Abstract
A spectrophotometric method has been developed for the estimation of di-butyl phosphate present in a solution of TBP in n-DD. The quantitative conversion of NaDBP brought from TBP phase in to phosphate ion was achieved in a single-step digestion with potassium peroxo di-sulfate in dilute sulfuric acid solution at 400–410 K. The concentration of the resultant phosphate ion and equivalent HDBP was determined in the form of ammonium molybdo phosphate by spectrophotometry. The accuracy and precision of this method was found to be less than ± 6.4% for the HDBP concentration ranging from 30 to 200 mg/L in the organic sample.
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References
Schulz WW, Burger LL, Navratil JD (1990) Science and technology of tributyl phosphate, applications of tributyl phosphate in nuclear fuel processing, vol 3. CRC Press, FL
Natarajan R, Raj B (2007) Fast reactor fuel reprocessing technology in India. J Nucl Sci Technol 44(3):393–397
Amber W, Patricia PH (2010) Review of physical and chemical properties of tri butyl phosphate/diluent/nitric acid systems. Sep Sci Technol 45:1753–1762
Schulz WW, Navratil JD (1984) Science and technology of tributyl phosphate. Synthesis, properties, reactions and analysis, vol 1. CRC Press, Boca Raton
Kuno Y, Hina T (1992) Degradation of tributyl phosphate in plutonium nitrate solution. J Nucl Sci Technol 29(8):762–767
Natarajan R (1998) Challenges in fast reactor fuel reprocessing. IANCAS Bull 14(2):27–32
Mishra S, Chandan M, Patra C, Vishnu Anand P, Puspalata R, Sivakumar D, Desigan N, Dhamodharan K, Velavendan P, Rajeev R, Venkatesan KA, Ananthasivan K (2022) Comparison of the performance of solvent wash reagents used for the primary clean-up of degraded PUREX solvent. Radiochim Acta 111(1):53–62
Uetak N (1989) Precipitation formation of zirconium-dibutyl phosphate complex in purex process. J Nucl Sci Technol 26(3):329–338
Natarajan R, Baldev R (2015) Technology development of fast reactor fuel reprocessing in India. Curr Sci 108:30–38
Ramanujam A, Gopalkrishna V, Venkatesan M, Kazi JA, Nadkarni MN (1980–1981) Titrimetric estimation of dibutyl phosphate in highly degraded tributyl phosphate samples. In: Proceedings of the nuclear chemistry and radiochemistry symposium (held at) Waltair, February 25–28
Apelbalt A, Azoulay D (1973) Determination of monobutyl phosphate and dibutyl phosphate in tributyl phosphate. J Inorg Nucl Chem 35(11):3938–3940
Hardy CJ (1964) Analysis of alkyl esters of phosphoric acid by gas chromatography. J Chromatogr A 13:372–376
Brignocchi A, Gasparini GM (1973) The gas chromatographic determination of the decomposition products of tributyl phosphate. Analyt Lett 6(6):523–530
Glastrup J (1998) Diazomethane preparation for gas chromatographic analysis. J Chromatogr A 827(1):133–136
Velavendan P, Ganesh S, Pandey NK, Kamachi Mudali U, Natarajan R (2012) Comparative studies on the determination of di-n-butyl phosphate in degraded solvent of PUREX process by ion chromatography and gas chromatography methods. Desalin Water Treat 49(1–3):123–129
Grant KE, Mong GM, Clauss SA, Wahl KL, Cmpbell JA (1997) Determination of monobutyl phosphate and dibutyl phosphate in mixed hazardous wastes by ion-pair chromatography. J Radioanal Nucl Chem 220:31–35
Lamouroux C, Virelizier H, Moulin C, Tabet JC, Jankowski CK (2000) Direct determination of dibutyl and monobutyl phosphate in a tributyl phosphate/nitric aqueous-phase system by electrospray mass spectrometry. J Anal Chem 72(6):1186–1191
Ridal JJ, Moore RM (1990) A re-examination of the measurement of dissolved Organic phosphorus in seawater. Mar Chem 29:19–31
Sherrell CG, Saunders WMH (1966) An evaluation of methods for the determination of total phosphorus in soils. N Z J Agric Res 9(4):972–979
Worsfold P, McKelvie I, Monbet P (2016) Determination of phosphorus in natural waters: a historical review. Anal Chim Acta 918:8–20
Cembella AD, Antia NJ, Taylor FJR (1986) The determination of total phosphorus in seawater by nitrate oxidation of the organic component. Water Res 20(9):1197–1199
Pujo-Pay M, Raimbault P (1994) Improvement of the wet-oxidation procedure for simultaneous determination of particulate organic nitrogen and phosphorus collected on filters. Mar Ecol Prog Ser 105:203–207
Woo L, Maher W (1995) Determination of phosphorus in turbid waters using alkaline potassium peroxo disulphate digestion. Anal Chim Acta 315(1–2):123–135
Huang X-L, Zhang J-Z (2009) Neutral persulfate digestion at sub-boiling temperature in an oven for total dissolved phosphorus determination in natural waters. Talanta 78(3):1129–1135
Saien J, Jafari F (2022) Methods of persulfate activation for the degradation of pollutants: fundamentals and influencing parameters. In: Persulfate-based oxidation proces in environmental remediation, Chapter 1, RCS Book series, Chemistry in the environment, pp 1–59
Lee C, Kim H-H, Park N-B (2018) Chemistry of persulfates for the oxidation of organic contaminants in water. Membrane Water Treat 9(6):405–419
Xia YX, Friese JI, Moore DA, Bachelor PP, Rao L (2007) Complexation of plutonium (IV) with sulfate at variable temperatures. J Radioanal Nucl Chem 274(1):79–86
Kuno Y, Hina T, Akiyama T, Matsui M (1991) Simultaneous determination of tributyl phosphate and dibutyl phosphate in spent fuel reprocessing streams by gas chromatography. J Chromatogr A 537:489–493
Ganesh S, Khan F, Ahmed MK, Velavendan P, Pandey NK, Kamachi MU (2012) Spectrophotometric determination of trace amounts of phosphate in water and soil. Water Sci Technol 66(12):2653–2658
Lee J, von Gunten U, Kim J-H (2020) Persulfate-based advanced oxidation: critical assessment of opportunities and road blocks. Environ Sci Technol 54:3064–3081
Jurg Holgnd and Helnz Bader (1987) Nitrate-induced photo oxidation of trace organic chemicals in water. Environ Sci Technol 21(5):443–450
Wu Y, Bu L, Duan X, Zhu S, Kong M, Zhu N, Zhou S (2020) Mini review on the roles of nitrate/nitrite in advanced oxidation process: radicals transformation and products formation. J Clean Product 273:123065
Gao Y, Champagne P, Blair D, He O, Song T (2020) Activated persulfate by iron-based materials used for refractory organics degradation a review. Water Sci Technol 81(5):853–875
Kolthoff IM, Miller IK (1951) The chemistry of persulfate: the kinetics and mechanism of the decomposition of the persulfate ion in aqueous medium. J Am Chem Soc 73(7):3055–3059
Nagul EA, McKelvie ID, Worsfold P, Koleva SD (2015) The molybdenum blue reaction for the determination of orthophosphate revisited: Opening the black box. Anal Chim Acta 890:60–82
Acknowledgements
Authors are highly indebted to Dr. K. A. Venkatesan, Head PRCRRD, Reprocessing group, IGCAR for the valuable suggestion and guidance during the preparation of this manuscript. The valuable contributions of Mr. D. Shravan Kumar, Mrs. S. Poongodi & Mrs. M. Usha during the course of the experimental works are sincerely acknowledged.
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Aneesh, T., Devi, S.S., Chandran, N. et al. Spectrophotometric determination of di-butyl phosphate in PUREX solvent using peroxo disulfate as oxidizing agent. J Radioanal Nucl Chem 332, 2725–2732 (2023). https://doi.org/10.1007/s10967-023-08941-1
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DOI: https://doi.org/10.1007/s10967-023-08941-1