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Experimental study of ruthenium volatilization from boiling nitric solution

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Abstract

As part of study of the volatilization ruthenium behaviour in a boiling nitric solution, this paper presents the results of experiments dealing with the influence of different parameters (Ru and HNO3 concentrations, temperature, water addition) and the effect of in-situ inhibitors to mitigate potential releases. The amount of Ru volatilized from a nitric solution heated at 130 °C is about 2% of initial inventory. The addition of a low amount of inhibitors allowed to prevent ruthenium volatilization. Alternative strategies examined to restrict volatilization are the temperature decrease and the “water feed”, this later is more efficient.

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Acknowledgements

This work was performed in the French Institut de Radioprotection et de Sûreté Nucléaire (IRSN), with the financial support of ORANO Cycle.

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  1. PSN-RES, Institut de Radioprotection et de Sûreté Nucléaire (IRSN), BP 3, 13115, Saint-Paul-Lez-Durance Cedex, France

    Marie-Noëlle Ohnet, Karine Boucault, Philippe Nerisson, Thibault Bagnol & Laurent Cantrel

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  1. Marie-Noëlle Ohnet
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  2. Karine Boucault
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  3. Philippe Nerisson
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  4. Thibault Bagnol
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  5. Laurent Cantrel
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Correspondence to Marie-Noëlle Ohnet.

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Ohnet, MN., Boucault, K., Nerisson, P. et al. Experimental study of ruthenium volatilization from boiling nitric solution. J Radioanal Nucl Chem 331, 2939–2953 (2022). https://doi.org/10.1007/s10967-022-08351-9

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  • DOI: https://doi.org/10.1007/s10967-022-08351-9

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