Abstract
Absorption spectroscopic properties for various Pu oxidation states in nitric and hydrochloric acid solutions were investigated with UV-Visible spectrophotometry. As a result, it was confirmed that the intensities of the major absorption peaks had a tendency to decrease for Pu(III), Pu(IV) and Pu(VI) in HCl and HNO3 media, and the major peak positions were shifted to longer or shorter wavelengths depending on the complexforming abilities of Pu(III), Pu(IV) and Pu(VI) with the chloride or nitrate ion with increasing acid concentrations. The values of the wavelength and the molar absorptivity for the principal peaks of Pu(III), Pu(IV) and Pu(VI) in NHO3 and HCl solutions were similar to those reported in other works. The values of the molar absorptivity for the principal peaks of Pu(III), Pu(IV) and Pu(VI) in the HNO3 solution were a little higher than those in the HCl solution.
Similar content being viewed by others
References
R. J. Silva, H. Nitsche, MRS Bulletin, 26 (2001) 707.
N. A. Talvitie, Anal. Chem., 43 (1971) 1827.
R. P. Bauman, Absorption Spectroscopy, John Wiley & Sons, New York, 1962, p. 19.
J. C. Hindman, in: The Transuranium Elements, G. T. Seaborg, J. J. Katz, W. M. Manning (Eds), National Nuclear Energy Series IV, McGraw-Hill, New York, 1946. p. 384; 388 and 608.
M. N. Myers, Absorption Spectra of Plutonium and Impurity Ions in Nitric Acid Solution, U. S. Atomic Energy Commission Report HW-44744, 1956.
C. A. Colvin, Quantitative Determination of Plutonium Oxidation States in Variable Nitric Acid Solutions for Control Laboratories, U. S. Atomic Energy Commission Report RL-SA-33, 1965.
P. G. Hagan, F. J. Miner, Spectrophotometric Determination of Plutonium III, IV, and VI in Nitric Acid Solutions, U. S. Atomic Energy Commission Report REP-1391, 1969.
C. Keller, The Chemistry of the Transuranium Elements, Kernchemie in Einzeldarstellungen, Vol. 3, Verlag Chemie GmbH, 1971, p. 409.
M. Shiloh, Y. Marcus, J. Inorg. Nucl. Chem., 28 (1966) 2728.
Y. Marcus, J. Inorg. Nucl. Chem., 28 (1966) 209.
J. M. Cleveland, The Chemistry of Plutonium, American Nucl. Soc., 1979.
V. B. Shevchenko, V. G. Timoshev, A. A. Volkova, Soviet J. At. Energy, 6 (1969) 293 (1969).
J. L. Ryan, J. Phys. Chem., 65 (1961) 1856.
L. V. Lipis, B. G. Pozharskii, V. V. Fomin, J. Struct. Chem., USSR, 1 (1960) 125.
M. Y. Krevinskaia, V. D. Nikolskii, B. G. Pozharskii, Soviet Radiochem., 1 (1960) 244.
V. M. Vdovenko, A. A. Lipovskii, M. G. Kuzina, Soviet Radiochem., 2 (1960) 44.
C. K. McLane, J. S. Dixon, J. C. Hindman, in: The Transuranium Elements, G. T. Seaborg, J. J. Katz, W. M. Manning (Eds), National Nuclear Energy Series IV, McGraw-Hill, New York, 1946, p. 358.
R. E. Connick, M. Kasha, W. H. McVey, G. E. Sheline, in: The Transuranium Elements, G. T. Seaborg, J. J. Katz, W. M. Manning (Eds), National Nuclear Energy Series IV, McGraw-Hill, New York, 1946, p. 559.
G. R. Hall, P. D. Herniman, A. J. Walter, Spectrophotometric Studies of Plutonium in Nitric Acid Solution, Atomic Energy Research Establishment (AERE) C/R 712, 1951.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Lee, M.H., Park, Y.J. & Kim, W.H. Absorption spectroscopic properties for Pu(III, IV and VI) in nitric and hydrochloric acid media. J Radioanal Nucl Chem 273, 375–382 (2007). https://doi.org/10.1007/s10967-007-6848-1
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10967-007-6848-1