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Sol–gel preparation of Fe and Al co-doped ZnO nanostructured materials

  • Original Paper: Sol-gel and hybrid materials for dielectric, electronic, magnetic and ferroelectric applications
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Abstract

Fe and Al co-doped ZnO nanoparticles have been synthesized by sol–gel method and annealed in air and vacuum atmospheres. The results of structural characterization show that the samples have wurtzite structure with no other impurity phases and the doping atoms have not disturbed the hexagonal lattice. Resistivity measurement confirms good conductivity through vacuum annealing. Furthermore, by investigating the magnetic properties, room temperature ferromagnetism has been observed. The saturation magnetization goes up to 1.4 emu/g by sintering the nanoparticles under vacuum. The results suggest that oxygen vacancies play the most important role in mediating the ferromagnetism.

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References

  1. Kaur P, Kumar S, Negi SN, Rao SM (2015) Enhanced magnetism in Cr-doped ZnO nanoparticles with nitrogen co-doping synthesized using sol–gel technique. Appl Nanosci 5:367–362

    Article  Google Scholar 

  2. Arshad M, Azam A, Ahmed AS, Mollah S, Naqvi AH (2011) Effect of Co substitution on the structural and optical properties of ZnO nanoparticles synthesized by sol–gel route. J Alloys Compd 509:8378–8381

    Article  Google Scholar 

  3. Liu H, Zhang X, Li LY, Wang YX, Gao KH, Li ZQ, Zheng RK, Ringer SP, Hang BZ, Zhang XX (2007) Role of point defects in room-temperature ferromagnetism of Cr-doped ZnO. Appl Phys Lett 91:072511

    Article  Google Scholar 

  4. Birajdar SD, Khirad PP, Humbe AV, Jadhav KM (2016) Presence of intrinsic defects and transition from diamagnetic to ferromagnetic state in Co2+ ions doped ZnO nanoparticles. J Mater Sci: Mater Electron 27:5575–5583

    Google Scholar 

  5. Mao XY, Zhong W, Du YW (2008) Ferromagnetism of Ni cluster in Ni-doped ZnO by solid state reaction. J Magn Magn Mater 320:1102–1105

    Article  Google Scholar 

  6. Shafiq MS, Furqan M, Atiq S, Saleem M, Riaz S, Naseem S (2016) Carriers mediated magnetic and impedance spectroscopic analysis of sol–gel synthesized Zn0 95-xMnxFe0 05O (0 ≤ x ≤ 0 05) DMSs. J Sol-Gel Sci Technol 79:353–542

    Article  Google Scholar 

  7. Ramachandran S, Narayan J, Prater JT (2006) Effect of oxygen annealing on Mn doped ZnO diluted magnetic semiconductors. Appl Phys Lett 88:242503

    Article  Google Scholar 

  8. Kumar P, Pandey PC (2016) Investigations on absorption photoluminescence and magnetic properties of ZnO: Co nanoparticles. J Sol-Gel Sci Technol 80:342–352

    Article  Google Scholar 

  9. Tong LN, Cheng T, Han HB, Hu JL, He XM, Tong Y, Schneider CM (2010) Photoluminescence studies on structural defects and room temperature ferromagnetism in Ni and Ni–H doped ZnO nanoparticles. J Appl Phys 108:023906

    Article  Google Scholar 

  10. Elilarassi R, Rao PS, Chandrasekaran G (2011) Diluted magnetic semiconductor properties in Zn1-xCuxO nanoparticles synthesized by sol gel route. J Sol-Gel Sci Technol 57:101–108

    Article  Google Scholar 

  11. Liu H, Cheng X, Liu X, Yang J, Liu Y, Liu X, Gao M, ZhanG X (2012) Properties of Cu and V co-doped ZnO nanoparticles annealed in different atmospheres. Superlattice Microst 52:1171–1177

    Article  Google Scholar 

  12. Kumar S, Tiwari N, Jha SN, Chatterjee S, Bhattacharyya D, Sahoo NK, Ghosh AK (2015) Insight into the origin of ferromagnetism in Fe-doped ZnO diluted magnetic semiconductor nanocrystals: an EXFAS study of local structure. RSC Adv 5:94658–94669

    Article  Google Scholar 

  13. Han J, Mantas PQ, Senos AMR (2001) Effect of Al and Mn doping on the electrical conductivity of ZnO. J Eur Ceram Soc 21:1883–1886

    Article  Google Scholar 

  14. Singh RPP, Hudiara IS, Panday S, Rana SB (2016) The effect of Co doping on the structural optical and magnetic properties of Fe-doped ZnO nanoparticles. J Supercond Nov Magn 30:819–827

    Article  Google Scholar 

  15. Siddheswaran R, Medlın R, Belsky P, Vavrunkova, Ocenasek J, David B, Sutta P (2014) Heterogeneous phase formation in diluted magnetic semiconducting Zn1-x-yCoxAlyO (CAZO) nanoparticles. RSC Adv 4:23405

    Article  Google Scholar 

  16. Chang GS, Kurmaev EZ, Boukhvalov DW, Finkelstein LD, Moewes A, Bieber H, Colis S, Dinia A (2009) Co and Al co-doping for ferromagnetism in ZnO:Co diluted magnetic semiconductors. J Phys Condens Matter 21:056002

    Article  Google Scholar 

  17. Liu Y, Yang Y, Yang J, Guan Q, Liu H, Yang L, Zhang Y, Wang Y, Wei M, Liu X, Fei L, Cheng X (2011) Intrinsic ferromagnetic properties in Cr-doped ZnO diluted magnetic semiconductors. J Solid State Chem 184:1273–1278

    Article  Google Scholar 

  18. Gilliland S, Segura A, Sánchez-Royo JF, García LM, Bartolomé F, Sans JA, Criado GM, Villacorta FJ (2010) Absence of ferromagnetism in single-phase wurtzite Zn1-xMnxO polycrystalline thin films. J Appl Phys 108:073922

    Article  Google Scholar 

  19. Ghanaatshoar M, Moradi M, Khodabandeh Z (2013) Magnetic and optical properties of Fe-doped SnO2 thin films prepared by electron beam evaporation technique. J Supercond Nov Magn 26:995–999

    Article  Google Scholar 

  20. Lu ZL, Hsu HS, Tzeng YH, Zhang FM, Du YW, Huang JCA (2009) The origins of ferromagnetism in Co-doped ZnO single crystalline films: from bound magnetic polaron to free carrier-mediated exchange interaction. Appl Phys Lett 95:102501

    Article  Google Scholar 

  21. Coey JMD, Venkatesan M, Fitzgerald CB (2005) Donor impurity band exchange in dilute ferromagnetic oxides. Nat Mater 4:173–179

    Article  Google Scholar 

  22. Buchholz DB, Chang RP, Song JY, Ketterson JB (2005) Room-temperature ferromagnetism in Cu-doped ZnO thin films. Appl Phys Lett 87:082504

    Article  Google Scholar 

  23. Yu CF, Lin TJ, Sun SJ, Chou H (2007) Origin of ferromagnetism in nitrogen embedded ZnO: N thin films. J Appl Phys 40:6497

    Google Scholar 

  24. Singhal RK, Sharma SC, Kumari P, Kumar S, Xing YT, Deshpande UP, Shripathi T, Saitovitch E (2011) Study of electronic structure and magnetization correlations in hydrogenated and vacuum annealed Ni doped ZnO. J Appl Phys 109:063907

    Article  Google Scholar 

  25. Mishra AK, Das D (2010) Investigation on Fe-doped ZnO nanostructures prepared by a chemical route. Mater Sci Eng B 171:5–10

    Article  Google Scholar 

  26. Kumar S, Kim YJ, Koo BH, Vargas JM, Knobel M, Gautam S, Chae KH, Kim DK, Kim YK, Lee CG (2009) Structural and magnetic properties of chemically synthesized Fe doped ZnO. J Appl Phys 105:07C520

    Article  Google Scholar 

  27. Ahn GY, Park SI, Kim CS (2007) Enhanced ferromagnetic properties of diluted Fe doped ZnO with an Al co-doping. Phys Stat Sol 204:4037–4040

    Article  Google Scholar 

  28. Wang X, Song Y, Tao LL, Feng LF, Sui Y, Tang J, Song B, Wang Y, Wang Y, Zhang Y, Han XF (2014) Origin of ferromagnetism in aluminum-doped TiO2 thin films: Theory and experiments. Appl Phys Lett 105:262402

    Article  Google Scholar 

  29. Vadivel M, Babu RR, Ramamurthi K (2014) Studies on the structural optical and magnetic properties of Al doped ZnO nanoparticles. Int J Chem Tech Res 7:1206–1211

    Google Scholar 

  30. Asemi M, Ghanaatshoar M (2017) Hydrothermal growth of one-dimensional Ce-doped TiO2 nanostructures for solid-state DSSCs comprising Mg-doped CuCrO2. J Mater Sci 52:489–503

    Article  Google Scholar 

  31. Asemi M, Ghanaatshoar M (2016) Controllable growth of vertically aligned Bi-doped TiO2 nanorod arrays for all-oxide solid-state DSSCs. J Appl Phys A 122:853

    Article  Google Scholar 

  32. Panigraphy B, Aslam M, Bahadur D (2010) Aqueous synthesis of Mn- and Co-doped ZnO nanorods. J Phys Chem C 114:11758–11763

    Article  Google Scholar 

  33. Asemi M, Ghanaatshoar M (2014) Preparation of CuCrO2 nanoparticles with narrow size distribution by sol-gel method. J Sol-Gel Sci Technol 70:416–421

    Article  Google Scholar 

  34. Sharma S, Kundu RS, Singh A, Murugavel S, Punia R, Kishore N (2015) Structural optical electrical and magnetic properties of Zn0 7MnxNi0 3-xO nanoparticles synthesized by sol-gel technique. Cogent Phys 2:1055623

    Article  Google Scholar 

  35. Vijayaprasath G, Murugan R, Asaithambi S, Anandha Babu G, Sakthivel P, Mahalingam T, Hayakawa Y, Ravi G (2016) Structural characterization and magnetic properties of Co co-doped Ni/ZnO nanoparticles. Appl Phys A 122:11

    Article  Google Scholar 

  36. Saleh R, Prakoso SP, Fishli A (2012) The influence of Fe doping on the structural magnetic and optical properties of nanocrystalline ZnO particles. J Magn Magn Mater 324:665–670

    Article  Google Scholar 

  37. Asemi M, Mameghani H, Ghanaatshoar M (2016) Preparation and characterization of all-oxide CuFeO2:Zn/ZnO:Al transparent heterojunction diode by using all-chemical solution deposition. J Sol-Gel Sci Technol 80:201–207

    Article  Google Scholar 

  38. Thangeeswari T, George AT, Kumar AA (2016) Optical properties and FTIR studies of cobalt doped ZnO nanoparticles by simple solution method. Indian J Sci Technol 9:1–4

    Article  Google Scholar 

  39. Rao KS, Vanaja T (2015) Influence of transition metal (Cu, Al) ions doping on structural and optical properties of ZnO nanopowders. Mater today proc 2:3743–3749

    Article  Google Scholar 

  40. Xiong G, Pal U, Serrano JG, Ucer KB, Williams RT (2006) Photoluminescence and FTIR study of ZnO nanoparticles: the impurity and defect perspective. Phys Stat Sol (c) 3:3577–3581

    Article  Google Scholar 

  41. Vanaja A, Ramaraju GV, Rao KS (2016) Structural and optical investigation of Al doped ZnO nanoparticles synthesized by sol-gel process. Indian J Sci Technol 9:1–6

    Article  Google Scholar 

  42. Hernandez S, Cauda V, Hidalgo D, Rivera VF, Manfredi D, Chiodoni A, Pirri FC (2014) Fast and low-cost synthesis of 1DZnO-TiO2 core-shell nanoarrays: characterization and enhanced photo-electrochemical performance for water splitting. J Alloys and Compd 615:S530–S537

    Article  Google Scholar 

  43. Asemi M, Ghanaatshoar M (2016) Conductivity improvement of CuCrO2 nanoparticles by Zn doping and their application in solid-state dye-sensitized solar cells. Ceram Int 42:6664–6672

    Article  Google Scholar 

  44. Verma KC, Kotnala RK (2016) Oxygen vacancy induced by La and Fe into ZnO nanoparticles to modify ferromagnetic ordering. J Solid State Chem 237:211–218

    Article  Google Scholar 

  45. Baek S, Song J, Lim S (2007) Improvement of the optical properties of ZnO nanorods by Fe doping. Physica B 399:101–102

    Article  Google Scholar 

  46. Lin CY, Wang YH, Lee CS, Sun KY, Suen YW (2009) Magnetophotoluminescence properties of Co-doped ZnO nanorods. Appl Phys Lett 94:151909

    Article  Google Scholar 

  47. Xiong G, Pal U, Serrano JG, Ucer KB, Williams RT (2006) Photoluminescence and FTIR study of ZnO nanoparticles: the impurity and defect perspective. Phys Stat Sol (c) 3:3577–3581

    Article  Google Scholar 

  48. Weng HM, Yang XP, Dong JM, Mizuseki H, Kawasaki M, Kawazoe Y (2004) Electronic structure and optical properties of the Co-doped anatase TiO2 studied from first principles. Phys Rev B 69:125219

    Article  Google Scholar 

  49. Sharma PK, Dutta RK, Pandey AC, Layek S, Verma HC (2009) Effect of iron doping concentration on magnetic properties of ZnO nanoparticles. J Magn Magn Mater 321:2587–2591

    Article  Google Scholar 

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Correspondence to Majid Ghanaatshoar.

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Jannesari, M., Asemi, M. & Ghanaatshoar, M. Sol–gel preparation of Fe and Al co-doped ZnO nanostructured materials. J Sol-Gel Sci Technol 83, 181–189 (2017). https://doi.org/10.1007/s10971-017-4397-9

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  • DOI: https://doi.org/10.1007/s10971-017-4397-9

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