Abstract
A collagen fiber adsorbent was prepared by a modification of collagen fiber with alkali activation. The alkali-activated collagen fiber (AACF) was characterized and its adsorption mechanism was analyzed. The results demonstrated that U(VI) adsorption was mainly achieved by ion exchange and complexation coordination. Its maximum adsorption capacity reached 182.27 mg g−1 at 328.15 K, and it fitted well to the Langmuir isotherm model. The calculated thermodynamic parameters showed that the adsorption was a spontaneous and endothermic process. Moreover, the ultrahigh adsorption properties of AACF for U(VI) ions showed that it has high potential for the extraction of uranium from a simulated high-salinity environment.
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References
Kahouli S (2011) Re-examining uranium supply and demand: new insights. Energy Policy 39:358–376
Bai ZQ, Yuan LY, Zhu L, Liu ZR, Chu SQ, Zheng LR, Zhang J, Chai ZF, Shi WQ (2014) Introduction of amino groups into acid-resistant MOFs for enhanced U(VI) sorption. J Mater Chem A 3:525–534
Kim J, Tsouris C, Mayes RT, Oyola Y, Saito T, Janke CJ, Dai S, Schneider E, Sachde D (2013) Recovery of uranium from seawater: a review of current status and future research needs. Sep Sci Technol 48:367–387
An S, Zhijiani W (2007) Feasibility of uranium extraction from oilfield waters and salt lake brines in Qaidam basin. J Salt Lake Res 15:55–62
Yan T, Luo X, Zou Z, Lin X, He Y (2017) Adsorption of uranium(VI) from a simulated saline solution by alkali-activated leather waste. Ind Eng Chem Res 56:3251–3258
Jian S, Wenyi T, Wuyong C (2008) Ultrasound-accelerated enzymatic hydrolysis of solid leather waste. J Clean Prod 16:591–597
Qiang T, Luo M, Bu Q, Wang X (2012) Adsorption of an acid dye on hyperbranched aminated collagen fibers. Chem Eng J 197:343–349
Liao XP, Shi B (2004) Adsorption of fluoride on zirconium(IV)-impregnated collagen fiber. Environ Sci Technol 38:324–328
Ayten A, Akgül G (2016) Modification of natural zeolite with NaOH for removal of manganese in drinking water. Powder Technol 287:285–291
Chen Z, Wang J, Pu Z, Zhao Y, Jia D, Chen H, Wen T, Hu B, Alsaedi A, Hayat T, Wang X (2017) Synthesis of magnetic Fe3O4/CFA composites for the efficient removal of U(VI) from wastewater. Chem Eng J 320:448–457
Li F, Li D, Li X, Liao J, Li S, Yang J, Yang Y, Tang J, Liu N (2016) Microorganism-derived carbon microspheres for uranium removal from aqueous solution. Chem Eng J 284:630–639
Ai L, Luo X, Lin X, Zhang S (2013) Biosorption behaviors of uranium(VI) from aqueous solution by sunflower straw and insights of binding mechanism. J Radioanal Nucl Chem 298:1823–1834
Bai J, Yin X, Zhu Y, Fan F, Wu X, Tian W, Tan C, Zhang X, Wang Y, Cao S, Fan F, Qin Z, Guo J (2016) Selective uranium sorption from salt lake brines by amidoximated saccharomyces cerevisiae. Chem Eng J 283:889–895
Shao DD, Jiang ZQ, Wang XK, Li JX, Meng YD (2009) Plasma induced grafting carboxymethyl cellulose on multiwalled carbon nanotubes for the removal of UO2 2+ from aqueous solution. J Phys Chem B 113:860–864
Košak A, Lobnik A, Bauman M (2013) Adsorption of mercury(II), lead(II), cadmium(II) and zinc(II) from aqueous solutions using mercapto-modified silica particles. Int J Appl Ceram Technol 12:461–472
Shafa-Amry NN, Khalili FI, Ebraheem KAK, Mubarak MS (2006) Synthesis and chelation properties of Mannich polymers derived from piperazine and some hydroxy benzaldoximes. React Funct Polym 66:789–794
Manos MJ, Kanatzidis MG (2012) Layered metal sulfides capture uranium from seawater. J Am Chem Soc 134:16441–16446
Li JQ, Gong LL, Feng XF, Zhang L, Wu HQ, Yan CS, Xiong YY, Gao HY, Luo F (2017) Direct extraction of U(VI) from alkaline solution and seawater via anion exchange by metal-organic framework. Chem Eng J 316:154–159
Li S, Bai H, Wang J, Jing X, Liu Q, Zhang M, Chen R, Liu L, Jiao C (2012) In situ grown of nano-hydroxyapatite on magnetic CaAl-layered double hydroxides and its application in uranium removal. Chem Eng J 193:372–380
Das S, Pandey AK, Athawale AA, Manchanda VK (2009) Exchanges of uranium(VI) species in amidoxime-functionalized sorbents. J Phys Chem B 113:6328–6335
Sun X, Huang X, Liao X, Shi B (2010) Adsorptive recovery of UO2 2+ from aqueous solutions using collagen-tannin resin. J Hazard Mater 179:295–302
Ho YS, Mckay G (1999) Pseudo-second order model for sorption processes. Process Biochem 34:451–465
Yang S, Li J, Shao D, Hu J, Wang X (2009) Adsorption of Ni(II) on oxidized multi-walled carbon nanotubes: effect of contact time, pH, foreign ions and PAA. J Hazard Mater 166:109–116
Liu P, Wu H, Yuan N, Liu Y, Pan D, Wu W (2017) Removal of U(VI) from aqueous solution using synthesized β-zeolite and its ethylenediamine derivative. J Mol Liq 234:40–48
Langmuir I (1918) The adsorption of gases on plane surfaces of glass, mica and platinum. J Am Chem Soc 40:1361–1403
Freundlich HMF (1906) Over the adsorption in solution. J Chem Phys 57:385–470
Zhao YS, Liu CX, Feng M, Chen Z, Li SQ, Tian G, Wang L, Huang JB, Li SJ (2010) Solid phase extraction of uranium(VI) onto benzoylthiourea-anchored activated carbon. J Hazard Mater 176:119–124
Hu R, Wang XK, Dai SY, Shao DD, Hayat T, Alsaed A (2015) Application of graphitic carbon nitride for the removal of Pb(II) and aniline from aqueous solutions. Chem Eng J 260:469–477
Wang YQ, Zhang ZB, Liu YH, Cao XH, Liu YT, Li Q (2012) Adsorption of U(VI) from aqueous solution by the carboxyl-mesoporous carbon. Chem Eng J 198:246–253
Ji G, Zhu G, Wang X, Wei Y, Yuan J, Gao C (2017) Preparation of amidoxime functionalized SBA-15 with platelet shape and adsorption property of U(VI). Sep Purif Technol 174:455–465
Wang X, Xia L, Tan K, Zheng W (2012) Studies on adsorption of uranium(VI) from aqueous solution by wheat straw. Environ Prog Sustain 31:566–576
Buema G, Noli F, Misaelides P, Sutiman D, Cretescu I, Harja M (2014) Uranium removal from aqueous solutions by raw and modified thermal power plant ash. J Radioanal Nucl Chem 299:381–386
Menacer S, Lounis A, Guedioura B, Bayou N (2016) Uranium removal from aqueous solutions by adsorption on Aleppo pine sawdust, modified by NaOH and neutron irradiation. Desalin Water Treat 57:1–12
Zhu K, Chen C, Li J, Zhang R (2016) Alkali-treated cellulose fibers for U(VI) separation and enrichment. J Radioanal Nucl Chem 308:981–990
Acknowledgements
This work was financially supported by National Nuclear Energy Development Research Project (Grant 16zg6101). Technology support of Engineering Research Center of Biomass Materials, Ministry of Education, Southwest University of Science and Technology, is greatly appreciated.
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Deng, G., Zhang, Y., Luo, X. et al. Direct extraction of U(VI) from a simulated saline solution by alkali-activated collagen fiber. J Radioanal Nucl Chem 318, 1109–1118 (2018). https://doi.org/10.1007/s10967-018-6083-y
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DOI: https://doi.org/10.1007/s10967-018-6083-y