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Adsorptivity of various metal ions onto benzo-18-crown-6 and dibenzo-18-crown-6 resins

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Abstract

Adsorptivity of metal ions onto silica-supported benzo-18-crown-6 (B18C6) and dibenzo-18-crown-6 (DB18C6) resins was investigated in nitric acid and hydrochloric acid media to evaluate the applicability of these resins for selective separation of nuclides from radioactive waste solutions. Both resins adsorbed Pd(II) and Ag(I) from HNO3, and Fe(III) and Ba(II) from HCl. It was also found that the B18C6 and DB18C6 resins adsorbed Sr(II) from HCl and Ca(II) from HNO3, respectively. This indicates that the two resins adsorb metal ions with smaller cationic diameters with different selectivity. This behavior is different from other impregnated adsorbents and extractants containing the 18-crown-6 moiety.

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Acknowledgments

This work was partially supported by a Grant-in-Aid for Scientific Research (B) (KAKENHI No. 23360423).

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Authors and Affiliations

  1. Department of Electric and Electronic Engineering, Kinki University, Higashi-osaka, Japan

    Masanobu Nogami & Tomohiro Haratani

  2. Department of Nuclear System Safety Engineering, Nagaoka University of Technology, Nagaoka, Japan

    Yu Tachibana & Tatsuya Suzuki

  3. Research Laboratories for Nuclear Reactors, Tokyo Institute of Technology, Tokyo, Japan

    Toshitaka Kaneshiki & Masao Nomura

Authors
  1. Masanobu Nogami
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  2. Tomohiro Haratani
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  3. Yu Tachibana
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  4. Toshitaka Kaneshiki
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  5. Masao Nomura
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  6. Tatsuya Suzuki
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Correspondence to Masanobu Nogami.

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Nogami, M., Haratani, T., Tachibana, Y. et al. Adsorptivity of various metal ions onto benzo-18-crown-6 and dibenzo-18-crown-6 resins. J Radioanal Nucl Chem 303, 1549–1553 (2015). https://doi.org/10.1007/s10967-014-3555-6

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  • DOI: https://doi.org/10.1007/s10967-014-3555-6

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