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Determination of chemical elements in two Algerian bentonites by k0-NAA and WDXRF techniques

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Abstract

To perform a complete chemical analysis of two Algerian bentonites Mag and Mos, k0-NAA and WDXRF techniques were used. The concentration values of thirty seven elements including ten rare earth elements (REE) have been determined. The k0-NAA results indicate that the concentration of trace elements is respectively 290 and 285 mg/kg for Mag and Mos. The content of REE is greater in Mos 176 mg/kg than in Mag 87 mg/kg. The values of SiO2/Al2O3 in Mos and Mag were found to be 4.5 and 2.8 respectively. The high proportion of transition elements in Mag (38%) shows a more reductive character compared to Mos (29%). In addition Mag is more affected by anthropogenic activity than Mos due to content of As and Sb.

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References

  1. Brown TJ, Idoine NE, Raycraft ER, Shaw RA, Everett P, Deady EA, Bide T (2018) World mineral production 2012–2016

  2. Boualla N, Adjdir M (2019) Relation ship between Na activated Ca-bentonite on experimental study on the swelling behavior of expansive soil. In: 1st International congress on advances in geotechnical engineering and construction management ICAGECM’19. p 116

  3. Benaissa M, Bendani K, Belas N, Missoum, H (2016) Effet de l’ajout de la bentonite sur les propriétés des mortiers et des bétons autoplaçants. Matériaux Techn 104:608

    Article  CAS  Google Scholar 

  4. Benyounes K, Mellak A, Benchabane A (2010) The effect of carboxymethylcellulose and xanthan on the rheology of bentonite suspensions. Energy Sour Part A Recover Utilization Environ Eff 32:1634–1643

    Article  CAS  Google Scholar 

  5. Arbaoui F, Boucherit MN (2014) Comparison of two algerian bentonites: Physico-chemical and retention capacity study. Appl Clay Sci 91:6–11

    Article  Google Scholar 

  6. Arbaoui F, Amzert SA, Boucherit MN (2017) Corrosion of a carbon steel covered by treated bentonites in aqueous solution. J Fundamental Appl Sci 9:1300–1319

    Article  CAS  Google Scholar 

  7. Ararem A, Bouras O, Arbaoui F (2011) Adsorption of caesium from aqueous solution on binary mixture of iron pillared layered montmorillonite and goethite. Chem Eng J 172:230–236

    Article  CAS  Google Scholar 

  8. Hamoudi SA, Hamdi B, Brendlé J (2021) Tetracycline removal from water by adsorption on geomaterial, activated carbon and clay adsorbents. Ecol Chem Eng S 28:303–328

    CAS  Google Scholar 

  9. Youcef L (2021) Optimization of process conditions to improve copper adsorption capacity of raw and treated algerian bentonite: characterization, kinetics and equilibrium study. Indian J Chem Technol (IJCT) 28:249–261

    Google Scholar 

  10. Feddal I, Mimanne G, Dellani A, Taleb S (2021) Synthesis and characterization of an adsorbent material: application to textile dye elimination. Materials Today: Proceedings

  11. Mesboua N, Benyounes K, Benmounah A (2018) Study of the impact of bentonite on the physico-mechanical and flow properties of cement grout. Cogent Eng 5:1446252

    Article  Google Scholar 

  12. Benyounes K (2019) Rheological behavior of cement-based grout with algerian bentonite. SN Appl Sci 1:1–8

    Article  Google Scholar 

  13. Maske MM, Patil NK, Katdare AD (2021) Review of application of plain and calcined bentonite as a cement blending material in concrete and mortar. Psychol Educ J 58:5873–5878

    Google Scholar 

  14. Babahoum N, Ould Hamou M (2021) Characterization and purification of algerian natural bentonite for pharmaceutical and cosmetic applications. BMC Chem 15:1–11

    Article  Google Scholar 

  15. Khalaf H, Bouras O, Perrichon V (1997) Synthesis and characterization of Al-pillared and cationic surfactant modified Al-pillared algerian bentonite. Microporous Mater 8:141–150

    Article  CAS  Google Scholar 

  16. Hadj Bachir D, Khalaf H, Ferroukhi S, Boutoumi Y, Schnee J, Gaigneaux EM (2020) Preparation and characterization of TiO2 pillared clay: effect of palladium and photosensitizer on photocatalytic activity. Res J Chem Environ V24(3):1–14

    Google Scholar 

  17. Kumari N, Mohan C (2021) Basics of clay minerals and their characteristic properties. In: Clay and clay minerals. IntechOpen

  18. Bojarska K, Bzowski Z (2020) Monitoring analysis of major and trace elements in hard coal waste by XRF and ICP methods. In: Mine Planning and Equipment selection 1997. CRC Press, London, pp 835–838

  19. Waheed S, Rahman S, Faiz Y, Siddique N (2012) Neutron activation analysis of essential elements in Multani mitti clay using miniature neutron source reactor. Appl Radiat Isot 70:2362–2369

    Article  CAS  PubMed  Google Scholar 

  20. Ferriday T, Montenari M (2016) Chemostratigraphy and chemofacies of source rock analogues: a high-resolution analysis of black Shale successions from the lower silurian formigoso formation (cantabrian mountains, NW Spain). In: Stratigraphy & Timescales, Elsevier, pp 123–255

    Google Scholar 

  21. Nizio KD, Harynuk JJ (2012) Analysis of alkyl phosphates in petroleum samples by comprehensive two-dimensional gas chromatography with nitrogen phosphorus detection and post-column deans switching. J Chromatogr A 1252:171–176

    Article  CAS  PubMed  Google Scholar 

  22. Declercq Y, Delbecque N, De Grave J, De Smedt P, Finke P, Mouazen AM, Nawar S, Vandenberghe D, Van Meirvenne M, Verdoodt A (2019) A comprehensive study of three different portable XRF scanners to assess the soil geochemistry of an extensive sample dataset. Remote Sens 11:2490

    Article  Google Scholar 

  23. Révay Z, Kennedy G (2012) Application of the k0 method in neutron activation analysis and in prompt gamma activation analysis. Radiochim Acta 100:687–698

    Article  Google Scholar 

  24. Czichos H, Saito T, Smith LE (2011) Springer handbook of metrology and testing. Springer, Berlin

    Book  Google Scholar 

  25. Hamidatou L (2010) Doctorate Thesis. Fehhat Abbes University of Sétif, Algeria.

  26. Hamidatou L, Slamene H, Akhal T, Zouranen B (2013) Concepts, instrumentation and techniques of neutron activation analysis. Imaging and radioanalytical techniques in interdisciplinary research—Fundamentals and cutting edge applications, InTech, Rijeka, pp 141–178

  27. Mansouri A, Keskas S, Azli T, Bouhila Z, Hamidatou L, Slamene H, Benamar MEA (2021) Instrumental neutron activation analysis (INAA) of zinc concentrations in scalp hair and fingernails samples of Algerian females with breast cancer. Radiochim Acta 109:915–923

    Article  CAS  Google Scholar 

  28. Salima B, Abdelhak B (2013) Geology, mineralogy, and chemistry of the M’zila bentonitic clay deposit (Mostaganem, NW Algeria). Arab J Geosci 6:2165–2172

    Article  CAS  Google Scholar 

  29. Alghem Hamidatou L, Ramdhane M (2008) Characterization of neutron spectrum at Es-Salam research reactor using Høgdahl convention and Westcott formalism for the k0-based neutron activation analysis. J Radioanal Nucl Chem 278:627–630

    Article  CAS  Google Scholar 

  30. De Corte F (2001) The standardization of standardless NAA. J Radioanal Nucl Chem 248:13–20

    Article  Google Scholar 

  31. Jacimovic R (2003) Aggregate Thesis. University Ljubljiana, Slovenia.

  32. Dung H, Cho S (2003) A simple method for a determination. J Radioanal Nucl Chem 257:573–575

    Article  CAS  Google Scholar 

  33. Dung H, Sasajima F (2003) Determination of α and f for k0-NAA in irradiation sites with high thermalized neutrons. J Radioanal Nucl Chem 257:509–512

    Article  CAS  Google Scholar 

  34. Liu X, Lu X, Wang R, Meijer, E. J, Zhou, H (2011) Acidities of confined water in interlayer space of clay minerals. Geochim Cosmochim Acta 75:4978–4986

    Article  CAS  Google Scholar 

  35. Sadran G, Bonifas M, Millot G (1955) Sur l’origine des gisements de bentonites de Lalla Maghnia (Oran). Publications du service de la carte géologique de l’Algérie

  36. Chung C-Y (1994) Doctorate Thesis. New Jersey Institute of Technology, USA.

  37. Elbaz-Poulicheet F, Nagy A, Cserny T (1997) The distribution of redox sensitive elements (U, as, Sb, V and Mo) along a river-wetland-lake system (Balaton Region, Hungary). Aquat Geochem 3:267–282

    Article  Google Scholar 

  38. Nagarajan R, Madhavaraju J, Nagendra R, Armstrong-Altrin JS, Moutteet (2007) Geochemistry of neoproterozoic shales of the Rabanpalli formation, Bhima Basin, Northern Karnataka, southern India: implications for provenance and paleoredox conditions. Revista mexicana de ciencias geológicas 24:150–160

    Google Scholar 

  39. McDonough, WF, Sun, SS (1995). The composition of the Earth. Chemical geology, 120(3–4), 223–253.

    Article  CAS  Google Scholar 

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Acknowledgements

Authors wish to acknowledge the support of the colleagues of the NAA group in nuclear research centre of Birine in Algeria. As well as our colleagues from the nuclear research centre of Algiers for their contribution in WDXRF analysis.

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Correspondence to Lylia Hamidatou.

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Hamidatou, L., Arbaoui, F., Boucherit, M.N. et al. Determination of chemical elements in two Algerian bentonites by k0-NAA and WDXRF techniques. J Radioanal Nucl Chem 332, 573–580 (2023). https://doi.org/10.1007/s10967-023-08787-7

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