Abstract
In this paper we review our research work of the last few years on the synthesis and the gas sensing properties of nanocomposite thin films of sensitive materials with a large specific surface area, which consist of porous matrices containing functional nanocrystals of metal oxides and gold. The film porosity provides a path for the gas molecules to reach the active reaction sites on the nanoparticles surface undergoing chemical reactions which nature depends on the nature of the active material. The introduction of Au nanoparticles affects the reactions mechanism improving the sensing process, moreover the Au Surface Plasmon Resonance peak can be used for the realization of selective optical gas sensor. Two different synthetic approaches will be described, each of them characterized by a peculiar control of the final materials morphology, structure and micro-structure.
Similar content being viewed by others
References
Eranna G, Joshi BC, Runthala DP, Gupta RP (2004) Crit Rev Solid State Mater Sci 29:111
Capone S, Forleo A, Francioso L, Rella R, Siciliano P, Spadavecchia J, Presicce DS, Taurino AM (2003) J Optoelectron Adv Mater 5:1335
Feng CD, Shimizu Y, Egashira M (1994) J Electrochem Soc 141:220
Horrillo MC, Serventi A, Rickerby D, Gutiérrez J (1999) Sens Actuators B 58:474
Kennedy MK, Kruis FE, Fissan H, Nienhaus H, Lorke A, Metzger TH (2005) Sens Actuators B 108:62
Carotta MC, Cervi A, di Natale V, Gherardi S, Giberti A, Guidi V, Puzzovio D, Vendemiati B, Martinelli G, Sacerdoti M, Calestani D, Zappettini A, Zha M, Zanotti L (2009) Sens Actuators B 137:164
Gurlo A (2011) Nanoscale 3:154
Kohl D (1990) Sens Actuators B 1:158
Ando M, Kobayashi T, Haruta M (1997) Catal Today 36:135
Martucci A, Pasquale M, Guglielmi M, Post M, Pivin JC (2003) J Am Cer Soc 86:1638
Martucci A, Buso D, De Monte M, Guglielmi M, Cantalini C, Sada C (2004) J Mater Chem 14:2889
van de Hulst HC (1981) Light scattering by small particles. Dover, New York
Buso D, Guglielmi M, Martucci A, Mattei G, Mazzoldi P, Sada C, Post ML (2006) Nanotechnology 17:2429
Mattei G, Mazzoldi P, Post ML, Buso D, Guglielmi M, Martucci A (2007) Adv Mater 19:561
Buso D, Guglielmi M, Martucci A, Mattei G, Mazzoldi P, Sada C, Post ML (2008) Cryst Growth Des 8(2):744
Almeida RM, Pantano CG (1990) J Appl Phys 68(8):4225
Lide DR (2007) Handbook of chemistry and physics, 84th edn. CRC Press, Boca Raton, pp 3–562
Rodriguez JA, Hanson JC, Frenkel AI, Kim JY, Pérez M (2002) J Am Chem Soc 124:346
Hotovy I, Huran J, Siciliano P, Capone S, Spiess L, Rehacek V (2004) Sens Actuators B 103:300
Matsumiya M, Qiu F, Shin W, Izu N, Murayama N, Kanzaki S (2002) Thin Solid Films 419:213
Buso D, Busato G, Guglielmi M, Martucci A, Bello V, Mazzoldi P, Mattei G, Post ML (2007) Nanotechnology 18(47):1
Della Gaspera E, Buso D, Guglielmi M, Martucci A, Bello V, Mattei G, Post M, Cantalini C, Agnoli S, Granozzi G, Sadek A, Kalantar-zadeh K, Wlodarski W (2010) Sens Actuators B 143:567
Hagleitner C, Hierlemann A, Lange D, Kummer A, Kerness N, Brand O, Baltes H (2001) Nature 414:293
Della Gaspera E, Guglielmi M, Agnoli S, Granozzi G, Post ML, Bello V, Mattei G, Martucci A (2010) Chem Mater 22:3407
Xiao T, An L, Zhang W, Sheng S, Xiong G (1992) Catal Lett 12:287
Zhang H, Banfield JF (2000) J Phys Chem B 104:3481
Della Gaspera E, Pujatti M, Guglielmi M, Post ML, Martucci A (2011) Mater Sci Eng B 176:716
Lee D, Rubner MF, Cohen RE (2006) Nano Lett 6:2305
See the website www.radiello.com for details
Sellers H, Ulman A, Shnidman Y, Eilers JE (1993) J Am Chem Soc 115:9389
Della Gaspera E, Guglielmi M, Giallongo G, Agnoli S, Granozzi G, Quaglio F, Martucci A (2011) Sens Lett 9:591
Buso D, Pacifico J, Martucci A, Mulvaney P (2007) Adv Funct Mater 17:347
Hache F, Richard D, Flytzanis C, Kreibig K (1988) Appl Phys A 47:347
Aramendía MA, Marinas A, Marinas JM, Moreno JM, Urbano FJ (2005) Catal Today 101:187
Turkevich J (1951) Discuss Farad Soc 11:55
Buso D, Post ML, Cantalini C, Mulvaney P, Martucci A (2008) Adv Funct Mater 18(23):3843
Manera MG, Spadavecchia J, Buso D, de Julian Fernandez C, Mattei G, Martucci A, Mulvaney P, Perez-Juste J, Rella R, Vasanelli L, Mazzoldi P (2008) Sens Actuators B 132:107
Sun Y, Xia Y (2002) Science 298:2176
Habas SE, Lee H, Radmilovic V, Somorjai GA, Yang P (2007) Nat Mater 6:692
Park J, An K, Hwang Y, Park JG, Noh HJ, Kim JY, Park JH, Hwang NM, Hyeon T (2004) Nature Mater 3:891
Kwon SG, Hyeon T (2008) Acc Chem Res 41:1696
Niederberger N, Pinna N (2008) Angew Chem Int Ed 47:5292
Antonello A, Brusatin G, Guglielmi M, Bello V, Mattei G, Zacco G, Martucci A (2011) J Nanoparticles Res 13:1697
Della Gaspera E, Antonello A, Guglielmi M, Post ML, Bello V, Mattei G, Romanato F, Martucci A (2011) J Mater Chem 21(12):4293
Acknowledgments
This work has been supported trough Progetto Strategico PLATFORMS of Padova University and 7FP EU Project—ORION #222517. E.D.G. thanks Fondazione CARIPARO for financial support.
Author information
Authors and Affiliations
Corresponding author
Additional information
Enrico Della Gaspera and Dario Buso contributed equally to this work.
Rights and permissions
About this article
Cite this article
Della Gaspera, E., Buso, D. & Martucci, A. Gold nanoparticles to boost the gas sensing performance of porous sol–gel thin films. J Sol-Gel Sci Technol 60, 366–377 (2011). https://doi.org/10.1007/s10971-011-2493-9
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10971-011-2493-9