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The studies on absorption behavior of calix[4]-bis-crown-6 chromatographic resin and its application to the separation of HLW

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Abstract

In this paper, to separation Cs(I) effectively from HLW, a kind of chromatographic rein was synthesized through immobiling calix[4]-bis-crown-6 on the macroporous polystyrene -divinylbenzene polymeric material. The synthesized chromatographic resin showed high ability to absorb Cs(I). While the radioactive elements Pu(III), Np(V), U(VI), Th(IV), as well as all of the fission and non-fission products showed almost no sorption towards chromatographic rein. The separation of Cs from HLW can be realized through adjusting the valence of Np and Pu or adding H2C2O4. All the results showed that the application of the new chromatographic rein to the analysis of HLW is possible.

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Authors and Affiliations

  1. Department of Radiochemistry, China Institute of Atomic Energy, P.O. Box 275-88, Beijing, 102413, People’s Republic of China

    Xiaojuan Hao, Shuping Tan & Weiqin Deng

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  1. Xiaojuan Hao
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  2. Shuping Tan
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  3. Weiqin Deng
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Correspondence to Shuping Tan.

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Hao, X., Tan, S. & Deng, W. The studies on absorption behavior of calix[4]-bis-crown-6 chromatographic resin and its application to the separation of HLW. J Radioanal Nucl Chem 292, 1291–1296 (2012). https://doi.org/10.1007/s10967-012-1617-1

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  • DOI: https://doi.org/10.1007/s10967-012-1617-1

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