Abstract
This paper reports silica gel loaded with p-tert-butylcalix[8]arene as a new solid phase extractor for determination of trace level of uranium. Effective extraction conditions were optimized in column methods prior to determination by spectrophotometry using arsenazo(III). The results showed that U(VI) ions can be sorbed at pH 6 in a mini-column and quantitative recovery of U(VI) (>95–98%) was achieved by stripping 0.4 mol L−1 HCl. The sorption capacity of the functionalized sorbent is 0.072 mmol uranium(VI) g−1 modified silica gel. The relative standard deviation and detection limit were 1.2% (n = 10) for 1 μg uranium(VI) mL−1 solution and 0.038 μg L−1, respectively. The method was employed to the preconcentration of U(VI) ions from spiked ground water samples.
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Camel V (2003) Spectrochim Acta B 58:1177
Terada K (1991) Anal Sci 7:187
Garg BS, Sharma RK, Bhojak N, Mittal S (1999) Microchem J 61:94
Sharma RK, Mittal S, Koel M (2003) Crit Rev Anal Chem 33:183
Ayata S, Kaynak I, Merdivan M (2009) Environ Monit Assess 153:333
Sarkar M, Das M, Data PK (2002) J Colloid Interface Sci 246:263
Duru PE, Bektas S, Genc O, Patir S, Denizli A (2001) J Appl Polym Sci 81:197
Sadeghi S, Sheikhzadeh E (2009) J Hazard Mater 163:861
Aziz M, Beheir SG, Sakin KJ (1993) J Radioanal Nucl Chem 172:319
Miyake Y, Sugimara Y, Mayada M (1970) J Oceanogr Soc Jpn 26:123
Starvin M, Prasada Rao T (2004) Talanta 63:225
Kumar M, Rathore DPS, Singh AK (2001) Microchim Acta 137:127
Jain VK, Handa A, Sait SS, Shrivastav P, Agrawal YK (2001) Anal Chim Acta 429:237
Metilda P, Sanghamitra K, Gladis JM, Naidu GRK, Rao TP (2005) Talanta 65:192
Gladis JM, Rao TP (2002) Anal Bioanal Chem 373:867
Schmeide K, Heise KH, Bernhard G, Keil D, Jansen K, Praschak D (2004) J Radioanal Nucl Chem 261:61
Barbette F, Rascalou F, Chollet H, Babouhot JL, Denat F, Guilard R (2004) Anal Chim Acta 502:179
Jain VK, Handa A, Pandya R, Shirvastav P, Agrawal KK (2002) React Funct Polym 51:101
Metilda P, Gladis JM, Rao TP (2005) Radiochim Acta 93:219
Hirata S, Ishida Y, Aihara M, Honda K, Shikino O (2001) Anal Chim Acta 438:205
Merdivan M, Seyhan S, Gok C (2006) Microchim Acta 154:109
Sadeghi S, Akbarzadeh Mofrad A (2007) React Funct Polym 67:966
Seyhan S, Colak M, Merdivan M, Demirel N (2007) Anal Chim Acta 584:462
Pathak R, Rao GN (1996) Anal Chim Acta 335:283
Praveen RS, Metilda P, Daniel S, Rao TP (2005) Talanta 67:960
Shinkai S, Mori S, Koreishi H, Tsubaki T, Manabe O (1986) J Am Chem Soc 108:2409
Memon S, Tabakci M, Roundhill DM, Yilmaz M (2005) Polymer 46:1553
Grunder M, Dozol JF, Asfari Z, Vicens J (1999) J Radioanal Nucl Chem 241:59
Baglan N, Dinse C, Cossonnet C, Abidi R, Asfari Z, Leroy M, Vicens J (1997) J Radioanal Nucl Chem 226:261
Chisholm-Brause CJ, Berg JM, Matzner RA, Morris DE (2001) J Colloid Interface Sci 233:38
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Ayata, S., Merdivan, M. p-tert-Butylcalix[8]arene loaded silica gel for preconcentration of uranium(VI) via solid phase extraction. J Radioanal Nucl Chem 283, 603–607 (2010). https://doi.org/10.1007/s10967-009-0397-8
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DOI: https://doi.org/10.1007/s10967-009-0397-8