Abstract
Occurrence of uranium isotopes in groundwater provides a tracer technology for quality, sources, and recharge conditions. Groundwater samples collected from different aquifer types (sand dune, Quaternary clastics, ophiolite, carbonates and sabkha) in the UAE were analyzed for 238U and 235U. In addition to uranium isotopes, monitoring indicators also cover groundwater pH, temperature and TDS. The concentration of uranium isotopes (238U + 235U) range from 4 to 69,745 ng/L. The distribution of the isotopes in the groundwater of the UAE can be linked to aquifer lithological variability, distance from recharge front and seawater intrusion. In general, about 3% of the groundwater analyzed have uranium concentration above the WHO permissible limit for drinking water.
Similar content being viewed by others
References
Alshamsi D, Ahmed M, Aldahan A, Hou XL (2013) Uranium isotopes in carbonate aquifers of arid region setting. J Radioannal Nucl Chem. https://doi.org/10.1007/s10967-013-2558-z
Almasoud F, Ababneh Z, Alanazi Y, Khandaker M, Sayyed MI (2019) Assessment of radioactivity contents in bedrock groundwater samples from the northern region of Saudi Arabia. Chemosphere. https://doi.org/10.1016/j.chemosphere
Bhattacharya P, Ramanathan AL, Mukherjee AB, Bundschuh J, Chandrasekharam D, Keshari AK (2008) Groundwater for sustainable development: problems, perspectives and challenges. CRC Press, Boca Raton
Nolan J, Weber KA (2015) Natural uranium contamination in major U.S. aquifers linked to nitrate. Environ Sci Technol Lett. https://doi.org/10.1021/acs.estlett.5b00174
Riedel T, Kübeck C (2017) Uranium in groundwater—a synopsis based on a large hydrogeochemical data set. Water Res. https://doi.org/10.1016/j.watres.2017.11.001
Guidelines for drinking-water quality (4th edition, incorporating the 1st addendum) (2017). World Health Organization. https://apps.who.int/iris/bitstream/handle/10665/254637/9789241549950-eng.pdf;jsessionid=3B6E139A1AC219D99C4865ED1AD11710?sequence=1
The water quality regulations (fourth edition) (2014). The Regulation in the Emirate of Abu Dhabi. http://rsb.gov.ae/assets/documents/366/regswaterquality4thedition.pdf
Murad A, Aldahan A (2019) The impact of climate change on the future resources of the UAE. In: Climate change and the future of water. The Emirates Center for Strategic Studies and Research, pp 45–69
Zheng MJ, Murad A, Zhou XD, Yi P, Alshamsi D, Hussein S, Chen L, Hou XL, Aldahan A, Yu ZB (2015) Distribution and sources of 226Ra in groundwater of arid region. J Radioanal Nucl Chem. https://doi.org/10.1007/s10967-015-4632-1
Adithya VS, Chidambaram S, Keesari T, Mohokar HV, Prasanna MV (2017) Occurrence of uranium in groundwater along the lithological contacts in central tamilnadu, india: an isotope hydrogeochemical perspective. Expos Health. https://doi.org/10.1007/s12403-017-0269-3
Erőss A, Csondor K, Izsák Bálint (2018) Uranium in groundwater—the importance of hydraulic regime and groundwater flow system’s understanding. J Environ Radioact. https://doi.org/10.1016/j.jenvrad.2018.10.002
Kozaia N, Ohnukia T, Iwatsukib T (2013) Characterization of saline groundwater at Horonobe, Hokkaido, Japan by SEC-UV-ICP-MS: speciation of uranium and iodine. Water Res 47:1570–1584
Dunk RM, Mills RA, Jenkins WJ (2002) A reevaluation of the oceanic uranium budget for the Holocene. Chem Geol. https://doi.org/10.1016/S0009-2541(02)00110-9
Andersson PS, Porcelli D, Gustafsson O, Ingri J, Wasserburg GJ (2001) The importance of colloids for the behavior of uranium isotopes in the low-salinity zone of a stable estuary. Geochim Cosmochim Acta. https://doi.org/10.1016/S0016-7037(00)00514-7
Valencia A, Oliva JL, Bodega G, Chiloeches A, Baskaran M (1997) The importance of colloids and mires for the transport of uranium isotopes through the Kalix River watershed and Baltic Sea. Geochim Cosmochim Acta. https://doi.org/10.1016/S0016-7037(97)00235-4
Anderson PS, Wasserburg GJ, Chen JH, Papanastassiou DA, Ingri J (1995) 238U-234U and 232Th-230Th in the baltic sea and in river water. Earth Planet Sci Lett. https://doi.org/10.1016/0012-821X(94)00262-W
Andersson PS, Porcelli D, Wasserburg GJ, Ingri J (1998) Particle transport of 234U–238U in the Kalix river and in the Baltic Sea. Geochim Cosmochim Acta. https://doi.org/10.1016/S0016-7037(97)00342-6
Radiation Information for Uranium. U.S. Environmental Protection Agency (31 July 2009)
ToxFAQ for Uranium. Agency for Toxic Substances and Disease Registry. September 1999 (18 February 2007)
Guerrero JL, Vallejos A, Cerón JC (2016) U-isotopes and 226Ra as tracers of hydrogeochemical processes in carbonated karst aquifers from arid areas. J Environ Radioact. https://doi.org/10.1016/j.jenvrad.2016.03.015
Daniel JC, Noah M, Stephen RN, Samuel AB (2010) Isotopic composition (238U/235U) of some commonly used uranium reference materials. Geochim Cosmochim Acta. https://doi.org/10.1016/j.gca.2010.09.019
Fleischer RL, Raabe RO (1978) Recoiling alpha-emitting nuclei: mechanisms for uranium-series disequilibrium. Geochim Cosmochim Acta 42:973–978
Krall L, Luis AS, Jordi GO, Eva-Lena T, Giada T, Juhani S, Don P, Per A (2019) Radium isotopes to trace uranium redox anomalies in anoxic groundwater. Geol Chem. https://doi.org/10.1016/j.chemgeo.2019.119296
Murad A, Alshamsi D, Hou XL, Shidi AF, Kendi AR, Aldahan A (2014) Radioactivity in groundwater along the borders of Oman and UAE. J Radioannal Nucl Chem. https://doi.org/10.1007/s10967-013-2911-2
Farrant AR (2006) Geology of the Ras AL Khaimah, 1:100,000 map sheet, 100-1, United Arab Emirates. United Arab Emirates. Petroleum & Minerals Sector, Minerals Department
Tomita J, Zhang J, Yamamoto M (2014) Radium isotopes (Ra-226 and Ra-228) in Na-Cl type groundwaters from Tohoku District (Aomori, Akita and Yamagata Prefectures) in Japan. J Environ Radioact. https://doi.org/10.1016/j.jenvrad.2014.07.021
Craft E, Abu-Qare A, Flaherty M, Garofolo M, Rincavage H, Abou-Donia M (2004) Depleted and natural uranium: chemistry and toxicological effects. J Toxicol Environ Health. https://doi.org/10.1080/10937400490452714
Faroon O, Ingerman L, Roney N, Scinicariello F, Wilbur SB (2013) Toxicological profile for uranium. Agency for Toxic Substances and Disease Registry (ATSDR)
Hindin R, Brugge D, Panikkar B (2005) Teratogenicity of depleted uranium aerosols: a review from an epidemiological perspective. Environ Health. https://doi.org/10.1186/1476-069x-4-17
Arfsten DP, Still KR, Ritchie GD (2001) A review of the effects of uranium and depleted uranium exposure on reproduction and fetal development. Toxicol Ind Health. https://doi.org/10.1191/0748233701th111oa
Acknowledgements
This research was supported by the Hydraulic science, and technology in Hunan Province ([2017]230-36) and United Arab Emirate University through UPAR (31153). We also thank National Water Center Grants and the National Natural Science Foundation of China and the Special Fund of State Key Laboratory of Hydrology-Water Resources and Hydraulic Engineering of Hohai University (XDA2010010307, 51979072).
Author information
Authors and Affiliations
Corresponding authors
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Electronic supplementary material
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Xiong, L., Alshamsi, D., Yi, P. et al. Distribution of uranium isotopes in groundwater of the UAE: environmental radioactivity assessment. J Radioanal Nucl Chem 325, 57–66 (2020). https://doi.org/10.1007/s10967-020-07216-3
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10967-020-07216-3