobic silica aerogel glass-fibre composite with higher strength and thermal insulation based on methyltrimethoxysilane (MTMS) precursor. Energy Build 151:494–500. https://doi.org/10.1016/j.enbuild.2017.07.003
Udio C, Almeida MR, Ghica ME, Ramalho AL, Durães L (2021) Silica-based aerogel composites reinforced with different aramid fibres for thermal insulation in Space environments. J Mater Sci 56, https://doi.org/10.1007/s10853-021-06142-3
Ślosarczyk A, Barełkowski M, Niemier S, Jakubowska P (2015) Synthesis and characterisation of silica aerogel/carbon microfibers nanocomposites dried in supercritical and ambient pressure conditions. J Sol Gel Sci Technol 76(1):227–232. https://doi.org/10.1007/s10971-015-3798-x
Thapliyal PC, Singh K (2014) Aerogels as promising thermal insulating materials: an overview. J Mater 2014:1–10. https://doi.org/10.1155/2014/127049
Delhi N (2006) MINISTRY OF LAW AND JUSTICE (Legislative Department), 2(1):1–69
The Energy Conservation (Amendment) Bill (2022). https://prsindia.org/billtrack/the-energy-conservation-amendment-bill-2022. Accessed 13 Feb 2023
Linhares T, Pessoa De Amorim MT, Durães L, Teresa Linhares, de Amorim MTP, Durães L (2019) Silica aerogel composites with embedded fibres: a review on their preparation, properties and applications. J Mater Chem A 7(40):22768–22802. https://doi.org/10.1039/C9TA04811A
Baetens R, Jelle BP, Gustavsen A. (2011) Aerogel insulation for building applications: A state-of-the-art review. Energy Build 43.4:761–769
Berardi US, (Mark) Zaidi S (2019) Characterization of commercial aerogel-enhanced blankets obtained with supercritical drying and of a new ambient pressure drying blanket. Energy Build 198:542–552. https://doi.org/10.1016/j.enbuild.2019.06.027
Mazrouei-Sebdani Z et al. (2022) Multiple assembly strategies for silica aerogel-fiber combinations-A review. Materials & Design 223:111228
Siligardi C, Miselli P, Francia E, Lassinantti Gualtieri M (2017) Temperature-induced microstructural changes of fiber-reinforced silica aerogel (FRAB) and rock wool thermal insulation materials: a comparative study. Energy Build 138:80–87. https://doi.org/10.1016/J.ENBUILD.2016.12.022
Hoseini A, McCague C, Andisheh-Tadbir M, Bahrami M (2016) Aerogel blankets: from mathematical modeling to material characterization and experimental analysis. Int J Heat Mass Transf 93:1124–1131. https://doi.org/10.1016/j.ijheatmasstransfer.2015.11.030
Bheekhun N, Rahim A, Talib A, Hassan MR (2013) Aerogels in aerospace: a review. Adv Mater Sci Eng 2013:1–18
Circular, Advisory. Powerplant Installation and Propulsion System Component Fire Protection Test Methods, Standards, and Criteria. US Department of Transportation, Federal Aviation Administration: 20–135
Kistler SS (1932) Coherent expanded aerogels. J Phys Chem 36(1):52–64. https://doi.org/10.1021/j150331a003
Prakash SS, Brinker CJ, Hurd AJ, Rao SM (1995) Silica aerogel films prepared at ambient pressure by using surface derivatization to induce reversible drying shrinkage. Nature 374(6521):439–443
Wu H, Chen Y, Chen Q, Ding Y, Zhou X, Gao H (2013) Synthesis of flexible aerogel composites reinforced with electrospun nanofibers and microparticles for thermal insulation. J Nanomater 2013, https://doi.org/10.1155/2013/375093
Patil SP, Shendye P, Markert B (2020) Molecular dynamics simulations of silica aerogel nanocomposites reinforced by glass fibers, graphene sheets and carbon nanotubes: a comparison study on mechanical properties. Compos Part B Eng 190:107884. https://doi.org/10.1016/J.COMPOSITESB.2020.107884
Zhang ZH et al. (2022) Silicone/graphene oxide co-cross-linked aerogels with wide-temperature mechanical flexibility, super-hydrophobicity and flame resistance for exceptional thermal insulation and oil/water separation. J Mater Sci Technol 114:131–142. https://doi.org/10.1016/J.JMST.2021.11.012
Venkataraman M, Mishra R, Jasikova D, Kotresh TMT, Militky J (2015) Thermodynamics of aerogel-treated nonwoven fabrics at subzero temperatures. J Ind Text 45(3):387–404. https://doi.org/10.1177/1528083714534711
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This research has been supported by General Electric project funded under grant agreement MI02163.
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JS: Conceptualization, experiment, writing. SS: Testing, Figure preparation, writing. OS : Testing of the sample and analysis. JS: Supervision and review. BKB: Supervision and review.
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Sharma, J., Shukla, S., Singh, O. et al. Multi-field and multi-scale characterization of non-supercritical dried silica aerogel-based glass blankets: investigating thermal, mechanical, acoustic, and fire performance. J Sol-Gel Sci Technol 108, 60–72 (2023). https://doi.org/10.1007/s10971-023-06186-8
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DOI: https://doi.org/10.1007/s10971-023-06186-8