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Adsorption behavior of a carbonized paper sludge towards 137Cs

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Abstract

The adsorption of 137Cs by a carbonized paper sludge (PSC) was studied using the original and its modified form (PFC-PSC) by impregnating with 1 % potassium ferrocyanide. The distribution coefficient of PSC decreases with increasing Cs+ concentration in 137Cs solutions whereas that of PFC-PSC is highest at around and lower than 60 Bq ml−1. The Freundlich constant of PFC-PSC is much higher than that of PSC, suggesting that the 137Cs affinity of the former is higher than the latter. The pseudo second order rate constant of PSC decreases but that of PFC-PSC increases with decreasing Cs+ concentration.

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References

  1. Khalili NR, Vyas JD, Weangkaew W, Westfall SJ, Parulekar SJ, Sherwood R (2002) Synthesis and characterization of activated carbon and bioactive adsorbent produced from paper mill sludge. Sep Purif Technol 26:295–304

    Article  CAS  Google Scholar 

  2. Li Y, Yue Q, Qi Y, Li W, Zhao H, Zhao Y, Du J (2012) Preparation of paper mill sludge-based granular activated carbon fillers for fluidized-bed bioreactor (FBBR). Environ Technol 33:1701–1708

    Article  CAS  Google Scholar 

  3. Caccin M, Giacobbo F, Da Ros M, Besozzi L, Mariani M (2013) Adsorption of uranium, cesium and strontium onto coconut shell activated carbon. J Radioanal Nucl Chem 297:9–18

    Article  CAS  Google Scholar 

  4. Kubota T, Fukutani S, Ohta T, Mahara Y (2013) Removal of radioactive cesium, strontium, and iodine from natural waters using bentonite, zeolite, and activated carbon. J Radioanal Nucl Chem 296:981–984

    Article  CAS  Google Scholar 

  5. Watari K, Izawa M (1965) Separation of radiocesium by copper ferrocyanide-anion exchange resin. J Nucl Sci Technol 2:321–322

    Article  CAS  Google Scholar 

  6. Lehto J, Harjula R, Wallace J (1987) Absorption of cesium on potassium cobalt hexacyanoferrate (II). J Radioanal Nucl Chem 111:230–297

    Article  Google Scholar 

  7. Mimura H, Lehto J, Harjula R (1997) Ion exchange of cesium on potassium nickel hexacyanoferrate (II)s. J Nucl Sci Technol 34:484–489

    Article  CAS  Google Scholar 

  8. Lalhriatpuia, Lalhmunsiama C, Tiwari D, Lee S-M (2014) Immobilized nickel hexacyanoferrate on activated carbons for efficient attenuation of radio toxic Cs(I) from aqueous solutions. Appl Surf Sci 321:275–282

    Article  Google Scholar 

  9. Japanese Patent 3352019 (2002)

  10. Japanese Patent 5605782 (2014)

  11. Gillman GP, Sumpter EA (1986) Modification to the compulsive exchange method for measuring exchange characteristics of soils. Aust J Soil Res 24:61–66

    Article  CAS  Google Scholar 

  12. Akiba K, Hashimoto H, Kanno T (1989) Distribution coefficient of cesium and cation exchange capacity of minerals and rocks. J Nucl Sci Technol 26:1130–1135

    Article  CAS  Google Scholar 

  13. El-Kamash AM, Zaki AA, El Geleel MA (2005) Modelling batch kinetics and thermodynamics of zinc and cadmium ions removal from waste solutions using synthetic zeolite A. J Hazard Mater B127:211–220

    Article  Google Scholar 

  14. Bayulken S, Bascetin E, Guclu K, Apak R (2011) Investigation and modeling of cesium (I) adsorption by Turkish clays : bentonite, zeolite, sepiolite, and kaolinite. Environ Prog Sustain Energy 30:70–80

    Article  Google Scholar 

  15. Mellah A, Chegrouche S, Barkat M (2006) The removal of uranium (VI) from aqueous solutions onto activated carbon: kinetic and thermodynamic investigations. J Colloid Interface Sci 296:434–441

    Article  CAS  Google Scholar 

  16. Yildiz B, Erten HN, Kis M (2011) The sorption behavior of Cs+ ion on clay minerals and zeolite in radioactive waste management: sorption kinetics and thermodynamics. J Radioanal Nucl Chem 288:475–483

    Article  CAS  Google Scholar 

  17. El-Kamash AM, El-Gammal B, El-Sayed AA (2007) Preparation and evaluation of cerium (IV) tungstate powders as inorganic exchanger in sorption of cobalt and europium ions from aqueous solutions. J Hazard Mater 141:719–728

    Article  CAS  Google Scholar 

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Acknowledgments

One of the authors (M. Yanaga) is indebted to the Japan Science and Technology Agency (JST) for its Grant-in-Aid for Scientific Research (C) (25350124) from which this research was partially funded.

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Correspondence to A. Van Tran.

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Van Tran, A., Yanaga, M. Adsorption behavior of a carbonized paper sludge towards 137Cs. J Radioanal Nucl Chem 308, 857–863 (2016). https://doi.org/10.1007/s10967-015-4529-z

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  • DOI: https://doi.org/10.1007/s10967-015-4529-z

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