Abstract
A method for rapid determination of plutonium isotopes in environmental samples with ultrasonic nebulisation and quadrupole ICP-MS detection was established. Techniques for sample dissolution, pre-concentration and chemical separation were evaluated and the optimal scheme outlined. Comparisons with α-spectrometry and high resolution ICP-MS confirmed the suitability of the method when applied to different environmental matrices within the global fallout concentration range in the northern hemisphere as well as more contaminated sites. Operational detection limits were 0.5–1.5 fg/l for fresh waters and 0.03–0.1 ng/kg for lake sediments and saline marsh sediments.
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References
V. P. Perelygin, Y. T. Chuburkov, Radiat. Meas., 28 (1997) 385.
B. Pellaud, Compt. Rend. Phys., 3 (2002) 1067.
M. Eriksson, E. Holm, P. Roos, H. Dahlgaard, Radioact. Environ., 1 (2001) 293.
E. Holm, Appl. Radiation Isotopes, 46 (1995) 1225.
T. Warneke, I. W. Croudace, P. E. Warwick, R. N. Taylor, Earth Planet. Sci. Lett., 203 (2002) 1047.
F. W. Walker, J. R. Parrington, F. Feiner, The Chart of the Nuclides, Knolls Atomic Power Laboratory, Neval Reactors, U.S. Department of Energy, 1988.
G. Pfennig, H. Klewe-Nebenius, W. Seelmann-Eggebert, Chart of the Nuclides, Forschungszentrum Karlsruhe, 1998.
K. S. Krane, Introductory to Nuclear Physics, Oregon State University, 1988.
M. V. Zoriy, P. Ostapczuk, L. Halicz, R. Hille, J. S. Becker, Intern. J. Mass Spectrom., 242 (2005) 203.
P. A. Burns, M. B. Cooper, K. H. Lokan, M. J. Wilks, G. A. Williams, Appl. Radiation Isotopes, 46 (1995) 1099.
C. Keller, The Chemistry of the Transuranium Elements, Karlsruhe, 1971.
L. L. Vintró, P. I. Mitchell, Determination of Actinides and other Alpha-emitters, Encyclopedia of Analytical Chemistry: Applications, Theory and Instrumentation, Wiley & Sons, Ltd., 2000, p. 12849.
P. I. Mitchell, J. V. Batlle, A. B. Downes, O. M. Condren, L. L. Vintró, J. A. Sánchez-Cabeza, Appl. Radiation Isotopes, 46 (1995) 1175.
N. A. Talvite, Anal. Chem., 44 (1972) 280.
L. Hallstadius, Nucl. Instr. Meth., 223 (1984) 266.
U. Nygren, H. Ramebäck, C. Nilsson, J. Radioanal. Nucl. Chem., 272 (2007) 45.
E. Holm, S. Ballestra, Measurement of Radionuclides in Food and the Environment, A Guidebook, IAEA Tech. Rept. Vienna, Ser. No. 295, 1989, p. 105.
A. E. Eroglu, C. W. Mcleod, K. S. Leonard, D. Mccubbin, Spectrochim. Acta Part, B53 (1998) 1221.
R. S. Strebin, S. K. Fadeff, Sequential Separation of Americium and Plutonium by Extraction Chromatography, DOE Methods, RP800, Draft, 1994.
Eichrom Technologies Inc., Neptunium and Throium in Urine, ACU03, Eichrom Technologies Inc., Analytical Procedures, 2001.
Eichrom Technologies Inc., Eichrom Newsletter, November, 7 (2002).
J. C. Miller, J. N. Miller, Statistics for Analytical Chemistry, 1993.
C. Greis, A. Düker, H. Pettersson, S. Karlsson, B. Allard, Rapid Method for ICP-MS Analysis of Plutonium in Sediment Samples, Scientific Basis for Nuclear Waste Management XXVIII. Materials Research Society, 2004, p. 824.
E. Grahn, C. Greis, S. Karlsson, A. Düker, B. Allard, H. Pettersson, J. Environ. Radioact., Submitted, 2006.
C. Greis, A. Düker, B. Allard, P. Roos, E. Holm, J. Radioanal. Nucl. Chem., in press (2006).
L. Benedik, T. Altzitzoglou, R. Van Ammel, S. Pomme, S. Richter, G. Sibbens, A. Stolarz, A. Verbruggen, R. Wellum, NUSIMEP 5: Uranium, Plutonium and Caesium Isotopic Abundances in a Saline Matrix, Report to Participants, 2006.
M. Eriksson, On Weapons Plutonium in the Arctic Environment (Thule, Greenland), Department of Radiation Physics, Lund University, 2002.
P. P. Povince, M. K. Pham, Report on the Intercomparison Run. IAEA-384. Radionuclides in Fangataufa Lagoon Sediment, 2000.
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Greis, C., Karlsson, S., Düker, A. et al. Determination of plutonium in environmental samples with quadrupole ICP-MS. J Radioanal Nucl Chem 275, 55–70 (2008). https://doi.org/10.1007/s10967-006-7004-z
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DOI: https://doi.org/10.1007/s10967-006-7004-z