Abstract
Aluminum doped cobalt ferrite nanoparticles(CoFe2–xAlxO4(x = 0.0 and 0.5)) were synthesized by wet chemical co-precipitation method. X-ray diffraction pattern confirmed the successful doping of the smaller cation of Al3+ and the single-phase cubic spinel structure of the prepared nanoparticles. The crystallite size of nanoparticles was examined ~25 nmusing X-ray diffraction data.The lattice parameter ‘a ’ also decreased by doping the Al3+cation. Two functional groups and fundamental peaks of calcined samples were identified byFourier-transform infrared spectroscopy in the range of 450–600 cm−1, these characteristic absorption bandsconfirmed the cubic spinel structure of prepared nanoparticles. Field emission electron microscopy images confirm the formation of nearly spherical ferrite nanoparticles with an average size ~25–30 nm that is in good agreement with XRD results. Magnetic hysteresis study at room temperature confirmed the ferrimagnetic nature of the prepared samples and the decrease in saturation magnetization (MS = 74–44 emu/g) and reduction in coercivity (HC = 627.8–539.4 Oe) due to doping the Al3+cation. Improved values of dielectric constant, low dielectric loss and resistivity were displayed by Al3+cation doped ferrite nanoparticles and has been measured at room temperature for frequency dependence in the range of 100 Hz–10 MHz using impedance analyzer. It is revealed strong dependence of dielectric parameters on frequency and Al3+ ion content. Doping the Al3+ cation was increasing the values of dielectric constant and dielectric loss for (CoFe2–xAlxO4(x = 0.0 and 0.5)) while decreases the electrical resistance of prepared nanoparticle. results explored the capability of the Al doped cobalt ferrite to be suitable for high frequency applications and magnetic memory devices.
Graphical Abstract
Highlights
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Aluminum Cobalt ferrite nanoparticles are prepared by co precipitation method using sodium hydroxide as reactant agent.
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Crystal size of the prepared nanoparticles is calculated by the XRD data ~25 nm and confirmed by FESEM spectroscopy techniques.
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Magnetic hysteresis study confirmed the ferrimagnetic nature of Aluminum Cobalt ferrite nano particles.
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Impedance spectroscopy analysis indicates the material to be suitable for memory device applications.
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References
Hassan A et al. (2015) Nanocrystalline Zn1− x Co0. 5xNi0. 5x Fe2O4 ferrites: fabrication via co-precipitation route with enhanced magnetic and electrical properties. J Magn Magn Mater 393:56–61
Mustafa G et al. (2015) Influence of the divalent and trivalent ions substitution on the structural and magnetic properties of Mg0. 5− xCdxCo0. 5Cr0. 04TbyFe1. 96− yO4 ferrites prepared by sol–gel method. J Magn Magn Mater 387:147–154
Hashim M et al. (2012) Structural, electrical and magnetic properties of Co–Cu ferrite nanoparticles. J Alloy Compd 518:11–18
Reddy RA et al. (2022) Structural, electrical and magnetic properties of cobalt ferrite with Nd3+ doping. Rare Met 41(1):240–245
Daruvuri HR et al. (2022) Effect on structural, dc electrical resistivity, and magnetic properties by the substitution of Zn2+ on Co-Cu nano ferrite. Inorg Chem Commun 143:109794
Bhanu V et al. (2022) Neutron diffraction study and temperature variation of magnetic anisotropy in Bi substituted nickel ferrite. Ceramics Int 48(16):23300–23306. https://doi.org/10.1016/j.ceramint.2022.04.316
Sivakumar K et al. (2022) Development of peanut husk carbon quantum dots and ferrite foil epoxy composite for EMI shielding at high frequency bands. Biomass Conv Bioref. https://doi.org/10.1007/s13399-022-03469-y
Vurro F et al. (2022) Doped Ferrite Nanoparticles Exhibiting Self-Regulating Temperature as Magnetic Fluid Hyperthermia Antitumoral Agents, with Diagnostic Capability in Magnetic Resonance Imaging and Magnetic Particle Imaging. Cancers 14(20):5150
Jermy BR et al. (2022) PEGylated green halloysite/spinel ferrite nanocomposites for pH sensitive delivery of dexamethasone: A potential pulmonary drug delivery treatment option for COVID-19. Appl Clay Sci 216:106333
Dessai PPG, Singh AK, Verenkar V (2022) Mn doped Ni-Zn ferrite thick film as a highly selective and sensitive gas sensor for Cl2 gas with quick response and recovery time. Mater Res Bull 149:111699
Mekuria T et al. (2020) Cobalt ferrite nanoparticle intercalated carbon nanotubes for a nanomagnetic ultrasensitive sensor of Cr-VI in water. AIP Adv 10(6):065134
Gupta R, Kotnala R (2022) A review on current status and mechanisms of room-temperature magnetoelectric coupling in multiferroics for device applications. J Mater Sci 57(27):12710–12737
Anukool W et al. (2022) Effects of aluminum substitution on the microstructure and magnetic properties of cobalt ferrites prepared by the co-precipitation precursor. Appl Phys A 128(8):1–10
Wang A et al. (2022) Effects of sintering temperature on structural, magnetic and microwave absorption properties of Ni0. 5Zn0. 5Fe2O4 ferrites. J Magn Magn Mater 563:169958
Dogan N et al. (2022) Manganese doped-iron oxide nanoparticles and their potential as tracer agents for magnetic particle imaging (MPI). J Magn Magn Mater 561:169654
Velayutham L et al. (2022) Photocatalytic and Antibacterial Activity of CoFe2O4 Nanoparticles from Hibiscus rosa-sinensis Plant Extract. Nanomaterials 12(20):3668
Meibodi FS, Soori E (2022) Synthesis of magnetic nanoparticles (Fe3O4) coated with fatty acids and surfactants and their application in demulsification of crude oil-in-water emulsions. J Appl Res Water Wastewater 9(1):76–84
Cho H, Lee N, Kim BH (2022) Synthesis of Highly Monodisperse Nickel and Nickel Phosphide Nanoparticles. Nanomaterials 12(18):3198
Punia P et al. (2022) Synthesis and characterization of Ca substituted Ni-Zn nanoferrites-microstructural, magnetic and dielectric analysis. J Alloy Compd 928:167248
Naik CC, Salker A (2022) Fractional substitution of Mn ions in cobalt-copper ferrite: Effect on its magnetic, dielectric and microstructural properties. Inorg Chem Commun 142:109684
Malyshev A, Surzhikov A, Stary O (2022) Chemical homogeneity, microstructure and magnetic properties of LiTiZn ferrite ceramics doped with Al2O3 or ZrO2. J Alloy Compd 911:165005
Shayestefar M et al. (2022) Optimization of the structural and magnetic properties of MnFe2O4 doped by Zn and Dy using Taguchi method. J Magn Magn Mater 541:168390
Lu Y et al. (2022) Effect of Gd and Co contents on the microstructural, magneto-optical and electrical characteristics of cobalt ferrite (CoFe2O4) nanoparticles. Ceram Int 48(2):2782–2792
Hölscher J et al. (2020) Magnetic Property Enhancement of Spinel Mn–Zn Ferrite through Atomic. Inorganic Chem 59(15):11184–11192
Nairan A et al. (2022) Structural and temperature-dependent magnetic characteristics of Ho doped CoFe2O4 nanostructures. Ceram Int 48(21):32164–32172
Desoky W et al. (2022) Exploring the impact of nickel doping on the structure and low-temperature magnetic features of cobalt nano-spinel ferrite. Appl Phys A 128(9):1–14
Martinez-Vargas S et al. (2020) Enhancing the capacitance and tailoring the discharge times of flexible graphene supercapacitors with cobalt ferrite nanoparticles. Synth Met 264:116384
Martinez-Luevanos A et al. (2017) Effect of cobalt on the electrochromic properties of NiO films deposited by spray pyrolysis. Appl Phys A 123(5):349
Ati AA, Abdalsalam AH, Abbas HH (2022) Influence of annealing on structural, morphology, magnetic and optical properties of PLD deposited CuFe2O4 thin films. Inorganic Chem Commun 146:110072. https://doi.org/10.1016/j.inoche.2022.110072
Shanigaram M, Kodam U, Noh J-S, Nam Y-W (2022) Cation distribution in MFe2O4 (M= Ni, Co): X-ray diffraction, electron spectroscopy, Raman, and magnetization studies. J Phys Chem Solids 171:111036. https://doi.org/10.1016/j.jpcs.2022.111036
Mazrouei A, Saidi A (2018) Microstructure and magnetic properties of cobalt ferrite nano powder prepared by solution combustion synthesis. Mater Chem Phys 209:152–158
Abdullah M, Hasany S, Amir Qureshi M, Hussain S (2022) Cost-Effective Synthesis of Cobalt Ferrite Nanoparticles by Sol-Gel Technique. In Mater Sci Forum. Trans Tech Publ Ltd.: Bäch SZ, Switzerland, 1067:213–219
Li W et al. (2022) Comparison of copper and aluminum doped cobalt ferrate nanoparticles for improving biohydrogen production. Bioresour Technol 343:126078
Abbas N et al. (2020) Aluminum-doped cobalt ferrite as an efficient photocatalyst for the abatement of methylene blue. Water 12(8):2285
Aghav P et al. (2011) Effect of aluminum substitution on the structural and magnetic properties of cobalt ferrite synthesized by sol–gel auto combustion process. Phys B: Condens Matter 406(23):4350–4354
Gabal M et al. (2013) Influence of Al-substitution on structural, electrical and magnetic properties of Mn–Zn ferrites nanopowders prepared via the sol–gel auto-combustion method. Polyhedron 57:105–111
Gul I, Pervaiz E (2012) Comparative study of NiFe2− xAlxO4 ferrite nanoparticles synthesized by chemical co-precipitation and sol–gel combustion techniques. Mater Res Bull 47(6):1353–1361
Shirtcliffe NJ et al. (2007) Highly aluminium doped barium and strontium ferrite nanoparticles prepared by citrate auto-combustion synthesis. Mater Res Bull 42(2):281–287
Luo H et al. (2012) Physical and magnetic properties of highly aluminum doped strontium ferrite nanoparticles prepared by auto-combustion route. J Magn Magn Mater 324(17):2602–2608
Shim JH et al. (2006) Coexistence of ferrimagnetic and antiferromagnetic ordering in Fe-inverted zinc ferrite investigated by NMR. Phys Rev B 73(6):064404
Joshi S et al. (2014) Structural, magnetic, dielectric and optical properties of nickel ferrite nanoparticles synthesized by co-precipitation method. J Mol Struct 1076:55–62
Ponce A et al. (2013) High coercivity induced by mechanical milling in cobalt ferrite powders. J Magn Magn Mater 344:182–187
Ati AA et al. (2014) Structural and magnetic properties of Co–Al substituted Ni ferrites synthesized by co-precipitation method. J Mol Struct 1058:136–141
Dabagh S et al. (2015) Effect of Cu–Al substitution on the structural and magnetic properties of Co ferrites. Mater Sci Semiconductor Process 33:1–8
Xia A et al. (2013) Hydrothermal Mg1− xZnxFe2O4 spinel ferrites: Phase formation and mechanism of saturation magnetization. Mater Lett 105:199–201
Ali R et al. (2014) Structural, magnetic and dielectric behavior of Mg1− xCaxNiyFe2− yO4 nano-ferrites synthesized by the micro-emulsion method. Ceram Int 40(3):3841–3846
Oumezzine E et al. (2015) Structural, magnetic and magnetocaloric properties of Zn0. 6− xNixCu0. 4Fe2O4 ferrite nanoparticles prepared by Pechini sol-gel method. Powder Technol 278:189–195
Muthuselvam IP, Bhowmik R (2010) Mechanical alloyed Ho3+ doping in CoFe2O4 spinel ferrite and understanding of magnetic nanodomains. J Magn Magn Mater 322(7):767–776
Priya AS, Geetha D, Kavitha N (2019) Effect of Al substitution on the structural, electric and impedance behavior of cobalt ferrite. Vacuum 160:453–460
Tan X et al. (2022) Insights on perovskite-type proton conductive membranes for hydrogen permeation. Int J Hydrogen Energy. https://doi.org/10.1016/j.ijhydene.2022.08.244
Dabagh S et al. (2018) Study of structural phase transformation and hysteresis behavior of inverse-spinel α-ferrite nanoparticles synthesized by co-precipitation method. Results Phys 8:93–98
Sathiya Priya A, Geetha D, Kavitha N (2019) Effect of Al substitution on the structural, electric and impedance behavior of cobalt ferrite. Vacuum 160:453–460
Waldron R (1955) Infrared spectra of ferrites. Phys Rev 99(6):1727
Wahba AM, Mohamed MB (2014) Structural, magnetic, and dielectric properties of nanocrystalline Cr-substituted Co0. 8Ni0. 2Fe2O4 ferrite. Ceram Int, 40(4):6127–6135
Dabagh S, Haris SA, Ertas YN (2022) Synthesis, Characterization and Potent Antibacterial Activity of Metal-Substituted Spinel Ferrite Nanoparticles. J Cluster Sci. https://doi.org/10.1007/s10876-022-02373-9
Rath C et al. (1999) Preparation and characterization of nanosize Mn–Zn ferrite. J Magn Magn Mater 202(1):77–84
Rajendran M et al. (2001) Magnetic properties of nanocrystalline CoFe2O4 powders prepared at room temperature: variation with crystallite size. J Magn Magn Mater 232(1–2):71–83
Gilani ZA et al. (2015) Impacts of neodymium on structural, spectral and dielectric properties of LiNi0. 5Fe2O4 nanocrystalline ferrites fabricated via micro-emulsion technique. Phys E: Low-dimensional Syst Nanostruct 73:169–174
Kodama RH (1999) Magnetic nanoparticles. J Magn Magn Mater 200(1–3):359–372
Ahsan M, Khan F (2018) Structural and electrical properties of manganese doped cobalt ferrite nanoparticles. Mater Sci Nanotechnol 2(2):1. 2018. 9
Arifuzzaman M, Hossen MB (2020) Effect of Cu substitution on structural and electric transport properties of Ni-Cd nanoferrites. Results Phys 16:102824
Gul IH, Maqsood A (2008) Structural, magnetic and electrical properties of cobalt ferrites prepared by the sol–gel route. J Alloy Compd 465(1):227–231
Singh AK et al. (2002) Dielectric properties of Mn-substituted Ni–Zn ferrites. J Appl Phys 91(10):6626–6629
Shitre A et al. (2002) X-ray diffraction and dielectric study of Co1− xCdxFe2− xCrxO4 ferrite system. Mater Lett 56(3):188–193
Brockman FG, Dowling P, Steneck WG (1949) Anomalous behavior of the dielectric constant of a ferromagnetic ferrite at the magnetic curie point. Phys Rev 75(9):1440
Mangalaraja R et al. (2002) Magnetic, electrical and dielectric behaviour of Ni0. 8Zn0. 2Fe2O4 prepared through flash combustion technique. J Magn Magn Mater 253(1–2):56–64
Khatun N et al. (2021) Effect of sintering temperature on structural, magnetic, dielectric and optical properties of Ni–Mn–Zn ferrites. J Adv Dielectr 11(06):2150028
Waghmare SP, Borikar DM, Rewatkar KG (2017) Impact of Al doping on structural and Magnetic Properties of Co-Ferrite. Mater Today: Proc 4(11, Part 3):11866–11872
Shao L et al. (2021) Microstructure, XPS and magnetic analysis of Al-doped nickel–manganese–cobalt ferrite. J Mater Sci: Mater Electron 32(15):20474–20488
Thang PD, Rijnders G, Blank DH (2005) Spinel cobalt ferrite by complexometric synthesis. J Magn Magn Mater 295(3):251–256
Rafferty A, Prescott T, Brabazon D (2008) Sintering behaviour of cobalt ferrite ceramic. Ceram Int 34(1):15–21
Coey JMD (1971) Noncollinear spin arrangement in ultrafine ferrimagnetic crystallites. Phys Rev Lett 27(17):1140
Singhal S, Namgyal T, Bansal S, Chandra K (2010) Effect of Zn substitution on the magnetic properties of cobalt ferrite nano particles prepared via sol-gel route. J Electromagnetic Analys Appl 2(6):376–381
Cedeño-Mattei Y et al. (2008) Tuning of magnetic properties in cobalt ferrite nanocrystals. J Appl Phys 103(7):07E512-07E512-3
Yadav RS et al. (2015) Magnetic Properties of Dysprosium-Doped Cobalt Ferrite Nanoparticles Synthesized by Starch-Assisted Sol-Gel Auto-combustion Method. J Superconductivity Novel Magnetism 28:2097–2107
Yadav S et al. (2013) Structural, morphological, dielectrical, magnetic and impedance properties of Co 1− xMnxFe 2 O 4. J Alloy Compd 555:330–334
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Anukool, W., El-Nabulsi, R.A. & Dabagh, S. Effect of Al3+doping on dielectric properties of cobalt ferrite nanoparticle for using in high frequency applications. J Sol-Gel Sci Technol 105, 405–415 (2023). https://doi.org/10.1007/s10971-022-06029-y
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DOI: https://doi.org/10.1007/s10971-022-06029-y