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Interactions of some protonated α-amino acid methyl esters with hexaethyl p-tert-butylcalix[6]arene hexaacetate in nitrobenzene saturated with water

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Abstract

The exchange extraction constants corresponding to the general equilibrium C+(aq) + Cs+(nb) ⇔ C+ (nb) + Cs+(aq) occurring in the two-phase water–nitrobenzene system (C+ = protonated α-amino acid methyl ester, 1 = hexaethyl p-tert-butylcalix[6]arene hexaacetate; aq = aqueous phase, nb = nitrobenzene phase) were evaluated on the basis of extraction experiments and γ-activity measurements. Further, the stability constants of the C+ cationic complex species in nitrobenzene saturated with water were calculated; they were found to increase in the following cation order: protonated l-tryptophan methyl ester < protonated l-phenylalanine methyl ester < protonated l-leucine methyl ester < protonated l-methionine methyl ester < protonated l-valine methyl ester.

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Acknowledgments

This work was supported by the Grant Agency of Faculty of Environmental Sciences, Czech University of Life Sciences, Prague, Project No.: 42900/1312/3114 “Environmental Aspects of Sustainable Development of Society,” and by the Czech Ministry of Education, Youth, and Sports, Project MSM 6046137307.

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Makrlík, E., Vaňura, P. & Selucký, P. Interactions of some protonated α-amino acid methyl esters with hexaethyl p-tert-butylcalix[6]arene hexaacetate in nitrobenzene saturated with water. J Radioanal Nucl Chem 300, 947–951 (2014). https://doi.org/10.1007/s10967-014-3036-y

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  • DOI: https://doi.org/10.1007/s10967-014-3036-y

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