Abstract
We studied solid–liquid extraction behavior of carrier-free Mo and W radiotracers onto an Aliquat 336-loaded resin from HCl solutions toward extraction chromatography experiments of element 106, seaborgium (Sg). Distribution coefficients (K d) of Mo and W on the resin were determined as a function of HCl concentration by a batch method. On-line extraction chromatography of Mo and W was also carried out in 2–8 M HCl solutions with an automated rapid chemistry apparatus. The order of extraction probability from 2 to 8 M HCl was Mo > W, which reflected the order of the K d values in the batch experiment.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Schädel M (2006) Angew Chem Int Ed 45:368–401
Türler A, Pershina V (2013) Chem Rev 113:1237–1312
Schädel M, Brüchle W, Schausten B, Schimpf E, Jäger E, Wirth G, Günther R, Kratz JV, Paulus W, Seibert A, Thörle P, Trautmann N, Zauner S, Schumann D, Andrassy M, Misiak R, Gregorich KE, Hoffman DC, Lee DM, Sylwester ER, Nagame Y, Oura Y (1997) Radiochim Acta 77:149–159
Schädel M, Brüchle W, Jäger E, Schausten B, Wirth G, Paulus W, Günther R, Eberhardt K, Kratz JV, Seibert A, Strub E, Thörle P, Trautmann N, Waldek A, Zauner S, Schumann D, Kirbach U, Kubica B, Misiak R, Nagame Y, Gregorich KE (1998) Radiochim Acta 83:163–165
Schädel M, Brüchle W, Jäger E, Schimpf E, Kratz JV, Scherer UW, Zimmermann HP (1989) Radiochim Acta 48:171–176
Haba H, Kaji D, Kudou Y, Morimoto K, Morita K, Ozeki K, Sakai R, Sumita T, Yoneda A, Kasamatsu Y, Komori Y, Shinohara A, Kikunaga H, Kudo H, Nishio K, Ooe K, Sato N, Tsukada K (2012) Phys Rev C 85:024611-1–024611-11
Ooe K, Yahagi W, Komori Y, Fujisawa H, Takayama R, Kikunaga H, Yoshimura T, Takahashi N, Haba H, Kudou Y, Ezaki Y, Shinohara A (2011) Proc Radiochemistry A Suppl Radiochim Acta 1:127–129
Yokokita T, Ooe K, Kasamatsu Y, Yoshimura T, Takahashi N, Shiohara N, Takamiya K, Komori Y, Kikutani Y, Kino A, Shinohara A (2014) APSORC13 proceedings. doi:10.1007/s10967-014-3449-7 [Epubahead of print]
Haba H, Tsukada K, Asai M, Toyoshima A, Ishii Y, Toume H, Sato T, Nishinaka I, Ichikawa T, Ichikawa S, Nagame Y, Sato W, Matsuo K, Kitamoto Y, Tashiro Y, Shinohara A, Saito J, Ito M, Ikezawa T, Sakamaki M, Goto S, Kudo H, Kikunaga H, Arai M, Kamataki S, Yokoyama A, Akiyama K, Sueki K, Oura Y, Schädel M, Brüchle W, Kratz JV (2007) Radiochim Acta 95:1–6
Pershina V, Kratz JV (2001) Inorg Chem 40:776–780
Kronenberg A, Mohapatra PK, Kratz JV, Pfrepper G, Pfrepper R (2001) Radiochim Acta 92:395–403
Heinter-Wirguin C, Cohen R (1965) J Inorg Nucl Chem 27:1989–1998
Sato T, Sato K (1995) Hydrometallurgy 37:253–266
Acknowledgments
A part of this work was performed at the RI Beam Factory operated by RIKEN Nishina Center and CNS, University of Tokyo. We express our gratitude to the crew of the RIKEN AVF cyclotron for their invaluable assistance in the course of these experiments. We also thank the crew of the AVF cyclotron of RCNP for the production of the radiotracer 181W.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Komori, Y., Yokokita, T., Kasamatsu, Y. et al. Solid–liquid extraction of Mo and W by Aliquat 336 from HCl solutions toward extraction chromatography experiments of Sg. J Radioanal Nucl Chem 303, 1385–1388 (2015). https://doi.org/10.1007/s10967-014-3476-4
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10967-014-3476-4