Skip to main content
Log in

Photocatalytic activities of multiferroic bismuth ferrite nanoparticles prepared by glycol-based sol–gel process

  • Original Paper
  • Published:
Journal of Sol-Gel Science and Technology Aims and scope Submit manuscript

Abstract

The uniform multiferroic BiFeO3 nanoparticles with fairly narrow particle size distribution have been successfully synthesized by a simple glycol-based sol–gel route at relatively low temperature. The thus-prepared powders were characterized by X-ray diffractometry (XRD), thermogravimetric and differential thermal analysis (DTA/TG), and transmission electron microscopy (TEM). Rapid sintering and subsequently quenching to room temperature are the two vital important factors for the preparation of pure BiFeO3. The ferroelectric phase transition was determined by differential scanning calorimeter analysis (DSC), revealing the ferroelectric nature of the as-prepared BiFeO3 nanoparticles. The strong band-gap absorption at 2.55 eV and the enhanced photocatalytic activities of the BiFeO3 nanoparticles with H2O2 addition may bring some novel applications in water treatment field.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. Fiebig M, Lottermoser T, Fröhlich D, Goltsev A, Pisarev R (2002) Observation of coupled magnetic and electric domains. Nature 419:818–820

    Article  CAS  Google Scholar 

  2. Eerenstein W, Mathur N, Scott J (2006) Multiferroic and magnetoelectric materials. Nature 442:759–765

    Article  CAS  Google Scholar 

  3. Wang J, Neaton J, Zheng H, Nagarajan V, Ogale S, Liu B, Viehland D, Vaithyanathan V, Schlom D, Waghmare U, Spaldin N, Rabe K, Wuttig M, Ramesh R (2003) Epitaxial BiFeO3 multiferroic thin film heterostructures. Science 299:1719–1722

    Article  CAS  Google Scholar 

  4. Kimura T, Kawamoto S, Yamada I, Azuma M, Takano M, Tokura Y (2003) Magnetocapacitance effect in multiferroic BiMnO3. Phys Rev B 67:180401–180404

    Article  Google Scholar 

  5. Fischer P, Polomska M, Sosnowska I, Szymanksi M (1980) Temperature dependence of the crystal and magnetic structures of BiFeO3. J Phys C 13:1931

    Article  CAS  Google Scholar 

  6. Kubel F, Schmid H (1990) Structure of a ferroelectric and ferroelastic monodomain crystal of the perovskite BiFeO3. Acta Crystallogr Sect B 46:698–702

    Article  Google Scholar 

  7. Wang Y, Zhou L, Zhang M, Chen X, Liu J, Liu Z (2004) Room-temperature saturated ferroelectric polarization in BiFeO3 ceramics synthesized by rapid liquid phase sintering. Appl Phys Lett 84:1731–1733

    Article  CAS  Google Scholar 

  8. Park T, Papaefthymiou G, Viescas A, Moodenbaugh A, Wong S (2007) Size-dependent magnetic properties of single-crystalline multiferroic BiFeO3 nanoparticles. Nano Lett 7:766–772

    Article  CAS  Google Scholar 

  9. Mazumder R, Ghosh S, Mondal P, Bhattacharya D, Dasgupta S, Das N, Sen A, Tyagi A, Sivakumar M, Takami T, Ikuta H (2006) Particle size dependence of magnetization and phase transition near TN in multiferroic BiFeO3. J Appl Phys 100:033908–033916

    Article  Google Scholar 

  10. Achenbach G, James W, Gerson R (1967) Preparation of single-phase polycrystalline BiFeO3. J Am Ceram Soc 8:437–443

    Article  Google Scholar 

  11. Mahesh K, Palkar V, Srinivas K, Suryanarayana S (2007) Ferroelectricity in a pure BiFeO3 ceramic. Appl Phys Lett 76:2764–2766

    Google Scholar 

  12. Kim J, Kim S, Kim W (2005) Sol–gel synthesis and properties of multiferroic BiFeO3. Mater Lett 59:4006–4009

    Article  CAS  Google Scholar 

  13. Shetty S, Palkar V, Pinto R (2002) Size effect study in magnetoelectric BiFeO3 system. Pramana 58:1027–1030

    Article  CAS  Google Scholar 

  14. Das N, Majumdar R, Sen A, Maiti H (2007) Nanosized bismuth ferrite powder prepared through sonochemical and microemulsion techniques. Mater Lett 61:2100–2104

    Article  CAS  Google Scholar 

  15. Wei J, Xue D, Xu Y (2008) Photoabsorption characterization and magnetic property of multiferroic BiFeO3 nanotubes synthesized by a facile sol–gel template process. Scripta Mater 58:45–48

    Article  CAS  Google Scholar 

  16. Gao F, Yuan Y, Wang K, Chen X, Chen F, Liu J, Ren Z (2006) Preparation and photoabsorption characterization of BiFeO3 nanowires. Appl Phys Lett 89:102506–102508

    Article  Google Scholar 

  17. Liu H, Wang X (2008) Large electric polarization in BiFeO3 film prepared via a simple sol–gel process. J Sol-Gel Sci Technol 47:154–157

    Article  CAS  Google Scholar 

  18. Wang X, Zhang Y, Wu Z (2010) Magnetic and optical properties of multiferroic bismuth ferrite nanoparticles by tartaric acid-assisted sol–gel strategy. Mater Lett 64:486–488

    Article  CAS  Google Scholar 

  19. Chen J, Xing X, Watson A, Wang W, Yu R, Deng J, Yan L, Sun C, Chen X (2007) Rapid synthesis of multiferroic BiFeO3 single-crystalline nanostructures. Chem Mater 19:3598–3600

    Article  CAS  Google Scholar 

  20. Han J, Huang Y, Wu X, Wu C, Wei W, Peng B, Huang W, Goodenough J (2006) Tunable synthesis of bismuth ferrites with various morphologies. Adv Mater 18:2145–2148

    Article  CAS  Google Scholar 

  21. Wang Y, Xu G, Ren Z, Wei X, Weng W, Du P, Shen G, Han G (2007) Mineralizer-assisted hydrothermal synthesis and characterization of BiFeO3 nanoparticles. J Am Ceram Soc 90:615–2617

    Google Scholar 

  22. Chen C, Cheng J, Yu S, Chen L, Meng Z (2006) Hydrothermal synthesis of perovskite bismuth ferrite crystallites. J Cryst Growth 291:135–139

    Article  CAS  Google Scholar 

  23. Wang X, Lin Y, Jiang J (2011) Multiferroic bismuth ferrite nanoparticles: rapid sintering synthesis, characterization, and optical properties. Adv Mater Res 152–153:81–85

    Article  Google Scholar 

  24. Yu J, Koshikawa N, Arai Y, Yoda S, Saitou H (2001) Containerless solidification of oxide material using an electrostatic levitation furnace in microgravity. J Cryst Growth 231:568–576

    Article  CAS  Google Scholar 

  25. Kaczmarek W, Pajak Z, Polomska M (1975) Differential thermal analysis of phase transitions in (Bi1−xLax)FeO3 solid solution. Solid State Commun 17:807–810

    Article  CAS  Google Scholar 

  26. Yang H, Luo H, Wang H, Usov O, Suvorova N, Jain M, Feldmann D, Dowden P, Jia Q (2008) Rectifying current-voltage characteristics of BiFeO3/Nb-doped SrTiO3. Appl Phys Lett 92:102113–102115

    Article  Google Scholar 

  27. Wang X, Zhu J, Zhang Y, Jiang J, Wei S (2010) One-pot synthesis and optical properties of monodisperse ZnSe colloidal microspheres. Appl Phys A 99:651–656

    Article  CAS  Google Scholar 

  28. Yang X, Wang X, Zhang Z (2005) Synthesis and optical properties of single crystalline bismuth selenide nanorods via a convenient route. J Cryst Growth 3–4:566–570

    Article  Google Scholar 

  29. Nozik A, Memming R (1996) Physical chemistry of semiconductor—liquid interfaces. J Phys Chem 100:13061–13078

    Article  CAS  Google Scholar 

  30. Wang X, Lin Y, Ding X, Jiang J (2011) Enhanced visible-light-response photocatalytic activity of bismuth ferrite. J Alloy Compd 509:6585–6588

    Article  CAS  Google Scholar 

  31. Zhao W, Chen C, Li X, Zhao J (2002) Photodegradation of sulforhodamine-B dye in platinized titania dispersions under visible light irradiation: influence of platinum as a functional co-catalyst. J Phys Chem B 106:5022–5028

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was supported by the National Natural Science Foundation of China (21001064), the National Natural Science Foundation of Jiangsu Province (BK201022267), the Specialized Research Fund for the Doctoral Program of Higher Education of China (20103219120045) and the Outstanding Scholars Supporting Program of NUST.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to X. Wang.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Wang, X., Lin, Y., Zhang, Z.C. et al. Photocatalytic activities of multiferroic bismuth ferrite nanoparticles prepared by glycol-based sol–gel process. J Sol-Gel Sci Technol 60, 1–5 (2011). https://doi.org/10.1007/s10971-011-2542-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10971-011-2542-4

Keywords

Navigation