Skip to main content
Log in

Separation of no-carrier-added 71,72As from 46 MeV alpha particle irradiated Ga2O3 target by TK200 and DGA-N resins

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

No-carrier-added (NCA) 71,72As radionuclides were produced by irradiating gallium oxide target with 46 MeV alpha-beam. 71,72As were separated from the target matrix by solid liquid extraction (SLX) using TK200 and DGA-N resins based on trioctylphosphine oxide and N,N,N,N-tetra-n-octyldiglycolamide, respectively. Both the resins selectively extracted Ga at higher acidic concentrations, leaving behind NCA As radioisotopes in the aqueous medium. The best conditions for separation obtained for the resins were at TK200 + 4 M HCl and DGA-N + 4 M HCl with separation factors of 6 × 105 and 1.6 × 106, respectively.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. Boerman OC, Oyen WJ (2011) Immuno PET of cancer: a revival of antibody imaging. J Nucl Med 52:1171–1172

    Article  Google Scholar 

  2. Kim JS (2016) Combination radioimmunotherapy approaches and quantification of immuno-PET. Nucl Med Mol Imag 50:104–111

    Article  CAS  Google Scholar 

  3. Naskar N, Lahiri S (2021) Theranostic terbium radioisotopes: challenges in production for clinical application. Front Med. https://doi.org/10.3389/fmed.2021.675014

    Article  Google Scholar 

  4. Guin R, Das SK, Saha SK (1998) Separation of carrier-free arsenic from germanium. J Radioanal Nucl Chem 227:181–183

    Article  CAS  Google Scholar 

  5. Jennewein M, Qaim SM, Hermanne A, Jahn M, Tsyganov E, Slavine N, Seliounine S, Antich PA, Kulkarni PV, Thorpe PE, Mason RP (2005) A new method for radiochemical separation of arsenic from irradiated germanium oxide. Appl Radiat Isot 63:343–351

    Article  CAS  Google Scholar 

  6. Bokhari TH, Mushtaq A, Khan IU (2009) Separation of no-carrier-added arsenic-77 from neutron irradiated germanium. Radiochim Acta 97:503–506

    Article  CAS  Google Scholar 

  7. Ellison PA, Chen F, Barnhart TE, Nickles RJ, Cai W, DeJesus OT (2015) Production and isolation of 72As from proton irradiation of enriched 72GeO2 for the development of targeted PET/MRI agents. In: Proc of the 15th International Workshop on Targetry and Target Chemistry

  8. Ikeda H, Kikunaga H, Komori Y, Yokokita T, Mori D, Haba H, Watabe H (2019) Production of arsenic RI tracer from gallium oxide target by alpha beam irradiation. RIKEN Accel Prog Rep 52:206

    Google Scholar 

  9. Naskar N, Lahiri S (2021) Separation of no-carrier-added 71,72As from 46 MeV alpha particle irradiated gallium oxide target. Radiochim Acta. https://doi.org/10.1515/ract-2020-0120

    Article  Google Scholar 

  10. Naskar N, Lahiri S (2021) Separation of 71,72As from alpha particle induced gallium oxide target by solid cation and anion exchangers, DOWEX-50 and DOWEX-1. Appl Radiat Isot 176:109876

    Article  CAS  Google Scholar 

  11. Bombard A, Happel S, Bas M, Vajda N, Dirks C (2018) In: Lahiri S (ed) New TK200 resin: uses for actinides preconcentration and separation. Application of radiotracers and energetic beams in sciences, vol 5, pp 265–266

  12. Wang Z, Huang Z, Xie Y, Tan Z (2019) Method for determination of Pu isotopes in soil and sediment samples by inductively coupled plasma mass spectrometry after simple chemical separation using TK200 resin. Anal Chim Acta 1090:151–158

    Article  CAS  Google Scholar 

  13. Ali KA, Vanjara AK (2001) Solvent extraction and separation of Bi(III) and Sb(III) from HCl and HBr media using tri-n-octylphosphine oxide (TOPO). Indian J Chem Technol 8:239–243

    CAS  Google Scholar 

  14. Choudhury D, Lahiri S, Nag T, Sodaye S, Bombard A (2020) Separation of bulk Pb and Bi from proton irradiated lead bismuth eutectic (LBE) target by DGA-N and TK-200 resins. J Radioanal Nucl Chem 324:897–902

    Article  CAS  Google Scholar 

  15. Choudhury D, Naskar N, Lahiri S (2021) Distribution of different no-carrier-added radionuclides in Pb and Bi fractions after separation of bulk components of lead bismuth eutectic. J Radioanal Nucl Chem 328:1339–1347

    Article  CAS  Google Scholar 

  16. Sato T, Sato K, Noguchi Y (2001) Liquid-Liquid extraction of mercury (II) from hydrocholoric acid and nitric acid solutions by trioctylphosphine oxide. Shigen-to-Sozai 117:880–884

    Article  CAS  Google Scholar 

  17. Pourmand A, Dauphas N (2010) Distribution coefficients of 60 elements on TODGA resin: application to Ca, Lu, Hf, U and Th isotope geochemistry. Talanta 81:741–753

    Article  CAS  Google Scholar 

  18. Alliot C, Kerdjoudj R, Michel N, Haddad F, Huclier-Markai S (2015) Cyclotron production of high purity 44m,44Sc with deuterons from 44CaCO3 targets. Nucl Med Biol 42:524–529

    Article  CAS  Google Scholar 

  19. Dulanska S, Antalık I, Labaska M, Remenec B, Matel A (2013) Rapid determination of 239,240Pu, 238Pu, 241Am and 90Sr in high contaminated samples waste using combined SPE sorbents Ana- Lig_ Pu-02, AnaLig_ Sr-01 and DGA_ Resin. J Radioanal Nucl Chem 295:1635–1639

    Article  CAS  Google Scholar 

  20. Olfert JM, Dai X, Kramer-Tremblay S (2014) Rapid determination of 90Sr/90Y in water samples by liquid scintillation and Cherenkov counting. J Radioanal Nucl Chem 300:263–267

    Article  CAS  Google Scholar 

  21. Tazoe H, Obata H, Yamagata T, Karube Z, Nagai H, Yamada M (2016) Determination of strontium-90 from direct separation of yttrium-90 by solid phase extraction using DGA resin for seawater monitoring. Talanta 152:219–227

    Article  CAS  Google Scholar 

  22. Retzmann A, Zimmermann T, Pröfrock D, Prohaska T, Irrgeher J (2017) A fully automated simultaneous single-stage separation of Sr, Pb, and Nd using DGA resin for the isotopic analysis of marine sediments. Anal Bioanal Chem 409:5463–5480

    Article  CAS  Google Scholar 

  23. Triskem International, Extraction chromatography, Technical documentation https://www.triskeminternational.com/scripts/files/5fbc13a4ab55f4.79381966/technical-doc-all-resins-en-web.pdf

  24. Süfke F, Lippold J, Happe S (2018) Improved Separation of Pa from Th and U in marine Sediments with TK400 Resin. Anal Chem 90:1395–1401

    Article  Google Scholar 

  25. Kumbasar RA, Tutkun O (2004) Separation and concentration of gallium from acidic leach solutions containing various metal ions by emulsion type of liquid membranes using TOPO as mobile carrier. Hydrometallurgy 75:111–121

    Article  CAS  Google Scholar 

Download references

Acknowledgements

Authors are thankful to the cyclotron staffs of Variable Energy Cyclotron Centre (VECC), Kolkata for their cooperation.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Nabanita Naskar.

Ethics declarations

Conflict of interest

The authors declare that they have no conflict of interest.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Naskar, N., Lahiri, S. & Bombard, A. Separation of no-carrier-added 71,72As from 46 MeV alpha particle irradiated Ga2O3 target by TK200 and DGA-N resins. J Radioanal Nucl Chem 331, 215–220 (2022). https://doi.org/10.1007/s10967-021-08110-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10967-021-08110-2

Keywords

Navigation