Abstract
The condensation reaction of 3-methacryloxypropyl-trimethoxysilane (MPTS) and diisobutylsilanediol (DIBSD) in a non-hydrolytic sol-gel process was investigated in terms of the reaction time and the catalyst amount for fabrication of inorganic-organic hybrid materials. The degree of condensation, which was characterized by 29Si NMR, 1H NMR and Abbe refractometry, increases with increased the reaction time and greater catalyst amount. However, a the large catalyst amount breaks the methacryl group during the condensation reaction. Thus, the reaction time and the catalyst amount were optimized to synthesize the condensed methacryl oligosiloxanes.
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Nam, KH., Lee, TH., Bae, BS. et al. Condensation reaction of 3-(methacryloxypropyl)-trimethoxysilane and diisobutylsilanediol in non-hydrolytic sol-gel process. J Sol-Gel Sci Technol 39, 255–260 (2006). https://doi.org/10.1007/s10971-006-7884-y
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DOI: https://doi.org/10.1007/s10971-006-7884-y