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Gamma radiation induced modification in metal–organic framework: a case study

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Abstract

In the present manuscript, we report the synthesis of Zn-BDC MOF using a modified solvothermal method. As synthesized Zn-BDC MOF is exposed to gamma (γ) radiation doses, the dose exposure is between 0 and 50 kGy. It is observed that γ radiations are probably absorbed by zinc metal, and due to adsorption of γ the structure of the MOF is not changing, which suggests that the MOF structure regains its structural stability at higher γ radiation doses. Further, for the first time, we reported that the stability of Zn-BDC MOF is up to 35 kGy, it has been observed that, there is an irradiation effect on the higher porosity of MOF. The present findings strongly suggest the radiation-sensitive nature of Zn-BDC MOF.

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Acknowledgements

The authors would also like to thank Fergusson College (Autonomous), Pune, and Savitribai Phule Pune University for their kind financial assistance and support throughout the experiments.

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Authors and Affiliations

  1. Department of Physics, Fergusson College (Autonomous), Pune, 411004, India

    Suryaji N. Mane & Kailash B. Sapnar

  2. PDEA’s, Annasaheb Waghire College of Science, Arts & Commerce, Otur, Pune, M.S., 412409, India

    Sadhu K. Kolekar

  3. Department of Physics, Savitribai Phule Pune University, Pune, 411007, India

    Sanjay D. Dhole

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  1. Suryaji N. Mane
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  3. Kailash B. Sapnar
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Correspondence to Sadhu K. Kolekar or Kailash B. Sapnar.

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Mane, S.N., Kolekar, S.K., Sapnar, K.B. et al. Gamma radiation induced modification in metal–organic framework: a case study. J Radioanal Nucl Chem (2024). https://doi.org/10.1007/s10967-024-09430-9

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