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Investigation of actinides(III)-DOTA complexes by electrospray ionization mass spectrometry

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Abstract

Electrospray ionization mass spectrometry was used to investigate the complexation of plutonium(III) and americium(III) by DOTA in aqueous solution. As for europium(III) complexation, data obtained show the presence of a single extremely stable ion ML− in negative ion mode. The kinetic stability of gas phase ions has been investigated by both in-source and in-ion trap collision induced dissociation for lanthanides(III) and actinides(III) species and provides valuable information on the system.

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Authors and Affiliations

  1. Nuclear Energy Division, RadioChemistry & Processes Department, CEA, BP 17171, 30207, Bagnols-Sur-Cèze Cedex, France

    M. Audras, L. Berthon, N. Martin, N. Zorz & Ph. Moisy

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  1. M. Audras
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  2. L. Berthon
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  3. N. Martin
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  4. N. Zorz
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  5. Ph. Moisy
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Correspondence to L. Berthon.

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Audras, M., Berthon, L., Martin, N. et al. Investigation of actinides(III)-DOTA complexes by electrospray ionization mass spectrometry. J Radioanal Nucl Chem 303, 1897–1909 (2015). https://doi.org/10.1007/s10967-014-3672-2

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  • DOI: https://doi.org/10.1007/s10967-014-3672-2

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